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Progress in Chemistry 2018, Vol. 30 Issue (5): 547-563 DOI: 10.7536/PC171251 Previous Articles   Next Articles

• Review •

CO2: C1 Synthon in Carboxylation Reactions

Yu Zhang, Jinghe Cen, Wenfang Xiong, Chaorong Qi, Huanfeng Jiang*   

  1. Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Program on Key Research Project (No.2016YFA0602900) for financial support.
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Recently organic synthesis using carbon dioxide as the raw material has attracted considerable attention from scientists because of the resourceful and environmental factors. Especially, transition metal-catalyzed carboxylation reaction is an efficient method to construct carboxylic acids and their derivatives, which is regarded as one of ideal strategies for carbon dioxide utilization and carbon recycle. The recent advances of carboxylation reaction of CO2 with various substrates (electrophiles, hydrocarbons, nucleophiles) are reviewed herein.
Contents
1 Introduction
2 Carboxylation of CO2 with various electrophiles
2.1 Carboxylation of CO2 with halogenated hydrocarbon
2.2 Carboxylation of CO2 with esters or alcohols
2.3 Carboxylation of CO2 with other electrophiles
3 Carboxylation of CO2 with diverse hydrocarbon compounds containing C—H bond
3.1 Carboxylation of CO2 with hydrocarbon containing C(sp)—H bond
3.2 Carboxylation of CO2 with hydrocarbon containing C(sp2)—H bond
3.3 Carboxylation of CO2 with hydrocarbon containing C(sp3)—H bond
4 Carboxylation of CO2 with different nucleophiles
4.1 Carboxylation of CO2 with organoboranes
4.2 Carboxylation of CO2 with organosilanes
5 Conclusion and outlook
Key words: carbon dioxide, C1 synthon, carboxylation, C—C bond formation, transition metal-catalyzed

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Abstract

CO2: C1 Synthon in Carboxylation Reactions