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化学进展 2016, Vol. 28 Issue (11): 1672-1681 DOI: 10.7536/PC160502 前一篇   后一篇

• 综述与评论 •

新型生物质基平台分子γ-戊内酯的应用

魏珺楠, 唐兴*, 孙勇, 曾宪海, 林鹿*   

  1. 厦门大学能源学院 厦门 361102
  • 收稿日期:2016-05-01 修回日期:2016-09-01 出版日期:2016-11-15 发布日期:2016-10-08
  • 通讯作者: 唐兴, 林鹿 E-mail:x.tang@xmu.edu.cn;lulin@xmu.edu.cn
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Applications of Novel Biomass-Derived Platform Molecule γ-Valerolactone

Wei Junnan, Tang Xing*, Sun Yong, Zeng Xianhai, Lin Lu*   

  1. College of Energy, Xiamen University, Xiamen 361102, China
  • Received:2016-05-01 Revised:2016-09-01 Online:2016-11-15 Published:2016-10-08
通过生物质基平台分子将可再生的生物质资源转化为各种化学品和燃料的研究日益受到人们的关注。在众多生物质基平台分子中，γ-戊内酯（γ-valerolactone，GVL）可作为一种可持续供应的原料用于生产碳基化学品及能源，因此被认为是最具应用前景的平台分子之一。本文中将着重从四个方面介绍和总结近年来GVL的应用研究进展，包括以GVL作为绿色溶剂、以GVL作为起始原料合成其他碳基化学品、聚合材料及液体烃类燃料，以期为开拓生物质平台分子GVL的应用研究提供一些思路和参考。
关键词： 生物质, γ-戊内酯, 溶剂, 烃类燃料
The transformation of renewable biomass resources into a variety of chemicals and fuels via biomass-derived platform molecules has recently attracted increasing attention from industrial and academic communities. Of numerous platform molecules, γ-valerolactone (GVL) is able to be employed as a sustainable starting material that can be used to produce carbon-based chemicals and energy, which thus is considered as one of the most promising biomass-derived platform molecules. This paper mainly introduces and summarizes research advances on the downstream applications of GVL which have been made in the last decade, including employing GVL as a green solvent and employing GVL as a starting material to produce carbon-based chemicals, polymers and liquid hydrocarbon fuels. The perspective of GVL is also suggested in this review.

Contents
1 Introduction
2 Employing GVL as a green solvent
3 Synthesis of carbon-based chemicals from GVL
4 Synthesis of polymeric materials from GVL
5 Synthesis of liquid hydrocarbon fuels from GVL
6 Conclusion

Key words: biomass, γ-valerolactone, solvents, hydrocarbon fuels

中图分类号: 

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