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Progress in Chemistry 2022, Vol. 34 Issue (2): 319-327 DOI: 10.7536/PC210111 Previous Articles   Next Articles

• Review •

Transition Metal Chalcogenide Cathode Materials Applied in Aluminum-Ion Batteries

Xiaoqiong Feng1,2, Yunlong Ma3, Hong Ning2, Shiying Zhang1, Changsheng An1(), Jinfeng Li2()   

  1. 1 College of Biology and Environment Enginering, Changsha University,Changsha 410022, China
    2 College of Materials Science and Engineering, Central South University,Changsha 410083, China
    3 Beijing Institute of Aerospace System Engineering,Beijing 100076, China
  • Received: Revised: Online: Published:
  • Contact: Changsheng An, Jinfeng Li
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As a promising cathode of aluminum ion batteries (AIBs), transition metal chalcogenides (MX2 (X=S, Se, Te)) have excellent theoretical specific capacity and lower electronegativity, which endow it with great potential in commercial AIBs. Here, the relationship between the aluminum storage mechanism and the electrochemical properties of the transition metal sulfide compound (MX2 (X = S, Se, Te)) is summarized. According to the current problems of transition metal chalcogenides, we propose the corresponding solutions proposed by researchers and summarize the main material modification techniques. Finally, the development direction of transition metal chalcogenide cathode materials is prospected, and feasible strategies to improve its overall electrochemical performance are discussed.

Contents

1 Introduction

2 Aluminum storage of transition metal chalcogenides

2.1 Intercalation mechanism

2.2 Conversion mechanism

3 Transition metal chalcogenide based on conversion mechanism

3.1 Metal sulfide

3.2 Metal selenide

3.3 Metal telluride

3.4 Other chalcogenide

4 Conclusion and outlook

Key words: aluminum-ion battery, cathode material, transition metal chalcogenide, aluminum storage performance, material modification
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Fig. 2 The SEM of (a) MoS2[36], (b) MoS2/CNFs[37] and Schematic diagram of preparation method (c). Copyright 2018, ACS
Fig. 3 The schematic diagram of Co9S8@CNT-CNF material (a) and electrochemical performance (b)[41]. Copyright 2019, Elsevier
Fig. 4 The SEM (a, b), mapping diagram (c) and cycle performance curve (d) of CoSe2[45]. Copyright 2018, RSC
Fig. 5 (a) The Schematic preparation, SEM image (b, c) and electrochemical performance curve (d, e) of the positive electrode of Al-S battery[60]. Copyright 2018, Wiley
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