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化学进展 2014, Vol. 26 Issue (04): 545-552 DOI: 10.7536/PC130813 前一篇   后一篇

• 综述与评论 •

MFI型沸石形貌研究

史静1, 赵国良1, 滕加伟1, 王仰东1, 唐颐2, 谢在库*3   

  1. 1. 中国石油化工股份有限公司上海石油化工研究院 上海 201208;
    2. 复旦大学化学系 上海 200433;
    3. 中国石油化工股份有限公司 北京 100027
  • 收稿日期:2013-08-01 修回日期:2013-11-01 出版日期:2014-04-15 发布日期:2014-01-20
  • 通讯作者: 谢在库，e-mail：xzk@sinopec.com E-mail:xzk@sinopec.com
  • 基金资助:

    上海市博士后科研基金项目（No.13R21422000）、上海市基础研究重点项目（No.11JC1400400）和国家重点基础研究发展计划（973）项目（No.2009CB623500）资助

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Advances in the Research of MFI Zeolite Morphology

Shi Jing1, Zhao Guoliang1, Teng Jiawei1, Wang Yangdong1, Tang Yi2, Xie Zaiku*3   

  1. 1. SINOPEC Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China;
    2. Department of Chemistry, Fudan University, Shanghai 200433;
    3. SINOPEC, Beijing 100027, China
  • Received:2013-08-01 Revised:2013-11-01 Online:2014-04-15 Published:2014-01-20
  • Supported by:

    The work was supported by the Shanghai Postdoctoral Scientific Program (No.13R21422000), Science and Technology Commission of Shanghai Municipality (No.11JC1400400) and the National Basic Research Program of China, 973 Program (No.2009CB623500)

MFI沸石晶形及其形态的调控一直都是分子筛研究的重要方面。本文主要综述了单晶分子筛、纳米分子筛、核壳结构分子筛以及特殊取向分子筛（包括择优取向MFI沸石膜及具有择优取向自行生长的MFI沸石）形貌控制方法。其中，对模板剂、表面活性剂、合成体系组成及合成方法对MFI型沸石形貌的影响进行了详细综述，同时对MFI沸石形貌研究的发展前景进行了展望。

关键词： MFI分子筛, 形貌控制, 择优取向生长

The manipulating of crystal form and morphology for MFI zeolite has always been a crucial aspect in the research of zeolite. The strategies for the morphology control of single crystal zeolite、nanozeolite、zeolite with core-shell structure and/or special orientations (including oriented MFI membrane and oriented MFI zeolite crystal) are reviewed. The effect of template,surfactant,synthesis conditions and methods on the morphology of MFI zeolite has been described in detail. Furthermore, a brief outlook of the potential development of MFI zeolite morphology control is given.

Contents
1 Introduction
2 Recent advances in the research of MFI zeolite morphology
2.1 The morphology control of single crystal zeolite and nanozeolite
2.2 The morphology control of zeolite with core-shell structure
2.3 The morphology control of zeolite with special orientation
3 Outlook

Key words: MFI zeolite, morphology control, oriented growth

中图分类号: 

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摘要

MFI型沸石形貌研究