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化学进展 2013, Vol. 25 Issue (0203): 330-339 DOI: 10.7536/PC120746 前一篇   后一篇

• 综述与评论 •

异核多金属N-杂环卡宾化合物的合成及应用

顾绍金*1,2, 徐卫林1,2, 黄菁菁2   

  1. 1. 武汉纺织大学材料科学与工程学院 武汉 430073;
    2. 新型纺织材料绿色加工及其 功能化教育部重点实验室 武汉 430073
  • 收稿日期:2012-07-01 修回日期:2012-10-01 出版日期:2013-02-24 发布日期:2012-12-28
  • 通讯作者: 顾绍金 E-mail:gushaojin2005@163.com
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2012CB722701)和国家自然科学基金项目(No.21202127)资助

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导出 被引次数 ( 6 | 1 )

Synthesis and Applications of Heteromultimetallic Complexes Containing N-Heterocyclic Carbenes

Gu Shaojin*1,2, Xu Weilin1,2, Huang Jingjing2   

  1. 1. School of Materials Science and Engineering, Wuhan Textile University, Wuhan 430073, China;
    2. Key Laboratory of Green Processing and Functional Textiles of New Textile Materials, Ministry of Education, Wuhan Textile University, Wuhan 430073, China
  • Received:2012-07-01 Revised:2012-10-01 Online:2013-02-24 Published:2012-12-28

以N-杂环卡宾为配体的异核多金属化合物的合成、物理化学性质以及应用取得了很大的发展,尤其在多步串联催化反应方面显示出了优越的催化活性。本文根据构建异核多金属的配体种类,对异核多金属N-杂环卡宾化合物的合成及其应用进行了分类总结,并对异核多金属N-杂环卡宾化合物未来的研究前景进行了展望。

关键词： N-杂环卡宾, 异核多金属化合物, 合成, 应用

Due to the strong electronic donor properties and the versatile structures which can be readily modified, as well as the distinct topography, N-heterocyclic carbene(NHC)is a new class of ligands as an alternative to traditional phosphine ones. The catalytic properties of NHC-metal (NHC-M) complexes in homogeneous and asymmetric catalysis have been a focused research field and many successful results have been reported in recent years. The synthesis strategies, physical and chemical properties, as well as applications of heteromultimetallic complexes based on N-heterocyclic carbene ligand have made great development. It is worth noting that the remarkable catalytic activities have been obtained in multi-step catalytic tandem reaction. In this paper, the synthesis and applications of heteromultimetallic complexes containing N-heterocyclic carbene are summarized and reviewed according to the type of N-heterocyclic carbene ligand. The type of N-heterocyclic carbene ligand include:(a) heteromultimetallic complexes based on a triazolyl-di-ylidene ligand; (b) heteromultimetallic complexes based on a bridged bis(imidazol-2-ylidene) ligand; (c) heteromultimetallic complexes based on a functionalized multidentate N-heterocyclic ligand. Contents
1 Introduction
2 Synthesis and applications of heteromultimetallic complexes containing N-heterocyclic carbene
2.1 Heteromultimetallic complexes based on a triazolyl-di-ylidene ligand
2.2 Heteromultimetallic complexes based on a bridged bis(imidazol-2-ylidene) ligand
2.3 Heteromultimetallic complexes based on a functionalized multidentate N-heterocyclic ligand
3 Conclusion and Outlook

Key words: N-heterocyclic carbene, heteromultimetallic complexes, synthesis, applications

中图分类号: 

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