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金属-有机骨架材料及其在催化反应中的应用

李庆远, 季生福*, 郝志谋   

  1. 北京化工大学 化工资源有效利用国家重点实验室 北京100029
  • 收稿日期:2011-10-01 修回日期:2011-12-01 出版日期:2012-08-24 发布日期:2012-08-06
  • 通讯作者: 季生福 E-mail:jisf@mail.buct.edu.cn
  • 基金资助:

    国家自然科学基金重点项目(No.21136001)资助

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导出 被引次数 ( 130 | 12 )

Metal-Organic Framework Materials and Their Applications in Catalysis

Li Qingyuan, Ji Shengfu, Hao Zhimou   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2011-10-01 Revised:2011-12-01 Online:2012-08-24 Published:2012-08-06
金属-有机骨架(metal-organic frameworks, MOFs)材料是由金属离子和有机配体通过自组装而成的具有多孔结构的特殊晶体材料。由于其种类的多样性、孔道的可调性和结构的易功能化,已在气体的吸附和分离、催化、磁学、生物医学等领域表现出了诱人的应用前景。本文介绍了MOFs材料的类型和常用的合成方法,综述了近年来MOFs材料在催化领域的应用,特别是以MOFs材料中骨架金属作为活性中心、骨架有机配体作为活性中心和负载催化活性组分的催化反应,并对MOFs材料的催化应用趋势做了展望,以期对MOFs材料的催化性能有比较全面的认识。
关键词： 金属-有机骨架, 类型, 合成, 催化, 应用
Metal-organic Framework (MOF) materials, which are synthesized by self-assembling of the metal ions and the organic ligands, are the special crystal materials with porous structure. Because of their diverse structures, tunable cavity and easy functionalization, MOFs have exhibited the attractive prospects in many fields, such as the gas adsorption and separation, the catalysts, the magnetism and the bio-medicine. In order to get comprehensive understanding of the MOFs’ catalytic properties, in this paper, the categories and common synthesis methods of MOF materials are introduced. The catalysis of the MOF materials, especially, the catalysis of the metal active sites and the active organic ligands in the frameworks of the MOF, and the catalytic active components supported in MOFs, are summarized and reviewed. The development trends of MOF materials in the catalytic applications are also prospected. Contents 1 Introduction
2 Categories and syntheses of MOFs materials
2.1 Categories of MOF materials
2.2 Syntheses of MOF materials
3 Applications of MOFs in catalysis
3.1 Catalytic reactions of MOFs with metal active sites
3.2 Catalytic reactions of MOFs with active organic ligands
3.3 Catalytic reactions of MOFs with loading active guests
4 Conclusion and outlook
Key words: metal-organic frameworks, categories, synthesis, catalysis, applications

中图分类号: 

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