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Progress in Chemistry 2015, Vol. 27 Issue (7): 806-817 DOI: 10.7536/PC150149 Previous Articles   Next Articles

• Review and comments •

The Application on Nitrogen-Coordinating Transition Metal Complexes on Hydrosilylation

Chen Feng, Bai Ying, Li Jiayun*, Xiao Wenjun, Peng Jiajian*   

  1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,Hangzhou Normal University, Hangzhou 311121, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21203049, 21303034) and the Natural Science Foundation of Zhejiang Province, China (No.LY14B030007).
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The study of nitrogen-coordinating transition metal complexes has been a significant development in the recent decades. Designing different excellent nitrogen ligands coordinated with various transition metal complexes, which its of great value in hydrosilylation reaction. In this paper, the latest progress of the application in nitrogen-coordinating transition metal(Rh, Fe, Re, Co, Zn and so on)complexes to ketone hydrosilylation or alkene hydrosilylation is reviewed. The design of optimized bisoxazolines or dihydropyrrolo nitrogen-containing ligands will greatly facilitate the successful development of nitrogen-containing iron, rhenium, cobalt complexes in the hydrosilylation of ketone or imine.

Contents
1 Introduction
2 The application on nitrogen-coordinating transition metal complexes on hydrosilylation
2.1 The application on nitrogen-coordinating rhodium complexes on hydrosilylation
2.2 The application on nitrogen-coordinating iron complexes on hydrosilylation
2.3 The application on nitrogen-coordinating rhenium complexes on hydrosilylation
2.4 The application on nitrogen-coordinating cobalt complexes on hydrosilylation
2.5 The application on nitrogen-coordinating zinc complexes on hydrosilylation
2.6 The application on nitrogen-coordinating titanium complexes on hydrosilylation
3 The study of mechanism
4 Conclusion

Key words: nitrogen-coordinating, transition metal complexes, hydrosilylation, catalyst

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