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化学进展 2014, Vol. 26 Issue (0203): 259-269 DOI: 10.7536/PC130767 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

锂离子电池富锂过渡金属氧化物xLi2MnO3·（1-x）LiMO2（M=Ni,Co或Mn）正极材料

白莹1,2, 李雨1, 仲云霞1, 陈实1,2, 吴锋1,2, 吴川*1,2   

  1. 1. 北京理工大学化工与环境学院 环境科学与工程北京市重点实验室 北京 100081;
    2. 国家高技术绿色材料发展中心 北京 100081
  • 收稿日期:2013-07-01 修回日期:2013-10-01 出版日期:2014-02-15 发布日期:2013-12-18
  • 通讯作者: 吴川，e-mail：chuanwu@bit.edu.cn E-mail:chuanwu@bit.edu.cn
  • 基金资助:

    国家重点基础研究发展计划（973）项目（No.2009CB220100）和教育部新世纪优秀人才支持计划（No.NCET-12-0047）资助

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Li-Rich Transition Metal Oxide xLi2MnO3·(1-x)LiMO2 (M=Ni, Co or Mn) for Lithium Ion Batteries

Bai Ying1,2, Li Yu1, Zhong Yunxia1, Chen Shi1,2, Wu Feng1,2, Wu Chuan*1,2   

  1. 1. Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering & Environment, Beijing Institute of Technology, Beijing 100081, China;
    2. National Development Center for High Technology Green Materials, Beijing 100081, China
  • Received:2013-07-01 Revised:2013-10-01 Online:2014-02-15 Published:2013-12-18
  • Supported by:

    This work was supported by the State Key Development Program for Basic Resarch of China (No.2009CB220100) and the Program for New Century Excellent Talents in University (No.NCET-12-0047)

作为下一代高比能锂离子电池正极材料的有力竞争者，富锂过渡金属氧化物xLi2MnO3 ·（1-x）LiMO2（M=Ni，Co或Mn）相对于传统的锂离子电池正极材料而言，具有比容量高的显著优势（可超过300 mAh/g），因此近年来得到了广泛关注。本文对富锂过渡金属氧化物xLi2MnO3 ·（1-x）LiMO2（M=Ni，Co或Mn）近几年的研究进展进行了总结，对该类材料的晶体结构特征以及首次充放电机理、不同合成方法的发展以及电化学性能的改善进行了评述，并对这类材料今后的发展方向提出了思考。

关键词： 锂离子电池, 正极材料, 过渡金属氧化物, 高容量, 合成方法

As a promising candidate of the cathode materials for the next generation of high energy density lithium-ion batteries, the Li-rich transition metal oxide xLi2MnO3 ·(1-x)LiMO2 (M=Ni, Co or Mn) is superior to the traditional cathode materials for its potential of achieving very high capacity of over 300mAh/g. Therefore, this type of materials is caught more and more attention in recent years. Here we give an overview of recent progress of xLi2MnO3 ·(1-x)LiMO2 in recent years. The research hotspots, the crystal structure characteristics and the mechanism of initial charge and discharge, the development of various synthesis methods, as well as the improvement of the electrochemical performances for xLi2MnO3 ·(1-x)LiMO2(M=Ni, Co or Mn) are commented. The future development trends of the xLi2MnO3 ·(1-x)LiMO2 (M=Ni, Co or Mn) is put forward.

Contents
1 Introduction
2 Research on initial charge-discharge mechanism of Li-rich composite cathode materials
2.1 Crystal structure of Li-rich composite cathode materials
2.2 Initial charge-discharge mechanism of Li-rich composite cathode materials
3 Synthesis methods for xLi2MnO3·(1-x)LiMO2
3.1 Co-precipitation method
3.2 Sol-gel method
3.3 Solid state method
3.4 Sucrose combustion method
3.5 Hydrothermal method
3.6 Low-temperature molten salt method
3.7 Other synthesis methods
4 Improvements on electrochemical properties of Li-rich composite cathode materials
4.1 Doping in the lattice
4.2 Surface coating
4.3 Doping other materials
4.4 Particle nanocrystallization and control of structures or morphologies of cathode materials
4.5 Proposing and exploration of new method
5 Conclusions and outlook

Key words: lithium-ion battery, cathode materials, transition metal oxide, high capacity, synthesis methods

中图分类号: 

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