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化学进展 2011, Vol. 23 Issue (6): 1050-1059 前一篇   后一篇

• 特约稿 •

取代型钒氧簇合物

高元哲1,2, 胡长文1*, 李晓芳1*   

  1. 1. 北京理工大学原子分子簇科学教育部重点实验室 北京 100081;
    2. 河北师范大学化学与材料科学学院 石家庄 050016
  • 收稿日期:2010-05-01 修回日期:2011-02-01 出版日期:2011-06-24 发布日期:2011-05-29
  • 作者简介:e-mail:cwhu@bit.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20731002)、北京市教委项目(No.20091739006)和高等学校学科创新引智计划项目(No.B07012)资助

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导出 被引次数 ( 2 | 1 )

Substituted Vanadium-Oxide Clusters

Gao Yuanzhe1,2, Hu Changwen1*, Li Xiaofang1*   

  1. 1. Key Laboratory of Cluster Science, Ministry of Education, Beijing Institute of Technology, Beijing 100081, China;
    2. College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050016, China
  • Received:2010-05-01 Revised:2011-02-01 Online:2011-06-24 Published:2011-05-29

钒氧簇是多金属氧簇的一个重要分支。由于钒氧簇具有多样的结构、优良的物理特性,使得其在催化、磁性及光学材料等方面具有广阔的应用前景,引起了人们的日益关注。将主族的金属或非金属元素引入到钒氧簇体系,可以形成结构新颖的取代型钒氧簇。新颖构型及其拓展结构取代型钒氧簇合物的合成,极大地丰富了钒氧簇的结构类型,推动了钒氧簇合成化学的持续发展。该类化合物在磁性方面有着潜在的应用前景。本文总结了近十年来取代型钒氧簇合物的研究成果,综述了已有化合物的磁学性质,并对其今后研究前景进行了展望。

关键词： 取代型钒氧簇合物, 合成, 结构, 磁学性质

Vanadium-oxide clusters are one class of the most important polyoxometalates. The design and assembly of polyoxovanadates (POVs) are currently of great interest in the field of crystal engineering, not only because of their structural diversity, but also their potential applications in the fields of catalytic, magnetic and optical materials. To date, a brand-new class of POVs with the incorporation of main group elements into vanadium-oxide clusters has been widely investigated. In recent years, transition-metal complexes (TMCs) are utilized to combine with different substituted vanadium-oxide clusters for the construction of various novel structural types with desired properties, which not only greatly enriched the structure of vanadium-oxide clusters, but also promoted its continuous development in the synthesis. A review has been mainly given to the new development of the substituted vanadium-oxide clusters in the aspects of structural characteristics and magnetic properties over the past several years. The prospects of them are also discussed in this paper.

Key words: substituted vanadium-oxide clusters, synthesis, structures, magnetic properties

中图分类号: 

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取代型钒氧簇合物