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化学进展 2014, Vol. 26 Issue (04): 553-559 DOI: 10.7536/PC130816 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

锂离子电池高电压电解液

张玲玲, 马玉林, 杜春雨, 尹鸽平*   

  1. 哈尔滨工业大学化工学院 特种化学电源研究所 哈尔滨 150001
  • 收稿日期:2013-08-01 修回日期:2013-12-01 出版日期:2014-04-15 发布日期:2014-01-20
  • 通讯作者: 尹鸽平，e-mail：yingphit@hit.edu.cn E-mail:yingphit@hit.edu.cn
  • 基金资助:

    国家高技术发展计划（863）项目（No. 2012AA110203）、国家自然科学基金项目（No.51202047）、黑龙江省博士后项目（No.LBH-Z11141）和中央高校基金项目（No.HIT.NSRIF.2011022）资助

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Research on the High-Voltage Electrolyte for Lithium Ion Batteries

Zhang Lingling, Ma Yulin, Du Chunyu, Yin Geping*   

  1. Institute of Advanced Chemical Power Sources, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China
  • Received:2013-08-01 Revised:2013-12-01 Online:2014-04-15 Published:2014-01-20
  • Supported by:

    The work was supported by the National High Technology Research and Development Program (863 Program) of China (No. 2012AA110203), National Science Foundation of China(No.51202047), Heilongjiang Postdoctoral Fund (No.LBH-Z11141) and Fundamental Research Funds for the Central Universities (No.HIT.NSRIF.2011022)

开发高电压正极材料是发展高能量密度锂离子电池的重要途径之一。常规电解液在高电压下容易与正极材料表面发生副反应，影响高电压正极材料性能的发挥，因此，高电压电解液引起了人们广泛的关注。本文主要从新型溶剂体系和常规碳酸酯溶剂体系两方面对锂离子电池高电压电解液进行综述与评价，提出了现有电解液的不足及面临的问题。从电解液溶剂分子设计理论入手，分析了砜类溶剂、腈基溶剂和离子液体等新型溶剂作为高压电解液溶剂的优缺点，同时探讨了不同种类添加剂在常规碳酸酯溶剂体系中的作用机理。此外，本文还介绍了理论计算方法在锂离子电池高电压电解液研究中的应用，并对其在设计新型高电压电解液中的应用前景进行了展望。

关键词： 锂离子电池, 高电压电解液, 添加剂, 理论计算

The research for high-voltage cathode materials is one of important way to develop high energy density of lithium ion batteries. Electrolyte is an essential part of lithium ion batteries, which affects the electrochemical behavior through the interface reactions with the electrodes and its Li+ ion diffusion characters. The conventional carbonate/LiPF6 electrolyte decomposes and tends to react with active cathode material when the voltage is higher than 4.5 V (vs Li/Li+), resulting in the poor performance. Therefore, searching for high-voltage electrolytes is essential to the realization of high-voltage lithium ion batteries. The progress on high-voltage electrolyte for lithium ion batteries is reviewed in this paper. The draw back and challenge of high-voltage electrolyte are also illustrated. On the theory of designing for electrolyte solvent molecular, the performance of high-voltage electrolyte is evaluated from aspects of new solvent system electrolytes and carbonate-based electrolytes. New electrolytes based on nitrile, sulfone and ionic liquids as high-voltage electrolytes with their advantage and drawbacks are analyzed. The action mechanisms of different additives in the carbonate-based electrolytes are discussed. In addition, the application of theoretical calculation methods on high-voltage electrolyte is discussed, and the vision utilizing theoretical calculation in designing novel high-voltage electrolyte is prospected.

Contents
1 Introduction
2 New organic solvents
2.1 Nitrile-based solvents
2.2 Sulfone-based solvents
2.3 Ionic liquids
3 Carbonate solvents and additives
3.1 Electrochemically polymerized additives
3.2 Phosphine-based additives
3.3 Boron-based additives
3.4 Others
4 The application of theoretical calculation method on high-voltage electrolyte
5 Conclusion and outlook

Key words: lithium ion battery, high-voltage electrolyte, additive, theoretical calculation

中图分类号: 

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摘要

锂离子电池高电压电解液