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• Review •

Heavier Homologues of Transition Metal Carbynes: Syntheses, Structures and Reactivity

Wu Xian   

  1. Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany
  • Received: Revised: Online: Published:
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Transition metal silylynes, germylynes, stannylynes and plumbylynes containing metal-element triple bonds are heavier homologues of transition metal carbynes. Since the discovery of the first transition metal germylyne complex in 1996, the whole series have been synthesized including the successful preparation of a molybdenum silylyne complex in 2010, which could be considered as a milestone in the transition metal chemistry of main group elements. These novel complexes have extended our knowledge of the bonding types between transition metals and main group elements and reveal the rich chemistry of metal-element triple bonds. This review covers the syntheses, structures and reactivity of transition metal germylynes, stannylynes, plumbylynes and silylynes which were reported from 1996 to present. Future developments in this area are discussed. Contents
1 Introduction
2 Syntheses and structures
2.1 Transition metal germylynes
2.2 Transition metal stannylynes
2.3 Transition metal plumbylynes
2.4 Transition metal silylynes
3 Reactivity
3.1 Substitution reactions
3.2 Addition reactions
3.3 Coupling reactions
4 Conclusions and outlook
Key words: transition metal, silylyne, germylyne, stannylyne, plumbylyne

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