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化学进展 2015, Vol. 27 Issue (6): 704-743 DOI: 10.7536/PC150172 前一篇   后一篇

• 超分子化学专辑 •

苝类化合物研究与应用

王辉1, Ponmani Jeyakkumar1, Sangaraiah Nagarajan1, 孟江平*2, 周成合*1   

  1. 1. 西南大学化学化工学院 生物有机与药物化学研究所 重庆市高校应用化学重点实验室 重庆 400715;
    2. 重庆文理学院材料与化工学院 环境材料与修复技术重庆市重点实验室 重庆 402160
  • 收稿日期:2015-01-01 修回日期:2015-03-01 出版日期:2015-06-15 发布日期:2015-04-16
  • 通讯作者: 孟江平, 周成合 E-mail:mengjp2006@163.com;zhouch@swu.edu.cn
  • 基金资助:
    国家自然科学基金项目(No.21172181,21372186)国际合作项目(No.81450110095),重庆市自然科学基金(No.CSTC2012jjB10026,CSTC2012jjA10153)和高等学校博士学科点专项科研基金(博导类)(SRFDP20110182110007)资助
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Current Researches and Applications of Perylene Compounds

Wang Hui1, Ponmani Jeyakkumar1, Sangaraiah Nagarajan1, Meng Jiangping*2, Zhou Chenghe*1   

  1. 1. Key Laboratory of Applied Chemistry of Chongqing Municipality, Institute of Bioorganic & Medicinal Chemistry, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China;
    2. Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, College of Materials and Chemical Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, China
  • Received:2015-01-01 Revised:2015-03-01 Online:2015-06-15 Published:2015-04-16
  • Contact: 10.7536/PC150172 E-mail:mengjp2006@163.com;zhouch@swu.edu.cn
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21172181, 21372186)(International(Regional)Cooperation and Exchange Program)(No. 81450110095), the Natural Science Foundation of Chongqing(No. CSTC2012jjB10026, CSTC2012jjA10153), and the Specialized Research Fund for the Doctoral Program of Higher Education of China(SRFDP 20110182110007).
苝类化合物具有大的共轭体系,易于进行结构修饰,可引入各种功能性基团,这种奇特结构赋予了苝类化合物优良的理化性质和特殊功能,在材料科学、超分子化学、生物、药学、医学等领域具有宽广的应用潜力,尤其在苝类有机光电材料已得到广泛的研究,取得了许多重要成就。尤其是近来越来越多的研究致力于开发苝类化合物其它可能的应用,已延伸到诸多领域,特别是相关生物医药的应用研究已成为近几年来异常活跃的新兴研究领域,引起广泛关注,进展迅速。本文结合课题组的研究工作,参考国内外近五年文献,首次系统地综述了苝类化合物在有机光电材料、纳米材料、生物医药光敏剂、生物荧光标记和成像、药物载体、人工诊断剂、人工离子受体和荧光分子探针等材料、生物、医药领域应用研究新进展。文中注重强化了化合物结构对苝类化合物性质和应用的影响。对未来苝类化合物研究与应用的发展趋势作了展望。
关键词： 苝, 材料科学, 超分子识别
Perylene compounds possess a large π-conjugated system and are easy to be chemically modified by various functional groups. These unique structural characteristics endow with favourable physical and chemical properties as well as special functions, and enable perylene compounds to have a wide range of potential applications in the fields of material science, supramolecular chemistry, biology, pharmacy, medicine and so on. In particular, perylene-based organic photoelectric materials have been widely investigated and many important achievements have been made. More recently, more and more effort has been dedicated to other possible applications of perylene compounds, and the relative research has been expanded to many fields, especially the biomedical research has become an increasingly active emerging field, and attracted wide attention in recent years. Combining with our researches and referring other works from literatures in five years, this paper for the first time systematically reviewed the recent advance in the current research and development of perylene compounds in the fields of material, biological and medical sciences including organic optoelectronic materials, nanomaterials, biomedicinal photosensitizers, fluorescent labeling and imaging agents, drug carriers, artificial diagnostic agents, artificial ion receptors and molecular probes. This review mainly focused on strengthening the effects of structures on properties and applications. At last the perspectives of the foreseeable future are also presented.

Contents
1 Introduction
2 Perylene compounds as organic optoelectronic materials
2.1 Perylene compounds as organic solar cells materials
2.2 Perylene compounds as optoelectronic information materials
3 Perylene compounds as organic nanomaterials
4 Perylene comounds as biomedicine photosensitizers
5 Perylene comounds as fluorescent labling and imaging agents
6 Perylene comounds as drug carriers
7 Perylene comounds as artificial diagnostic agents
8 Perylene comounds as artificial ion receptors
8.1 Perylene comounds as artificial cationic receptors
8.2 Perylene comounds as artificial anion receptors
9 Perylene comounds as molecular probes
10 Conclusion and outlook

Key words: perylene, material science, supramolecular recognition

中图分类号: 

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苝类化合物研究与应用