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Progress in Chemistry 2016, Vol. 28 Issue (2/3): 232-243 DOI: 10.7536/PC150804 Previous Articles   Next Articles

• Review and comments •

Metal-Organic Frameworks for Catalytic Oxidation

Guo Ruimei, Bai Jinquan*, Zhang Heng, Xie Yabo, Li Jianrong*   

  1. Department of Chemistry and Chemical Engineering, Beijing University of Technology, Beijing 100124, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21271015, 21322601, U1407119).
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The use of metal-organic frameworks (MOFs) as heterogeneous catalyst for oxidation reactions developed in recent years is reviewed. Because of their unique structural features and outstanding physical/chemical properties, including metal or organic active sites in pore surface, high porosity, large surface areas, and tailorable pore properties, MOFs are promising and favorable for application in various catalytic reactions. In this review, the applications of MOFs in catalytic oxidation as catalysts or as supports of catalytic active species are discussed. Catalytic MOFs with coordinatively unsaturated metal active sites and MOFs supported metal nanoparticles (MNPs), polyoxometalates (POMs), and metalloporphyrins are emphasized. Catalytic oxidization of varieties of organic molecules, including alkanes, benzylic hydrocarbons, olefins, alcohols, phenols, and sulfur compounds, as well as small inorganic molecules, including CO and water in MOFs and/or MOFs supported catalysts are summarized. In addition, the application of MOFs in the oxidation of organic dyes and biomimetic catalysis is also discussed. Catalytic performances of these MOFs and MOFs supported catalysts are evaluated from the stability, heterogeneity, and shape/size selectivity, as well as precipitation of the active species aspects. Finally, the development trend of MOFs in the catalytic applications is prospected.

Contents
1 Introduction
2 Catalytic oxidation by MOFs
2.1 Oxidation of alkanes
2.2 Oxidation of benzylic hydrocarbons
2.3 Oxidation of olefins
2.4 Oxidation of alcohols
2.5 Oxidation of phenols
2.6 Oxidation of sulfur compounds
2.7 Photocatalytic oxidative degradation of organic dyes
2.8 Other oxidation reactions
3 Catalytic oxidation by MOFs supported catalysts
3.1 Oxidation of CO
3.2 Oxidation of H2O
3.3 Oxidation of olefins
3.4 Oxidation of alcohols
3.5 Oxidation of sulfur compounds
3.6 Other oxidation reactions
4 Conclusion and outlook

Key words: metal-organic frameworks (MOFs), heterogeneous catalyst, catalytic oxidation

CLC Number: 

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