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Progress in Chemistry 2022, Vol. 34 Issue (8): 1678-1687 DOI: 10.7536/PC210920 Previous Articles   Next Articles

• Review •

Selective Catalytic Reduction of NOx by Hydrogen over Noble Metal Catalysts

Bin Jia1,2, Xiaolei Liu1,2, Zhiming Liu1,2()   

  1. 1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology,Beijing 100029, China
    2 Beijing Center for Environmental Pollution Control and Resource Recovery, Beijing University of Chemical Technology,Beijing 100029, China
  • Received: Revised: Online: Published:
  • Contact: Zhiming Liu
  • Supported by:
    National Natural Science Foundation of China(21876009); Fundamental Research Funds for the Central Universities(JD2110)
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The control of NOx is very important for the air quality improvement. Selective catalytic reduction of NOx by hydrogen (H2-SCR) has attracted much attention as an efficient and environmentally benign deNOx technology. In this review, we summarize the research development in the H2-SCR of NOx over noble metal catalysts. The typical H2-SCR reaction mechanisms are introduced first. Then the factors affecting the H2-SCR performance of noble metal catalysts, such as the active metal, support type, the added promoter and the nature of active metal, and the structure-activity relationship have been discussed. Finally, the challenges and the prospects for future development of H2-SCR catalyst are proposed.

Contents

1 Introduction

2 The reaction mechanisms of H2-SCR

2.1 Redox mechanism

2.2 Adsorption/dissociation of NO

2.3 Bifunction mechanism

3 Noble metal H2-SCR catalyst

3.1 Effect of active metal

3.2 Effect of the support

3.3 Effects of the additives

3.4 Alloy catalyst

3.5 Single atom catalyst

4 Conclusion and perspective

Key words: nitrogen oxides, H2-SCR, noble metal catalyst, reaction mechanism
Fig. 1 Mechanism of surface diffusion reaction of H species on Pt/MgO-CeO2 catalyst[7]
Fig. 2 Schematic diagram of NO adsorption and dissociation over the Pt/La0.5Ce0.5MnO3 catalyst[14]
Fig. 3 Reaction scheme of H2-SCR of NOx on Pd/V2O5/TiO2-Al2O3 catalyst[15]
Fig. 4 Reaction routes of Pt/SSZ-13 catalyst at different temperatures[19]
Fig. 5 Reaction routes of Pt/h-ZSM-5 catalyst in the different ranges of temperature[18]
Fig. 6 Mechanism diagram of H2-SCR reaction on Pt-HY catalyst[20]
Fig. 7 Relationship between the TOF of NO and the Pd particle size[25]
Fig. 8 Scheme for the preparation of Pt/TiO2 catalyst using the sacrificial carbon layer strategy[27]
Fig. 9 Comparison of the activities of Pt/TiO2 and Pt/TiO2-M catalysts[27]
Fig. 10 Schematic illustration of the synthesis of MOF-derived porous Pt/ZrO2@C nano-octahedra[43]
Fig. 11 H2-SCR performance of Pt/HZSM-5 and Pt-W/HZSM-5 catalysts. Reaction conditions:[NO] = 1000 ppm, [H2] =5000 ppm, [O2] = 10%[48]
Fig. 12 HAADF-STEM images of (a)Pt-SAC and (b)Pt-nano catalysts[62]
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