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化学进展 2021, Vol. 33 Issue (8): 1404-1413 DOI: 10.7536/PC200764 前一篇   后一篇

所属专题： 锂离子电池

• 综述 •

锂离子电容电池关键电极材料

蔡克迪1, 严爽1, 徐天野1, 郎笑石1,2,*(), 王振华3,*()   

  1. 1 渤海大学化学与材料工程学院 锦州 121013
    2 辽宁省超级电容器工程技术研究中心 锦州 121013
    3 北京理工大学化学与化工学院 北京 100081
  • 收稿日期:2020-07-28 修回日期:2020-10-13 出版日期:2021-08-20 发布日期:2020-11-19
  • 通讯作者: 郎笑石, 王振华
  • 基金资助:
    国家自然科学基金项目(22075030)
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Investigation of Electrode Materials for Lithium Ion Capacitor Battery

Kedi Cai1, Shuang Yan1, Tianye Xu1, Xiaoshi Lang1,2(), Zhenhua Wang3()   

  1. 1 College of Chemistry and Materials Engineering, Bohai University,Jinzhou 121013, China
    2 Liaoning Engineering Technology Research Center of Supercapacitor,Jinzhou 121013, China
    3 College of Chemistry and Chemical Engineering, Beijing Institute of Technology,Beijing 100081, China
  • Received:2020-07-28 Revised:2020-10-13 Online:2021-08-20 Published:2020-11-19
  • Contact: Xiaoshi Lang, Zhenhua Wang
  • Supported by:
    National Natural Science Foundation of China(22075030)

锂离子电容电池兼具锂离子电池和超级电容器的优势,凭借高能量密度、高功率密度、长循环寿命和快速充放电等优势成为具有前景的新型储能系统。然而,电池型电极和电容型电极之间的动力学不平衡、能量密度不太理想和循环稳定性较差等关键问题仍然存在,若要有效解决该问题需要在该领域开发出新型正负极电极材料。因此,本文详细介绍了锂离子电容电池正负极材料(例如金属氧化物、碳材料、硫化物等)的研究进展以及技术路线,并针对目前存在的问题进行了分析,同时对电极材料未来的研究方向进行了展望,以及对其他化学电源的研究提供了新思路和手段。

关键词： 锂离子电容电池, 负极材料, 正极材料, 复合, 性能

With the advantages of both lithium ion battery and supercapacitor, lithium ion capacitor battery has become a promising new energy storage system with its advantages of high energy density, high power density, long cycle life and fast charging and discharging. However, some key problems still exist, such as dynamic imbalance, less ideal energy density and poor cycling stability between battery electrode and capacitor electrode. The electrode material is an important part of the battery and seriously affects the overall electrochemical performance. To solve this problem effectively, a variety of new type of anode and cathode electrode materials should be developed in this field. Therefore, this paper introduces in detail the research progress and technical route of cathode(layered metal oxides, graphene composite anode and other novel cathode materials) and anode(transition metal oxides, carbon materials, lithium compounds and sulfides) materials for lithium ion capacitor batteries, and analyzes the existing problems. It is found that the properties of electrode materials can be improved by nano treatment, material coating and heteroatomic doping. At the same time, the future research direction of electrode materials is prospected, and new ideas and means are provided for the research of other chemical power sources.

Contents

1 Introduction

2 Anode materials

2.1 Transition metal oxide

2.2 Carbon materials

2.3 Lithium compound

2.4 Sulfide

3 Cathode materials

3.1 Layered metal oxide

3.2 Graphene composite cathode

3.3 Other new cathode materials

4 Conclusion and outlook

Key words: lithium ion capacitor battery, anode material, cathode material, composite, performance
()
图1 锂离子电容电池优势及挑战
Fig. 1 Diagram of advantages of Li-ion capacitor batteries
图2 MoS2/NC复合材料的合成工艺[37]
Fig. 2 Synthesis of MoS2/NC composite material[37]
图3 Li1.2Mn0.56Ni0.16Co0.08O2材料的制备过程[46]
Fig. 3 Preparation process of Li1.2Mn0.56Ni0.16Co0.08O2[46]
图4 (a)LiNi0.88Co0.095Mn0.025O2@Al复合材料的合成工艺,(b)1 C速率下的循环性能,(c)不同速率下的循环性能[47]
Fig. 4 (a) Synthesis of LiNi0.88Co0.095Mn0.025O2@Al composite material,(b) cycle capability at 1 C rate,(c) rate capability under different C-rates[47].
图5 (a)rGO/V2O5的合成工艺示意图,(b)真空300 ℃退火2h后rGO/V2O5纳米颗粒的SEM图像,(c)不同速率下的循环性能[56]
Fig. 5 (a) Schematic diagram of the synthesis of rGO/V2O5,(b) SEM images of V2O5 nanoparticles anchored on rGO nanosheets after annealing in vacuum at 300 ℃ for 2 h,(c) The rate performance at various rates from C/9 to 10 C[56].
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摘要

锂离子电容电池关键电极材料