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Diels-Alder反应在构建特殊结构高分子中的应用

王志鹏, 袁金颖*   

  1. 清华大学化学系 有机光电子与分子工程教育部重点实验室 北京 100084
  • 收稿日期:2012-05-01 修回日期:2012-06-01 出版日期:2012-12-24 发布日期:2012-12-11
  • 通讯作者: 袁金颖 E-mail:yuanjy@mail.tsinghua.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.21174076, 51073090, 20836004)和国家重点基础研究发展计划(973)项目(No.2009CB930602)资助

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导出 被引次数 ( 8 | 4 )

Applications of Diels-Alder Reaction in Synthesis of Polymers with Well-Defined Architectures

Wang Zhipeng, Yuan Jinying*   

  1. Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
  • Received:2012-05-01 Revised:2012-06-01 Online:2012-12-24 Published:2012-12-11
Diels-Alder反应是一类高选择性、高产率、高可靠性和环境耐受性的反应。从其发现以来,已广泛应用于有机合成化学,成为click化学中的一种类型。近来,在具有特殊结构的高分子合成中,Diels-Alder反应也由于其广泛的实用性与正交性逐渐成为重要的链接手段之一。本文以各类结构高分子的合成作为分类方法,综述Diels-Alder反应在构建这些高分子中的应用。在此基础上,本文展望了Diels-Alder反应在高分子科学中的一些应用前景。发展方法学、应用于特殊结构聚合物的合成、拓宽功能化是相关研究中的关键性问题。
关键词： Diels-Alder反应, click化学, 嵌段共聚物, 刷状共聚物
Diels-Alder reaction is a kind of reaction with high selectivity, high productivity, high reliability and condition tolerability. Ever since its discovery, it has been widely used in the organic synthetic chemistry and become a click chemistry. Recently, the Diels-Alder reaction is also gradually becoming an important linking method in the preparation for polymers with well-defined architectures, due to its broad practicability and orthogonality. Based on the classification of polymer architecture, this paper reviews the applications of Diels-Alder reaction in preparing these polymers. Moreover, the paper gives the outlook for further prospect of Diels-Alder reaction in the polymer science. The relative key questions include methodology developments, application in the preparation of polymers with more specialized architectures, and broadening the functional usages. Contents
1 Introduction
1.1 Diels-Alder reaction
1.2 Characteristics of Diels-Alder reaction
2 Diels-Alder reaction approaches of polymers synthesis
2.1 Diels-Alder stepwise polymerization
2.2 Block copolymers
2.3 Cyclic block copolymers
2.4 Telechelic functional group
2.5 Graft copolymers
2.6 Star polymers
2.7 Hyperbranched polymers
3 Other utilization of Diels-Alder reaction
3.1 Survey as a protection group
3.2 Diels-Alder reaction based on the product of a Diels-Alder reaction (double-Diels-Alder reaction)
3.3 Other special architectural polymers
4 Conclusion and outlook
Key words: Diels-Alder reaction, click chemistry, block copolymers, graft copolymers

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