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Progress in Chemistry 2017, Vol. 29 Issue (6): 637-648 DOI: 10.7536/PC170349 Previous Articles   Next Articles

• Review •

The Amphipathy Adjustment of Graphene Oxide and Graphene Quantum Dots and Their Application in Pickering Emulsion Polymerization

Linfeng Wei1, Jianzhong Ma1*, Wenbo Zhang2*, Yan Bao1   

  1. 1. Key Laboratory of Leather Cleaner Production, China National Light Industry, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China;
    2. Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology, Shaanxi University of Science & Technology, Xi'an 710021, China
  • Received: Revised: Online: Published:
  • Contact: 10.7536/PC170349 E-mail:majz@sust.edu.cn;zhangwenbo@sust.edu.cn
  • Supported by:
    The work was supported by the Science and Technology Coordinating Innovative Engineering Project in Shaanxi Province (No. 2015KTCL01-11) and the Scientific Research Initiation Foundation of Shaanxi University of Science & Technology(No. 2016BJ-28).
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Graphene oxide (GO) and graphene quantum dots (GQDs) are difficult to disperse in the polymer homogeneously. Pickering emulsion polymerization can effectively improve the dispersity of GO and GQDs in the polymer matrix, so the performances of composite material are improved. This article summarizes the preparation and structure of GO and GQDs, and expounds the influence of the GO size, ionic strength, pH, GO and GQDs structure designing, monomer polarity and other factors for the adjustment of amphiphilicity of GO and GQDs as well as the Pickering emulsion polymerization. The research progress of GO and GQDs used for improving the function of composite by Pickering emulsion polymerization is summarized. The ability for GO and GQDs to act as stabilizer for Pickering emulsions is related to the interfacial tension of liquid-liquid interfaces and liquid-solid interfaces and whether GO and GQDs can be adsorbed onto the liquid-liquid interfaces thermodynamically. All of the size, ionic strength, pH and structure designing have an effect on the liquid-solid interfacial tension. Hence, monomer polarity can decide the liquid-liquid and liquid-solid interfacial tension. The GO and GQDs can be modified by modification, reduction and other chemical methods, which can endow the polymer with excellent properties such as conductivity, thermal conductivity and magnetic responsivity. At last, the propects of GO and GQDs stabilizing Pickering emulsion are proposed.

Contents
1 Introduction
2 Graphene oxide
2.1 The preparation of GO
2.2 The structure of GO
2.3 Research progress of GO as Pickering emulsion stabilizer
3 Graphene quantum dots
3.1 The preparation of GQDs
3.2 The structure of GQDs
3.3 Research progress of GQDs as Pickering emulsion stabilizer
4 Conclusion

Key words: graphene oxide, graphene quantum dots, polymer, amphiphilicity, Pickering emulsion

CLC Number: 

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