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化学进展 2015, Vol. 27 Issue (8): 1074-1086 DOI: 10.7536/PC150314 前一篇   后一篇

• 综述与评论 •

烯烃易位聚合制备遥爪聚合物及嵌段共聚物

冯雨晨, 介素云*, 李伯耿   

  1. 浙江大学化学工程与生物工程学院 化学工程联合国家重点实验室 杭州 310027
  • 收稿日期:2015-03-01 修回日期:2015-04-01 出版日期:2015-08-15 发布日期:2015-06-05
  • 通讯作者: 介素云 E-mail:jiesy@zju.edu.cn
  • 基金资助:
    国家重点基础研究发展计划(973)项目(No. 2011CB606004)资助
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Telechelic Polymers and Block Copolymers Prepared via Olefin-Metathesis Polymerization

Feng Yuchen, Jie Suyun*, Li Bogeng   

  1. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2015-03-01 Revised:2015-04-01 Online:2015-08-15 Published:2015-06-05
  • Supported by:
    The work was supported by the National Basic Research Program of China (973 Program)(No. 2011CB606004).
遥爪聚合物因其聚合物链的两端带有反应性官能团,可用于制备嵌段、接枝、星形、超支化等具有特殊结构的聚合物,其制备方法主要包括传统自由基聚合与可控/“活性”自由基聚合、阴离子聚合、阳离子聚合、易位聚合和缩合聚合等。相比于其他的传统聚合方法,烯烃易位聚合是一种较为温和的、产物分子量及结构可控的聚合方法。本文主要概述在各种链转移剂的存在下,采用环烯烃的开环易位聚合(ring-opening metathesis polymerization, ROMP)和非环二烯易位(acyclic diene metathesis, ADMET)聚合制备带有各种官能团的遥爪聚合物以及与其他活性聚合方法(NMRP、ATRP、RAFT、ROP等)相结合制备嵌段共聚物的研究进展。
关键词： 烯烃易位聚合, 遥爪聚合物, 非环二烯易位, 开环易位聚合, 嵌段共聚物
Because of the two functional groups in their polymer chain ends, telechelic polymers are usually used for the preparation of copolymers with special structures, such as block, graft, star-like, hyperbranched copolymers. Telechelic polymers are mainly prepared by traditional radical polymerization, controlled/“living” radical polymerization, anionic polymerization, cationic polymerization, metathesis polymerization, and condensation polymerization, etc. In comparison with traditional polymerization methods, olefin metathesis polymerization can be conducted in milder conditions and the molecular weight and structure of products are more controllable. In this review, the preparation of telechelic polymers via ring-opening metathesis polymerization (ROMP) and acyclic diene metathesis (ADMET) polymerization in the presence of chain transfer agents are introduced. And the preparation of block copolymers via the combination with other living polymerization methods (such as NMRP, ATRP, RAFT, ROP, etc.) will be also included.

Contents
1 Introduction
2 Catalysts for olefin metathesis polymerization
3 Telechelic polymers via olefin metathesis polymerization
3.1 ROMP
3.2 ADMET polymerization
4 Block copolymers via the combination with other living polymerization methods
4.1 Combination of ROMP and NMRP
4.2 Combination of ROMP and ATRP
4.3 Combination of ROMP and RAFT
4.4 Combination of ROMP and ROP
5 Conclusion

Key words: olefin metathesis polymerization, telechelic polymers, acyclic diene metathesis(ADMET), ring-opening metathesis polymerization(ROMP), block copolymers

中图分类号: 

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