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Progress in Chemistry 2017, Vol. 29 Issue (8): 846-858 DOI: 10.7536/PC170543 Previous Articles   Next Articles

• Review •

All-Solid-State Z-Scheme Photocatalytic Systems Based on Silver-Containing Semiconductor Materials

Ming Ge1,2*, Zhenlu Li1   

  1. 1. College of Chemical Engineering, North China University of Science and Technology, Tangshan 063210, China;
    2. Hebei Key Laboratory of Photocatalytic and Electrocatalytic Materials for Environment, Tangshan 063210, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the Youth Foundation of Hebei Education Department (No. QN2017115, QN2014045) and the National Natural Science Foundation of China (No. 51504079).
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Photocatalytic technology based on semiconductor materials is expected to use clean solar energy to control the environmental pollution and ease the energy shortages.In recent years, some silver-containing semiconductor materials with narrow band gap exhibit excellent oxidation and reduction ability under visible light irradiation, hence, silver-containing photocatalysts have become one of the focuses in the field of photocatalytic materials. Single silver-containing photocatalytic materials have high cost and poor stability, which limit their practical applications. As a result, the composite photocatalytic materials have been widely studied. Recently, simulating the photosynthesis process of green plants, all-solid-state Z-scheme photocatalytic systems are established, which can enhance the stability and reduce the cost of silver-containing photocatalytic materials as well as improve their photocatalytic performances. In this paper, we firstly describes the derivation and reaction mechanism about the all-solid-state Z-scheme photocatalytic systems, and then reviews the construction, application and reaction mechanism of silver-containing semiconductor materials-based all-solid-state Z-scheme photocatalytic systems so far.At last, we point out some existing problems about these silver-containing semiconductor materials-based Z-scheme photocatalytic systems, and their research prospects are also proposed.
Contents
1 Introduction
2 The derivation and reaction mechanism of all-solid-state Z-scheme photocatalytic systems
3 The research findings of silver-containing semiconductor materials-based Z-scheme
photocatalytic systems
3.1 AgX-based Z-scheme photocatalytic systems
3.2 Ag3PO4-based Z-scheme photocatalytic systems
3.3 Ag2CO3-based Z-scheme photocatalytic systems
3.4 Ag2MO4-based Z-scheme photocatalytic system
4 Conclusion
Key words: silver-containing materials, visible light, Z-scheme system, photocatalytic application, reaction mechanism

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