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Progress in Chemistry 2009, Vol. 21 Issue (0203): 282-287 Previous Articles   Next Articles

• Special issues •

Heterogeneous Reaction of NO2 on the Surface of Mineral Dust Particles

Zhang Zefeng; Zhu Tong**; Zhao Defeng; Li Hongjun   

  1. (State Key Laboratory for Environmental Simulation and Pollution Control ,College of Environmental Science and Engineering , Peking University , Beijing 100871 , China)
  • Received: Online: Published:
  • Contact: Zhu Tong E-mail:tzhu@pku.edu.cn
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Heterogeneous reaction of NO2 on the surface of mineral dust particles could change the chemical composition, size, morphology, and hygroscopic properties of mineral dust particles, and hence their optical properties and cloud nucleation. Therefore, the heterogeneous reaction of NO2 on the surface of mineral dust particles will result in the changes of direct and indirect radiative forcing of mineral dust particles, and significantly impact on the atmospheric oxidizing capacity and climate change. This paper introduces the methodology and reaction systems used to study the heterogeneous reactions of reactive gases on particles, describes the findings of the heterogeneous reaction products and mechanisms of NO2 on the surfaces of oxide particles, summarizes literature of reported uptake coefficients of NO2 reaction on the surface of mineral dust particles, and discuss scientific questions about the reaction that needs further research.

Contents
1 Reaction systems and methodology
2 Reaction products and mechanism
2.1 Heterogeneous reaction of NO2 on the surface of SiO2 particles
2.2 Heterogeneous reaction of NO2 on the surface of Al2O3 particles
3 Uptake coefficients
4 Scientific questions need further research

Key words: uptake coefficients, reaction mechanism, mineral dust particles

CLC Number: 

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