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Progress in Chemistry 2015, Vol. 27 Issue (2/3): 174-191 DOI: 10.7536/PC140925 Previous Articles   Next Articles

• Review •

Advanced Functional Materials Derived from Metal-Organic Frameworks

Zhang Hui1, Zhou Yajing2, Song Xiaokai*1   

  1. 1. School of Chemical & Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, China;
    2. Changzhou Entry-Exit Inspection and Quarantine Bureau, Changzhou 213003, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21401083).

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Metal-organic frameworks (MOFs) are a class of crystalline coordination-based compounds in which metal ions (or metal clusters) are bridged via multitopic organic ligands to form infinite network structures. The organic ligands and metal clusters in the structures of MOFs could be served as carbon source and metal source, respectively. Fabrication of advanced functional materials from MOF precursors becomes one of the most popular research topics in MOFs chemistry and functional materials field. In this paper, the research progress of advanced functional materials derived from MOFs in recent years is reviewed. Synthesis methods of carbon materials (e.g. nanoporous carbon, carbon nanodots, carbon nanotubes), metal oxide nanomaterials (e.g. monometal oxide: Fe2O3, ZnO, Co3O4, MgO, In2O3, multimetal oxide nanocomposites: Gd2O3/Eu2O3, Fe2O3@TiO2), and metal oxide/carbon nanocomposites (e.g. Fe2O3/C, ZnO/C) derived from MOFs are introduced. The applications of these advanced functional materials in the fields such as supercapacitor, oxygen reduction reaction (ORR) catalyst, hydrogen storage, CO2 capture and photocatalyst of photocatalytic hydrogen production are presented. Besides, an outlook for future development of advanced functional materials derived from MOFs is given.

Contents
2 Synthesis methods and applications of advanced functional materials derived from MOFs
2.1 Carbon materials derived from MOFs
2.2 Metal oxide nanomaterials derived from MOFs
2.3 Metal oxide/carbon nanocomposites derived from MOFs
3 Conclusion

Key words: metal-organic frameworks (MOFs), precursor, porous carbon, metal oxide, composite

CLC Number: 

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