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Progress in Chemistry 2016, Vol. 28 Issue (9): 1289-1298 DOI: 10.7536/PC160418 Previous Articles   Next Articles

• Review and comments •

Capsid-Inspired Multi-Component Self-Assembly of Nanocontainers: Structure, Functionalization, and Applications

Zhang Guanglu1,2, Zhang Ting1, Zhou Lipeng1, Sun Qingfu1*   

  1. 1. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21402201).
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Inspired by the spontaneous self-assembly of hollow virus capsids and protein cages found in nature, a family of hollow spherical structure with general formula MnL2n can be obtained via the coordination-directed multi-component self-assembly of bent bis(pyridine) ligands and square-planar Pd2+ ions. Endo and exo-hedral functionalization of the nanocontainer complexes have been realized by introduction of functional groups into the organic ligands. Due to the nanoconcentrator effect, endo-functionalised spherical complex could be used not only for the template-synthesis of mono-dispersed polymers or nanoparticles, but also for the catalytic transformations of small substrates. Meanwhile, exo-functionalized complexes can selectively recognize a variety of substrates, such as oligonucleotides and DNA. The design principles, synthesis, characterization and functional applications of such nano-container molecules are summarized in this paper.

Contents
1 Introduction
2 Design and synthesis of the nano-containers
3 Functionalization and applications
3.1 Functional cavity
3.2 Functional surface
4 Conclusion and outlook

Key words: self-assembly, nano-containers, functionalization, application

CLC Number: 

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