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Progress in Chemistry DOI: 10.7536/PC200441 Previous Articles   Next Articles

Research and Prospect of Selective Oxidation of HMF

Lili Cheng, Yun Zhang, Yekun Zhu, Ying Wu   

  1. Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China
  • Online: Published:
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    The work was supported by the Natural Science Foundation of Zhe jiang Province(No. LY16B030002)
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In recent years,the use of abundant and renewable biomass resources to prepare high value-added chemicals and liquid fuels is one of the hot spots in the chemical research field,which is in line with the national strategy of sustainable development. 5-hydroxymethylfurfural(HMF)is one of the key biomass platform compounds,widely used in the preparation of fine platform compounds,drug intermediates,polymer synthesis and liquid fuel precursor. Therefore,the selective oxidation of HMF has gradually become a research hotspot in the field of biomass. This paper mainly introduces the research on preparation of biomass derivatives such as DFF,FFCA and FDCA by selective oxidation of HMF in last five years,and the transformation of biomass with HMF as intermediate. The selective oxidation of HMF mainly focuses on two ways:thermalcatalytic and photocatalytic. Among them,the selective oxidation of HMF to DFF and FDCA by thermalcatalytic is widely studied. The catalytic system under this approach mainly introduces the noble metals and non-precious metals. In the few photocatalytic pathways,the main catalytic system is g-C3N4 catalyst. In addition,the deficiencies in there search on the oxidation of HMF are pointed out and the possible solutions are proposed.
Key words: cellulose, glucose, fructose, selective oxidation, HMF

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