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Progress in Chemistry 2016, Vol. 28 Issue (4): 401-414 DOI: 10.7536/PC151024 Previous Articles   Next Articles

• Review and comments •

Reactivity of Heteronuclear Oxide Clusters with Small Molecules

Zhao Yanxia, He Shenggui*   

  1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21325314, 21273247, 21303215, 21573247).
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Gas phase study of the chemical reactions between heteronuclear oxide clusters and small molecules permits to address the behavior of oxides composed of multiple components in catalytic reactions at a strictly molecular level. In this review, we summarize the recent progress in activation and transformation of small molecules by heteronuclear oxide clusters. The local charge, local spin, and structural effects on the reactivity of important reactive oxygen species are discussed. The novel reaction pathways and reaction mechanisms appearing after doping with noble metals are also presented.

Contents
1 Introduction
2 Reactivity of heteronuclear oxide clusters doping with non-noble metals
2.1 Tune the local charge on atomic oxygen radicals
2.2 Tune the local spin on atomic oxygen radicals
2.3 Tune the reactivity of peroxide ions
3 Reactivity of heteronuclear oxide clusters doping with noble metals
3.1 The promotion role of noble metal atoms
3.2 The dominant role of noble metal atoms
3.3 The single atom catalysis
4 Conclusion and outlook

Key words: atomic clusters, heteronuclear oxides, reactive oxygen species, noble metals, reaction mechanisms

CLC Number: 

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