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化学进展 2018, Vol. 30 Issue (5): 463-475 DOI: 10.7536/PC180219 前一篇   后一篇

• 综述 •

新型大环超分子化学:从杂杯芳烃到冠芳烃——纪念黄志镗先生诞辰90周年

王梅祥*   

  1. 清华大学化学系 生命有机磷化学及化学生物学教育部重点实验室 北京 100084
  • 收稿日期:2018-02-12 修回日期:2018-03-09 出版日期:2018-05-15 发布日期:2018-04-25
  • 通讯作者: 王梅祥e-mail:wangmx@mail.tsinghua.edu.cn E-mail:wangmx@mail.tsinghua.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21732004，21572111，91427301）资助
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Macrocyclic and Supramolecular Chemistry: From Heteracalixaromatics to Coronarenes——In Memory of Professor Zhi-Tang Huang

Xiang Wang*   

  1. MOE Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology, Department of Chemistry, Tsinghua University, Beijing 100084, China
  • Received:2018-02-12 Revised:2018-03-09 Online:2018-05-15 Published:2018-04-25
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21732004, 21572111, 91427301).
本文介绍了杂杯芳烃和冠芳烃的研究起源，总结了杂杯芳烃和冠芳烃的设计与合成、构象和大环空腔结构特征，展示了杂杯芳烃和冠芳烃的分子识别和组装性质，概述了杂杯芳烃和冠芳烃在功能材料的制备中的应用，展望了大环超分子化学未来的发展方向。
关键词： 杂杯芳烃, 冠芳烃, 大环化学, 分子识别, 超分子化学
Research history of heteracalixaromatics and coronarenes are introduced herein. The design and synthesis of heteracalixaromatics and coronarenes are summarized followed by the description of the macrocyclic conformation and cavity structures. Molecular recognition towards cations, anions and neutral guest species and property of molecular assembly of these macrocyclic hosts are presented. Applications of heteracalixaromatics and coronarenes in the fabrication of functional materials are also demonstrated briefly. The future perspectives of heteracalixaromatics and coronarenes in macrocyclic and supramolecular chemistry are discussed at last.
Contents
1 Introduction
2 Macrocyclic and supramolecular chemistry of heteracalixaromatics
2.1 Synthesis and functionalization of heteracalixaromatics and their structures
2.2 Molecular recognition and molecular assembly of heteracalixaromatics
2.3 Probing high valent organocopper chemistry using heteracalixaromatics as molecular tools
2.4 Miscellaneous applications of heteracalixaromatics
3 Macrocyclic and supramolecular chemistry of coronarenes
3.1 Synthesis and functionalization reactions of coronarenes
3.2 Structure of coronarenes
3.3 Property and application of coronarenes
4 Conclusion and outlook
Key words: heteracalixaromatics, coronarenes, macrocyclic chemistry, molecular recognition, supramolecular chemistry

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