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化学进展 2010, Vol. 22 Issue (0203): 433-439 前一篇   后一篇

• 综述与评论 •

N-杂环卡宾/CO2加合物的合成及其应用*

王燕芹;李振江**;郭畅   

  1. (南京工业大学生物与制药工程学院 材料化学工程国家重点实验室 南京 210009）
  • 收稿日期:2009-04-03 修回日期:2009-05-30 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 李振江 E-mail:zjli@njut.edu.cn
  • 基金资助:

    国家高技术研究发展计划（863计划）;国家重点基础研究发展计划(973计划)

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The Preparation and Application of N-Heterocyclic Carbene/CO2 Adducts

Wang Yanqin; Li Zhenjiang**; Guo Chang   

  1. (State Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing 210009, China)
  • Received:2009-04-03 Revised:2009-05-30 Online:2010-03-24 Published:2010-03-18
  • Contact: Li Zhenjiang E-mail:zjli@njut.edu.cn

强亲核性的N-杂环卡宾（N-heterocyclic carbenes, NHC）是近年来研究最为活跃的一类小分子有机催化剂。本文综述了NHC-CO2的合成方法和NHC-CO2参与的4类重要反应。探讨了NHC-CO2作为NHC转移试剂参与的配位反应； 作为CO2转移试剂和催化剂调控的CO2固定和碳酸酯合成；作为羧基配体与过渡金属配位；作为潜在的NHC催化剂催化环状单体开环聚合反应等应用。最后，展望了其发展前景。

关键词： N-杂环卡宾, CO2, 加合物, 合成, 催化, 配位

The nucleophilic N-heterocyclic carbene (NHC) has emerged as a hot topic as organocatalyst in recent years. The two preparation methods and four important reactions are reviewed in this paper. The applications of N-heterocyclic carbene/CO2 adducts in metal coordination as NHC transfer reagents, in CO2 fixation and carbonate synthesis as catalysts and CO2 transfer reagents,in transition metal complexation as carboxylato-ligands, and as latent NHC in catalyzing ring-opening polymerization of cyclic monomers are summarized. The potential development of the research and application of NHC-CO2 is discussed.

Contents
1 Introduction
2 The preparation of N-heterocyclic carbene/CO2 adducts
2.1 NHC-CO2 prepared by direct reaction of free carbene and CO2
2.2 NHC-CO2 prepared by indirect methods
3 The application of N-heterocyclic carbene/CO2adducts
3.1 NHC-CO2 adducts as NHC transfer reagents
3.2 NHC-CO2 adducts as CO2 transfer reagents
3.3 NHC-CO2 adducts as carboxylato ligands
3.4 NHC-CO2 adducts as ring-opening polymerization catalysts of cyclic monomers
4 Conclusion and outlook

Key words: N-heterocyclic carbene, carbon dioxide, adducts, synthesis, catalysis, coordination

中图分类号: 

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