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化学进展 2013, Vol. 25 Issue (11): 1906-1914 DOI: 10.7536/PC130332 前一篇   后一篇

• 综述与评论 •

生物质基乙酰丙酸选择性还原制备新型平台化合物γ-戊内酯

唐兴, 胡磊, 孙勇*, 曾宪海, 林鹿*   

  1. 厦门大学能源研究院 厦门 361005
  • 收稿日期:2013-03-01 修回日期:2013-07-01 出版日期:2013-11-15 发布日期:2013-09-12
  • 通讯作者: 孙勇, 林鹿 E-mail:sunyong@xmu.edu.cn;lulin@xmu.edu.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No. 2010CB732201)、国家自然科学基金项目(No. 201106121)、中央高校基本业务费专项资金项目(No. 2010121077)和厦门大学研究生基础创新基金(No. 201212G006)资助

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Conversion of Biomass to Novel Platform Chemical γ-Valerolactone by Selective Reduction of Levulinic Acid

Tang Xing, Hu Lei, Sun Yong*, Zeng Xianhai, Lin Lu*   

  1. School of Energy Research, Xiamen University, Xiamen 361005, China
  • Received:2013-03-01 Revised:2013-07-01 Online:2013-11-15 Published:2013-09-12

生物质是唯一能替代化石资源转化得到液体燃料及化学品的可再生资源,近年来,催化转化生物质制备各种平台化合物的研究受到了人们越来越广泛的关注。和乙酰丙酸(LA)一样,γ-戊内酯(GVL)也被认为是一种具有广泛应用潜能的新型生物质基平台化合物。目前,人们已经开发出多种催化剂和反应体系用于催化生物质基LA选择性还原制备GVL。根据氢源的不同可将LA制备GVL的途径概括为4种:分别以分子H2、甲酸(FA)、合成气和醇类作为氢源的途径。本文着重从氢源的差异来归纳和总结生物质基LA选择性还原制备GVL的途径及其研究进展,以期为寻找一种高效、经济、环保的GVL合成途径提供一些思路和参考。

关键词： 乙酰丙酸, γ-戊内酯, 催化加氢, 生物质, 平台化合物

Biomass is the only renewable resources on the earth that can be converted to liquid fuels and chemicals to replace fossil resources. Recently, the catalytic conversion of biomass to platform molecules has attracted more and more attentions from the researchers worldwide. γ-Valerolactone (GVL) is regarded as a platform molecule that has extensive application potential, similar to levulinic acid (LA). Up to now, various of catalysts and reaction systems were developed and applied to the selective reduction of biomass-derived LA to GVL, and the hydrogenation of LA can be driven by various hydrogen sources, including molecule H2, formic acid (FA), syngas and alcohols. In this review, the catalytic hydrogenation routes and recent research progress for the reduction of LA are systematically summarized in view of the diversity of hydrogen sources. The future research trends of the selective reduction of LA to GVL are suggested.

Contents
1 Introduction
2 Catalytic hydrogenation mechanism of LA to GVL
3 Production of GVL using external molecule H2 as a hydrogen source
3.1 Heterogeneous catalytic systems
3.2 Homogeneous catalytic systems
4 Production of GVL using FA as a hydrogen source
5 Production of GVL using syngas as a hydrogen source
6 Production of GVL using alcohols as a hydrogen donor
7 Conclusion and outlook

Key words: levulinic acid, γ-valerolactone, catalytic hydrogenation, biomass, platform chemicals

中图分类号: 

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