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Progress in Chemistry 2016, Vol. 28 Issue (2/3): 375-390 DOI: 10.7536/PC150604 Previous Articles   Next Articles

• Review and comments •

Catalytic Oxidehydration of Glycerol to Acrylic Acid

Hua Donglong1, Zhuang Xiaoyu1, Tong Dongshen1, Yu Weihua1, Zhou Chunhui1,2*   

  1. 1. Institute for Advanced Catalytic Materials, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China;
    2. Institute for Agriculture and Environment, University of Southern Queensland, Toowoomba QLD 4350, Australia
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21373185) and the Distinguished Young Scholar Grants from the Natural Scientific Foundation of Zhejiang Province (No.R4100436).
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This article deals with the recent research and development on catalytic oxidehydration of glycerol into acrylic acid in a single reactor. The biorenewable glycerol as a platform chemical for the production of acrylic acid is introduced. The reaction parameters such as temperature, contact time, partial pressure of oxygen and glycerol concentration in the gas-solid systems and the liquid-solid systems are examined. The catalytic performances of oxide composites and molecular sieve-supported catalysts in a single-bed system and a double-bed gas-solid system are discussed. The catalysts include V-P, Fe-P, W-V, Mo-V, CsPW-Nb, VMo-SiC oxide composites, V2O5/BEA and V2O5/MFI. The postulated reaction mechanisms and probable side reactions in the gas-solid system are presented, followed by the discussion on the issues of catalyst deactivation and regeneration. Then the catalytic characteristics of Cu/SiO2-MnO2 and POM/Al2O3 catalysts and the reaction mechanism in the liquid-solid system are remarked. The problems and the prospects in the selection of catalytic system, the improvement of catalysts and the elimination of coking of catalysts are commented.

Contents
1 Introduction
2 Gas-solid catalytic reactions
2.1 Gas-solid catalytic reactions in a single-bed reactor
2.2 Gas-solid catalytic reactions in a double-bed reactor
2.3 Mechanism of gas-solid catalytic reactions
2.4 Deactivation and regeneration of catalysts
3 Liquid-solid catalytic reactions
3.1 Reaction conditions of liquid-solid catalytic reactions
3.2 Catalysts of liquid-solid catalytic reactions
3.3 Mechanism of liquid-solid catalytic reactions
4 Conclusion

Key words: glycerol, catalysts, dehydration, oxidation, acrylic acid, reaction mechanism

CLC Number: 

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