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  • Review article
    Jizhi Ai, Siyuan Li, Change Wu, Shuanjin Wang, Yuezhong Meng
    Progress in Chemistry. https://doi.org/10.7536/PC240615
    Accepted: 2025-04-30

    The rapid development of biodegradable plastics manufactured by chemical and biological processes, including the use of enzymes and microorganisms, makes it possible to reduce "white pollution" in specific areas by substituting biodegradable plastics with non-biodegradable ones. One type of one-dimensional material is fiber material, which is created by processing regular material in a particular way. The use of biodegradable materials in textiles, bio-medicine, and fiber-reinforced composites is extremely important. This paper reviews the biodegradable mechanism of materials, methods of manufacturing for biodegradable synthetic fiber, research status, and composite materials made of biodegradable synthetic fiber. It also describes the spinning molding techniques of materials and explains the relationship that some biodegradable plastics have with conventional fiber molding techniques. The challenges and prospects in the development of biodegradable synthetic fiber materials are also pointed out.

    Contents

    1 Introduction

    2 Biodegradable mechanism

    3 Method for preparing biodegradable synthetic fibers

    3.1 Melt spinning

    3.2 Solvent spinning

    3.3 Electrostatic spinning

    3.4 Centrifugal spinning

    4 Research status of biodegradable synthetic fibers

    4.1 PLA fiber

    4.2 PGA fiber

    4.3 PHA fiber

    4.4 PBAT fiber

    4.5 PCL fiber

    4.6 PBS fiber

    5 Biodegradable fiber composite materials

    6 Conclusion and outlook

  • Review article
    Xin Chen, Jingzhao Wang, Xiangming Cui, Mi Zhou, Jianan Wang, Wei Yan
    Progress in Chemistry. https://doi.org/10.7536/PC240713
    Accepted: 2025-04-30

    Li-S batteries have great application prospects because of their extremely high capacity and energy density. However, the instability and insulation of polysulfides (LiPSs) seriously hinder their further application. In order to solve the problem of slow reaction kinetics in Li-S batteries, it is urgent to explore efficient catalysts to accelerate the sulfur redox. In the case, transition metals with unique and excellent catalytic properties are considered as potential catalysts for Li-S battery. However, differences in the structure and properties of transition metals will lead to different catalytic mechanisms. Therefore, this work divides five types of transition metals (ferrous metals, conventional non-ferrous metals, precious metals, rare refractory metals, and rare earth metals) based on metal characteristics. Then, the catalytic mechanisms of transition metal catalysts were analyzed, including adsorption, accelerating electron transfer, reducing activation energy and co-catalysis. Besides, the research progress of various metals used in Li-S batteries was reviewed, and the catalytic mechanisms of different types of metals were clarified. Four optimization strategies were proposed: nanostructured design, doping-modification, alloying and external cladding, in order to provide certain references for the design of Li-S battery catalysts.

    Contents

    1 Introduction

    2 Catalytic mechanism and functionality of transition metal catalysts

    2.1 Catalytic mechanism

    2.2 Functionality

    3 The Application of transition metals in lithium sulfur batteries

    3.1 Ferrous metal

    3.2 Non-ferrous metal

    3.3 Noble metal

    3.4 Rare refractory metal

    3.5 Rare earth metal

    4 Challenges and optimization strategies of transition metal catalysts

    5 Conclusion and outlook

  • Review article
    Zhengru Hu, Wen Lei, Wei Wang, Wangwang Yu
    Progress in Chemistry. https://doi.org/10.7536/PC240611
    Accepted: 2025-04-30

    With the rapid development and increasing maturity of photopolymerization-based 3D printing technology, the market demand for photopolymer resins has become increasingly diverse and refined, driving the research and development of multifunctional photopolymer resins. The aim is to expand the application scope of photopolymer resins, particularly in the fields of high-performance and intelligent materials. As an emerging research direction, self-healing 3D-printed polymer materials have garnered significant attention from researchers in recent years. In this article, the latest progress in both intrinsic self-healing polymer materials based on mechanisms such as hydrogen bonding, disulfide bonds, coordinate bonds, and host-guest interactions and extrinsic self-healing polymer materials, such as those utilizing microcapsules and hollow fibers is reviewed. Different repair mechanisms of intrinsic and extrinsic systems are explored, with a focus on analyzing their application in the field of 3D printing. Currently, research on self-healing 3D-printed polymer materials is mainly concentrated on intrinsic self-healing materials. For rigid solid polymer materials requiring 3D printing and self-healing capabilities, extrinsic self-healing methods, mainly microcapsule-based and microvascular network-based self-healing approaches, are still required.

    Contents

    1 Introduction

    2. Intrinsic self-healing

    2.1 Hydrogen bond based self-healing

    2.2 Coordinate bond based self-healing

    2.3 Host-guest interaction based self-healing

    2.4 Diels-Alder rection based self-healing

    2.5 Hydrazone bond based self-healing

    2.6 Disulfide bond based self-healing

    3. Extrinsic self-healing
    3.1 Microcapsule type self-healing material

    3.1 Microvascular type self-healing material

    4 Conclusion and outlook

  • Review article
    Xiushuang Jiang, Junming Wang, Hongzhi Liu
    Progress in Chemistry. https://doi.org/10.7536/PC240612
    Accepted: 2025-04-30

    With the improvement of living standard and heightened awareness of environmental protection, renewable and environmentally friendly cellulose materials have attracted much attention in the field of daytime radiative cooling due to their high mid-infrared emissivity and the advantages of tunability of hierarchical structure. In this review, the classification, advantages/disadvantages of radiative cooling materials, the principles of radiative cooling, and the factors influencing their performance are introduced. The classification, state of the art as well as radiative cooling properties of cellulose-based daytime radiative cooling materials are elaborated. The recent progress in the four main application areas including building thermal management, personal thermal management, photovoltaics and low-temperature storage/transportation are summarized. Finally, the existing challenges in the current research are discussed and the future development in this field is also envisaged.

    Contents

    1 Introduction

    2 Radiative cooling

    2.1 Principles

    2.2 Influencing factors

    3 Cellulose-based daytime radiative cooling materials and classification

    3.1 Natural cellulose-based materials

    3.2 Cellulose derivatives-based materials

    3.3 Bacterial cellulose-based materials

    4 Application fields

    4.1 Building thermal management

    4.2 Personal thermal management

    4.3 Photovoltaics

    4.4 Low-temperature storage/transportation

    5 Conclusion and outlook

  • Review article
    Ji Liu, Yaochun Yao, Shaoze Zhang, Keyu Zhang, Changjun Peng, Honglai Liu
    Progress in Chemistry. https://doi.org/10.7536/PC240614
    Accepted: 2025-04-30

    Lithium metal batteries (LMBs) have emerged as a focal point for next-generation battery technology research due to their high energy density. However, the commercialization of lithium-metal batteries is hindered by a series of challenges, including lithium dendrite formation, volumetric expansion, and the rupture of the solid electrolyte interphase (SEI). Ionic liquids (ILs) are emerging as key candidate materials to address these issues due to their unique physical and chemical properties. Despite the significant potential of ionic liquids in lithium-metal batteries, several pressing issues, such as high costs and high viscosity, need to be addressed. Future research should focus on developing new low-cost, high-performance ionic liquids and further understanding their mechanisms in batteries. Additionally, combining advanced characterization techniques and theoretical calculations to explore the dynamic behavior and interfacial phenomena of ionic liquids in lithium metal batteries will help advance their practical applications. This review summarizes the safety issues involved in the research and development of lithium metal batteries, as well as the research progress of ionic liquids in their application as electrolytes and solid electrolytes in lithium metal batteries.

  • Review article
    Jiansong Liu, Guida Pan, Feng Zhang, Wei Gao, Juntao Tang, Guipeng Yu
    Progress in Chemistry. https://doi.org/10.7536/PC240705
    Accepted: 2025-04-30

    In recent years, covalent organic frameworks (COFs) have emerged as focal points in the research of membrane materials. Distinguished by their distinctive porous structures and structural versatility, COFs offer a promising avenue for advancement in membrane applications compared to conventional polymeric materials. This article delves into diverse interfacial systems, systematically detailing the methodologies for fabricating high-performance COF membranes via interfacial polymerization. The mechanisms underlying membrane formation across various interfacial systems and the strategies for precisely controlling the membrane structure will be elucidated. Furthermore, the intricate relationship between the membrane structure and application performance will be summarized. The challenges and perspectives in this field will be highlighted in the last part of this review.

    Contents

    1 Introduction

    2 Gas/liquid interface polymerization

    2.1 Langmuir-Blodgett method

    2.2 Surfactant-mediated

    3 Liquid/liquid interface polymerization

    3.1 Regulation of the system

    3.2 Additive-mediated

    3.3 Optimizing synthetic conditions

    4 Liquid/solid interface polymerization

    5 Solid/gas interface polymerization

    6 Applications of COF membrane

    6.1 Water resource treatment

    6.2 Gas separation and storage

    6.3 Membrane catalysis

    6.4 Electric device

    7 Conclusion and outlook

  • Review article
    Mingxia Feng, Jintian Qian, Dawu Lv, Wenfeng Shen, Weijie Song, Ruiqin Tan
    Progress in Chemistry. https://doi.org/10.7536/PC240704
    Accepted: 2025-04-30

    Human exhaled air has a close relationship with diseases, among which ammonia becomes a respiratory marker for diseases such as kidney disease. Traditional exhaled gas detection methods are mainly detected by gas chromatography, but the instrument is bulky and complex in operation. Emerging ammonia sensors, however, are garnering significant attention due to their portability, ease of integration, miniaturization, low cost, and simplicity of operation. This review systematically describes the working mechanism of ammonia gas sensors, sensor types, and common ammonia sensing materials. At the same time, it introduces the advantages of sensor array electronic nose technology over a single sensor, and puts forward the application research of ammonia sensors and electronic noses in diseases, aiming at the existing problems and future prospects of ammonia gas sensors.

    Contents

    1 Introduction

    2 Principe of semiconductor ammonia sensor

    2.1 Quartz crystal microbalance ammonia sensor

    2.2 Electrochemical ammonia sensor

    2.3 Colorimetric ammonia sensor

    2.4 Resistive ammonia sensor

    3 Resistive ammonia sensing gas sensitive material

    3.1 Metallic oxide

    3.2 Conducting polymer

    3.3 Carbon material

    3.4 2D material

    4 E-nose based on ammonia sensing

    4.1 Eigenvalue extraction

    4.2 Classical pattern recognition algorithm

    4.3 Neural network

    5 Applications of ammonia sensors in different diseases

    5.1 Application of ammonia sensor in chronic kidney disease

    5.2 Application of ammonia sensor in helicobacter pylori positive patients

    6 Conclusion and outlook

  • Review article
    Zhaoxia Lai, Runqi Fan, Xue Wang, Shusheng Zhang, Ting Qiu, Chenguo Feng
    Progress in Chemistry. https://doi.org/10.7536/PC20250103
    Accepted: 2025-04-30

    Organometallic compounds can undergo intramolecular C-H activation to form cyclometallic species, which can then undergo selective ring-opening to enable a “through space” migration of the metal atom within the molecule. Compared to the widely studied heteroatom-directed C-H activation reactions, this process is more complex and difficult to control. Over the past decade, significant progress has been made in this area, providing powerful new tools for the functionalization of remote C-H bonds. The aryl-to-vinylic 1,4-palladium migration represents one of the most significant research area in this field. Although it faces challenges, including the migration of palladium to the thermodynamically less stable vinyl position and the inherent diverse reactivity of alkenes, it provides a novel strategy for the highly stereoselective synthesis of polysubstituted alkenes. Owing to its considerable academic and practical significance, this method has garnered widespread attention.

    This review summarizes the key mechanisms of aryl-to-vinylic 1,4-palladium migration, various transformation reactions, and potential synthetic applications. Finally, the challenges encountered in this field and prospects for future development are discussed.

    Contents

    1 Introduction

    2 Palladium migration followed by reaction with C(sp2) coupling reagents

    2.1 Alkenyl coupling partners

    2.2 Aryl coupling partners

    2.3 Diazo coupling partners

    2.4 Carbonylation partners

    3 Palladium migration followed by reaction with C(sp3) coupling reagents

    4 Palladium migration followed by reaction with C(sp) coupling reagents

    5 Palladium migration followed by reaction with heteroatom coupling reagents

    6 Conclusion and outlook

  • Original article
    Guichu Yue, Yaqiong Wang, Jie Bai, Yong Zhao, Zhimin Cui
    Progress in Chemistry. https://doi.org/10.7536/PC241004
    Accepted: 2025-03-19

    Using catalytic processes to convert CO2 into low-carbon fuels and fine chemicals is one of the most efficient paths to addressing global energy imbalance and CO2 excess emissions. The advantages of one-dimensional nanocatalysts in long-range electron transport and controllable internal structure endow them with widely utilization in catalysis. Electrospinning, a top-down method for fabrication of fibers, offers unique advantages in regulating fiber composition and structure. This paper systematically reviews the designing strategies and application advancements of fiber catalysts based on electrospinning, including fully controllable synthesis strategies for multilevel structured fibers, methods for introducing active sites via one-step and post-load techniques, and research case of fiber catalysts in CO2 conversion. This review provides valuable references for the development of new concepts, methods, processes, and applications of fiber catalysts for CO2 conversion.

    Contents

    1 Introduction

    2 Electrospinning in designing of fiber catalysts

    2.1 Electrospinning

    2.2 Designing of fiber structures

    2.3 Introducing of active sites

    3 Applications of fiber catalysts in CO2 conversion

    3.1 Photocatalytic CO2 conversion

    3.2 Electrocatalytic CO2 conversion

    3.3 Thermocatalytic CO2 conversion

    4 Conclusion and outlook

  • Original article
    Guang Yang, Demei Yu
    Progress in Chemistry. https://doi.org/10.7536/PC241001
    Accepted: 2025-03-19

    With the advancement of technology, flexible pressure sensors have been widely utilized in wearable device fields such as medical monitoring and motion monitoring, primarily due to their thinness, lightness, flexibility, good ductility, as well as their faster response speed and higher sensitivity compared to traditional rigid sensors. When subjected to external forces, the elastic elements within these sensors undergo deformation, converting mechanical signals into electrical signals. Consequently, the choice of elastic elements significantly impacts the overall performance of flexible pressure sensors. Polydimethylsiloxane (PDMS) is extensively used as a flexible substrate in sensors because of its stable chemical properties, good thermal stability, low preparation cost, and excellent biocompatibility. By collecting relevant information, this paper reviews the sensing mechanisms of PDMS-based flexible pressure sensors, introduces preparation techniques to improve the properties of PDMS materials, including the recently popular methods of introducing porous structures and constructing surface architectures, and discusses the applications of PDMS-based flexible pressure sensors in medical monitoring, electronic skin, and other fields. Finally, the challenges faced by PDMS-based flexible sensors and their future opportunities are prospected.

    Contents

    1 Introduction

    2 Flexible pressure sensor

    3 Fabrication technology of flexible sensor with improved performance

    3.1 Pore structure

    3.2 Surface Micro-Nano Structures

    4 Application of flexible pressure sensor based on PDMS

    4.1 Health monitoring

    4.2 Electronic skin

    5 Conclusion and outlook

  • Original article
    Ting Ma, Chunyu Deng, Jie Li, Zhouyu Wang, Qian Zhou, Xiaoqi Yu
    Progress in Chemistry. https://doi.org/10.7536/PC240815
    Accepted: 2025-03-19

    ONOO, produced by the diffusion-controlled reaction of nitric oxide and superoxide radicals, is a strong oxidizing and nitrating agent that causes damage to DNA, proteins, and other biomolecules in cells. Since ONOO is characterized by its short lifetime, high reactivity, and low concentration under physiological conditions, and the pathophysiological roles it plays in biological systems are not yet fully understood, it is of great significance to develop highly sensitive and selective detection technologies to achieve real-time dynamic monitoring of ONOO. In this paper, we review the research progress of ONOO fluorescent probes in disease-related processes in the recent 5 years, revealing the potential role of ONOO in various diseases, such as inflammation, tumors, liver injury, and brain diseases. Finally, the bottlenecks in the development of ONOO probes and future trends are discussed, which will promote the application of ONOO probes in chemistry, biology, and pharmacology.

    Contents

    1 Introduction

    2 Design strategy of ONOO fluorescent probe

    3 Detection and imaging of ONOO by fluorescent probes in disease-related processes

    3.1 Detection and imaging of ONOO in inflammation

    3.2 Detection and imaging of ONOO in tumors

    3.3 Detection and imaging of ONOO in Liver Injuries

    3.4 Detection and Imaging of ONOO in Brain diseases

    3.5 Detection and imaging of ONOO in other disease models

    4 Conclusion and outlook

  • Original article
    Jianyu Wang, Shuai Wang, Chuanjie Fang, Baoku Zhu, Liping Zhu
    Progress in Chemistry. https://doi.org/10.7536/PC240802
    Accepted: 2025-03-19

    Two-dimensional nanochannel membrane is a new membrane composed of two-dimensional nanosheets with atomic layer thickness and stacked by self-assembly. Compared with traditional separation membranes, its ion separation behavior has many unique characteristics, and has important application potential in seawater desalination, energy storage and conversion, rare element extraction and separation, and other fields. These materials have attracted great interest and wide attention of researchers. It has become an important development direction and research hotspot in the field of membrane separation science and technology in recent years. In this paper, the construction strategy, performance evaluation method and mass transfer mechanism of two-dimensional nanochannel membranes were systematically summarized from the perspective of two-dimensional nanochannel membranes used for accurate ion sieving. The latest research progress in the preparation and application of two-dimensional nanochannel membranes in recent years was reviewed, and the development trend was prospected. We hope this review can provide enlightenments for structure design and optimization, performance enhancement, large-scale preparation and engineering applications of two-dimensional nanochannel membrane in the future.

    Contents

    1. Introduction

    2. Two-dimensional nanochannel ion sieving membrane and its construction methods

    2.1 Two-dimensional nanochannel ion screening membrane

    2.2 Construction method of 2D nanochannel ion sieving membrane

    2.3 Characterization of structure and evaluation of properties of two-dimensional nanochannel ion sieving membranes

    3. Mass transfer mechanism in two-dimensional nanochannels

    3.1 Mass transfer mechanism of solvent in two-dimensional channels

    3.2 Mass transfer mechanism of ions in two-dimensional channels

    4. Application of two-dimensional nanochannel ion sieving membrane

    4.1 Desalination of seawater

    4.2 Energy conversion and storage

    4.3 Extraction and separation of elements

    5. Conclusion and outlook

  • Original article
    Jiajia Jiang, Junhu Zhao, Qin Yu, Tian Zhang
    Progress in Chemistry. https://doi.org/10.7536/PC240608
    Accepted: 2025-03-19

    The sustained development of industry has brought enormous economic benefits, but it has also caused great harm to the environment. The excessive CO2 emissions from fossil fuel combustion are released into the natural environment, posing a threat to the environment and human health. So people are working hard to develop materials that can effectively capture CO2. At present, CO2 capture mainly occurs after the combustion of fossil fuels. According to the design standards for CO2 adsorbents, a variety of CO2 capture materials have been designed and developed, including solid adsorbents, liquid adsorbents, and multiphase adsorbents. The adsorption mechanisms of various adsorbents are also different, including adsorption, absorption, or a combination of both mechanisms.This review focuses on the capture performance, absorption mechanism, advantages and disadvantages of various common types of current adsorbents, and introduces amine solution absorbents, zeolite-based adsorbents, ionic liquids-based adsorbents, carbon-based adsorbents, metal-organic framework materials, covalent organic framework materials, metal-oxide materials, and biopolymer nanocomposites, respectively, with an outlook of the future development of CO2 adsorbent materials.

    Contents

    1 Introduction

    1.1 Current status and hazards of CO2 emissions

    1.2 CO2 capture technology

    1.3 Criteria for designing CO2 capture materials

    2 CO2 capture materials

    2.1 Amine solution absorbents

    2.2 Zeolites based adsorbents

    2.3 Ionic liquids absorbents(ILs)

    2.4 Carbon-based adsorbents

    2.5 Metal organic framworks(MOF)

    2.6 Covalent organic frameworks(COF)

    2.7 Metal oxide sorbents

    2.8 Biopolymeric nanocomposites

    3 Comparison and Prospect of Capture Materials

    4 Conclusion

  • Original article
    Wuyuxin Zhu, Linjun Qin, Guorui Liu
    Progress in Chemistry. https://doi.org/10.7536/PC240606
    Accepted: 2025-03-19

    Polyphenolic compounds are a class of naturally occurring bioactive substances widely found in environment. Their characteristics, such as low toxicity, low cost, and broad availability, make them become to be widely used chelating agents, reducing agents and capping agents for treating typical pollutants in water. Currently, polyphenols are extensively used in advanced oxidation processes (AOPs) through the coupling of common transition metal ions and peroxides. However, the chemical mechanisms of polyphenolic substances in water pollution remediation still lack systematic conclusions. This study reviews and summarizes the compositions of homogeneous and heterogeneous systems containing polyphenolic compounds, as well as the pro-oxidant, antioxidant, and chelating-reduction effects exhibited by polyphenols within these systems. It explains the main active species generated by polyphenolic substances under different systems from both radical and non-radical perspectives, along with the corresponding mechanisms for the removal of water pollutants. The dual role of polyphenols as natural redox mediators (RMs) in constructing complex catalytic systems is emphasized, and the effects of external energies such as light, heat, electricity, ultrasound, and plasma on the reaction mechanisms and pollutant degradation effectiveness in these systems are described. Finally, the article looks ahead to the future development directions of polyphenolic compounds in the field of water treatment.

    Contents

    1 Introduction

    2 H2O2/PS/PAA activation

    2.1 ROS of H2O2/PS/PAA

    2.2 Polyphenols/Fe(Cu) ions/peroxide systems

    2.3 Chelation and reduction of polyphenol-metal ions

    2.4 Non-radical reactions

    3 High-valent metal species

    3.1 Fe ions

    3.2 Cu ions

    3.3 Mn ions

    4 Solid catalyst

    4.1 Zero-valent metal monomers

    4.2 Monometallic compounds

    4.3 Polymetallic compounds

    4.4 Metal-organic complexes

    4.5 Carbon-based materials

    4.6 Inorganic salt supported metal catalysts

    5 Polyphenol-SQ•--Quinone

    5.1 Periodate and permanganate

    5.2 Peroxide

    5.3 O2, H2O and others

    5.4 Redox mediators

    6 External energy

    7 Conclusion and outlook

  • Original article
    Saiqun Nie, Pengcheng Xiao, Jiayao Chen, Fuli Luo, Tian Zhao, Yi Chen
    Progress in Chemistry. https://doi.org/10.7536/PC240523
    Accepted: 2025-03-19

    Due to HKUST-1 has ultra-high specific surface area and porosity, excellent thermal stability, and adjustable structure and function, HKUST-1 is one of the most widely studied MOFs. The HKUST-1-based composites have achieved excellent multi-component properties and demonstrated new physical and chemical properties, which have a significant impact on their applications. The structural characteristics and physicochemical properties of HKUST-1 and HKUST-1-based composites make them have broad application prospects in gas storage, gas adsorption, catalysis, drug delivery and release sensing and photodegradation. This article focuses on the application progress of HKUST-1 and HKUST-1-based composites in various fields in recent years, and finally looks forward to the research on HKUST-1-based composites.

  • Jia-Cheng Yu, Hao Su, Jun Zhang, Gang Xie, Ming Yao, Jin Qu
    Progress in Chemistry. https://doi.org/10.7536/PC240726
    Accepted: 2025-03-05
    Lithium-sulfur batteries are valued for their high theoretical specific capacity, energy density, and other advantages, but their commercialization is limited by the slow kinetics of sulfur species conversion and the "shuttle effect". In response, researchers have utilized the photocatalytic effect to develop a photo-assisted strategy for lithium-sulfur batteries, an emerging strategy that not only improves the adsorption and catalytic performance of the catalyst, but also enhances the battery performance in terms of both thermodynamics and kinetics, and even achieves the storage and release of solar energy through the photo-charging mechanism. In this paper, based on recently relevant studies, we introduce in detail the photoelectrochemical principles of photo-assisted lithium-sulfur batteries, discuss the design strategies of photocatalysts and photoanode, as well as the selection of optical windows and encapsulation materials, and review the typical configurations of photopositives and the research methodology of photo-assisted lithium-sulfur batteries, with the aim of attracting the extensive attention of our peers and providing references for the in-depth understanding and improvement of photo-assisted lithium-sulfur batteries.
  • Chaoyang Wu, Chao Wang, Feifan Chen, Xinhe Dong, Haiying Zheng
    Progress in Chemistry. https://doi.org/10.7536/PC240618
    Accepted: 2025-03-05
    Two-dimensional (2D) perovskite materials have been receiving considerable attention owing to their high stability. Despite this, there is still significant potential for improving their power conversion efficiency. Designing effective spacer cations is one of the crucial method to improve the photoelectric performance of 2D perovskite solar cells. Among the various strategies, halogen substitution has emerged as a particularly effective approach, which can fine-tune the stability and optical properties of the perovskite crystal structure, leading to notable improvements in photoelectric conversion efficiency as well as long-term stability. In recent years, there has been significant and notable progress of two-dimensional (2D) perovskites based on various halogen-substituted spacer cations in the preparation of high-performance perovskite solar cells. This paper initially provides a comprehensive overview of the development status of 2D perovskite materials and devices that employ different spacer cations. Following this, the focus shifts to an in-depth review of the advancements made in the fabrication of 2D perovskite solar cells (PSCs) and the surface modification of three-dimensional (3D) perovskites, specifically emphasizing the role of spacer cations that have been singly or multiply substituted with halogens such as fluorine, chlorine, and bromine. Finally, we present a concise discussion on the current challenges faced in this field and offer insights into the potential future directions for further research and development.
  • Zongxing Wang, Yue Zhang, Pengcheng Zhao, Yifei Wang, Ce Nan, Zhiyue Zhang
    Progress in Chemistry. https://doi.org/10.7536/PC240526
    Accepted: 2025-03-05
    Eu-Tb lanthanide bimetallic organic frameworks (Ln-BMOFs) are inorganic organic hybrid materials with periodic network structure and functional diversification, which are composed of lanthanide Eu-Tb as the center and organic ligands. It has unique luminescence characteristics, especially sharp absorption, and large Stokes displacement, which makes it exhibit excellent performance in the field of fluorescence sensing. By adjusting the ratio of Eu and Tb in MOFs, we can obtain a series of EuxTb1-x doped MOFs with different luminous colors, and containing different proportions of Eu and Tb, which have similar or different luminous sensing mechanisms. Since the Eu-Tb lanthanide bimetallic organic frameworks has important research value in the field of fluorescence sensing, this paper will comprehensively and systematically review the research progress of lanthanide bimetallic organic frameworks from the aspects of background, sensing mechanism and application of fluorescence sensing.
  • Mingxia Zhang, Heng Zhang, Anguo Ying
    Progress in Chemistry. https://doi.org/10.7536/PC240720
    Accepted: 2025-02-25
    In recent years, Pickering emulsions have attracted substantial attention owing to their facile preparation and superior stability. Characterized by solid-particle stabilization, these emulsions distinguish themselves from surfactant-stabilized emulsions through heightened stability, diminished toxicity, and stimulus-responsiveness. Solid particles, acting as the core part of the emulsion system, play an important role in the preparation and application of Pickering emulsions. Here, this review concentrates on the impact of various single stimulus responses (pH, temperature, carbon dioxide, redox, light irradiation, magnetic fields) and multiplexed stimulus responses on the stability and performance of Pickering emulsion systems. Additionally, it highlights the latest research and advancements concerning the application of Pickering emulsion systems in a multitude of reactions, such as oxidation, reduction reaction, hydrolysis reaction, condensation reaction, esterification transesterification reaction, and cascade reaction.
  • Yinyan Guan, Xiaorui Hao, Rui Xu, Hongfei Li, Yuhan Wu, Jiyan Liang
    Progress in Chemistry. https://doi.org/10.7536/PC240610
    Accepted: 2025-02-25
    Zinc-iodine batteries have attracted widespread attention as a novel green, low-cost, and highly safe electrochemical energy storage technology. Its basic principle is to use the electrochemical reaction between zinc and iodine to store and release energy. However, the low electronic conductivity, shuttle effect, and high solubility of iodine limit the practical application of zinc-iodine batteries. This work provides a systematic review of the research progress on carbon materials used in the cathode of zinc-iodine batteries, with a focus on several commonly used carbon materials, such as carbon nanotubes, graphene, activated carbon, biomass-derived carbon, and other porous carbon materials. Owing to their excellent conductivity, high specific surface area, and good chemical stability, these carbon materials can not only effectively adsorb and immobilize iodine molecules, preventing iodine loss and the shuttle effect, but also promote iodine redox reactions by regulating the pore structure and surface chemical properties, thereby improving the specific capacity and cycling stability of the battery. Additionally, we put forward the challenges and issues faced by carbon materials in the practical application of zinc-iodine batteries, including how to further enhance iodine adsorption capability and improve the structural stability of the electrode. Accordingly, several potential future research directions are proposed with a view to further improving the electrochemical performance and reducing the manufacturing cost, thus laying the foundation for advancing the development and application of this emerging battery technology.
    Contents
    1 Introduction
    1.1 Research background and significance of zinc-iodine batteries
    1.2 The importance of carbon materials in zinc-iodine batteries
    2 Overview of zinc-iodine batteries
    2.1 Reaction mechanism of zinc-iodine batteries
    2.2 Advantages and problems of zinc-iodine batteries
    3 The application of carbon materials in the cathode of zinc-iodine batteries
    3.1 Carbon nanotube-based cathodes
    3.2 Graphene-based cathodes
    3.3 Activated carbon-based cathodes
    3.4 Biomass-derived carbon-based cathodes
    3.5 Other porous carbon material-based cathodes
    4 Conclusions and outlook
  • Original article
    Jiawen Dai, Chunlin Xie, Rui Zhang, Huanhuan Li, Haiyan Wang
    Progress in Chemistry. https://doi.org/10.7536/PC240519
    Accepted: 2024-09-24

    Compared to lithium-ion batteries, sodium-ion batteries have greater advantages in terms of resources, cost, safety, power performance, low-temperature performance and so on. However, the energy density of sodium-ion batteries is relatively low. To explore broader application prospects, the development of high specific energy sodium batteries has become a research hotspot in both academia and industry. The anode is considered the key bottleneck constraining the development of the sodium battery industry due to limitations such as the inability of graphite to serve as sodium anodes and the high cost, low Coulombic efficiency, and poor kinetics of mainstream hard carbon materials. In recent years, anode-free sodium batteries (AFSBs) have garnered widespread attention due to their advantages in energy density, process safety, and overall battery cost. However, AFSBs generally show rapid capacity loss owing to the rupture of the solid-electrolyte interphase (SEI) layer, increased chemical side reactions, serious dendrite growth and the formation of dead sodium. As the AFSBs operate, active sodium is continuously consumed without additional metallic sodium to replenish it, leading to poor cycling performance and failure of AFSBs. These issues can be attributed to the following characteristics: the high reactivity of sodium, non-uniform nucleation and huge volume expansion. To elucidates the strategies of promoting dendrite-free growth on the anode side of AFSBs, this review focuses on the current collector-sodium interface and sodium-electrolyte interface, including the design of sodiophilic coatings, porous skeleton structure to regulate the sodium nucleation process, and the construction of robust SEI interface, which further guides the homogeneous sodium deposition and stripping process. This comprehensive review is expected to draw more attention to anode-free configurations and bring new inspiration to the design of high specific energy batteries.

    Contents

    1 Introduction

    2 Factors affecting sodium deposition on the anode side

    2.1 High reactivity of sodium

    2.2 Inhomogeneous sodium deposition

    2.3 Volumetric deformations

    3 Critical differences between sodium and lithium

    4 Interface design principles and strategies

    4.1 Design principles

    4.2 Homogeneous nucleation regulation at the current collector-sodium interface

    4.3 Formation of robust SEI at the sodium-electrolyte interface

    5 Conclusions and prospects

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