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Progress in Chemistry 2018, Vol. 30 Issue (8): 1242-1256 DOI: 10.7536/PC171013 Previous Articles   

• Review •

Perspective: Structures and Properties of Liquid Water

Chuang Yao1, Xi Zhang2*, Yongli Huang3, Lei Li1, Zengsheng Ma3, Changqing Sun1,4*   

  1. 1. Key Laboratory of Extraordinary Coordination Bond Engineering and Advanced Materials Technology(EBEAM) Chongqing Municipality, Yangtze Normal University, Chongqing 408100, China;
    2. Institute of Nanosurface Science and Engineering, Shenzhen University, Shenzhen 518060, China;
    3. School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China;
    4. School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798, Singapore
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the Science Challenge Project(No.TZ2016001), the National Natural Science Foundation of China(No. 11502223), the Hunan Natural Science Foundation of China(No. 2016JJ3119), and the Shenzhen Municipal Human Resources Fund(No. 827000131).
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The structure of liquid water particularly the number of bonds per water molecule has been a debating issue during 1933~1935 when Bernal, Fowler, and Pauling firstly proposed the scenario of proton "transitional quantum tunneling" in THz frequency at asymmetrical sites between two oxygen ions. Although conventions of the rigid or flexible dipole-dipole interaction, nanophase mixed amorphous structure or homogeneous fluctuating phase models, solute diffusion dynamics or hydration length scale premises have been becoming dominant, mysteries such as floating of ice, regelation of ice (compression melting), slipperiness of ice, fast cooling of warm water, etc. have yet to be resolved. The definition of hydrogen bond needs yet to be certain. In this perspective, we emphasize that it would be more efficient to transit the conventional "dipole-dipole" interaction to "hydrogen bond (O:H-O) asymmetrical, short-range, correlative" interaction, from the "proton translational tunneling" to "hydrogen bond cooperative relaxation". Progress also revealed that the O:H-O bond configuration and the numbers of protons and nonbonding electron lone pairs conserve and that water forms the tetrahedrally-coordinated, strongly correlated, fluctuating single liquid crystal. The O:H nonbond and the H-O bond segmental specific heat disparity derives a quasisolid phase between the liquid and the solid. With tunable boundaries, the quasisolid phase possesses the negative thermal expansion coefficient. Remarkably, molecular undercoordination results in a supersolid phase that is highly polarized, thermally stable, viscoelastic, and lesser dense. Extending hydrogen-bond knowledge to the energy storage-explosion reaction mechanics of energetic materials may further verify the comprehensiveness and universality of the current notion of hydrogen bond cooperativity-nonbonding interaction is ubiquitously important.
Contents
1 Introduction:challenges and opportunities
2 Strategies:manner of thinking
3 Principles:rules of conservation and prohibition
3.1 N number and O:H-O bond configuration conservation
3.2 Molecular orientation and proton tunneling prohibition
3.3 Water single crystal and O:H-O bond potential Path
3.4 O:H-O bond coorpertivity and ice water anomalies
4 Method:spectrometrics and analysis
5 Progress:mysteries resolution
5.1 Quasisolid cooling expansion:ice floating and density oscillation
5.2 Undercoordination supersolidity:slipperiness and skin hydorphobicity
5.3 O:H-O symmetrization:quasisolid phase boundary dispersion and regelation
5.4 Hot water cools faster:O:H-O bond memory and skin supersolidity
6 Conclusion:insight and perspective
Key words: hydrogen bond, temperature, coordination, pressure, phonon spectroscopy

CLC Number: 

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