| Material | Structure | Treatment | Diameter of nanoparticles | Target gas | Concentration | Response | T respose/T recovery | Temperature(℃) | Limit of detection | ref |
|---|---|---|---|---|---|---|---|---|---|---|
| Au-In2O3 | Nanofibers | Annealed at 500 ℃ for 2 h | 30~50 nm | Ethanol | 0.1‰ | 116.13 | 2/152 s | 175 | ~0.001‰ | 88 |
| Pt-In2O3 | Nanofibers | Reduction method | 50~100 nm | NO2 | 0.01‰ | 23.9 | -/358 s | RT | 0.00001‰ | 89 |
| Eu-SnO2 | Nanofibers | Calcined at 600 ℃ for 5 h | 10 nm | Acetone | 0.1‰ | 32.2 | 4/3 s | 280 | 0.0003‰ | 90 |
| Rh-SnO2 | Nanofibers | Calcined at 500 ℃ for 2 h | 150 nm | Acetone | 0.05‰ | 60.6 | 2/64 s | 200 | 0.001‰ | 59 |
| Cr-WO3 | Nanofibers | Calcined at 500 ℃ for 2 h | - | Xylene | 0.1‰ | 35.04 | 1/2 s | 255 | 0.002‰ | 91 |
| Pd-WO3/Pt-WO3 | Nanotubes | Calcined at 500 ℃ for 1 h | - | Toluene | 0.005‰ | 2.35/2.24 | - | 400 | 0.001‰ | 83 |
| Ni-ZnO | Nanofibers | Calcined at 500 ℃ for 4 h | 45 nm | HCHO | 0.1‰ | 532.7% | - | RT | 0.005‰ | 92 |
Fig.4 (a) Schematic illustration of synthetic process of PdO@ZnO-SnO2 NTs; (b) SEM image of as-spun Pd@ZIF-8/PVP/Sn composite NFs;(c) TEM image of as-spun Pd@ZIF-8/PVP/Sn composite NFs;(d) SEM image of PdO@ZnO-SnO2 NTs;(e) Dynamic acetone response transition in the concentration range of 0.0001‰~0.005‰ at 400 ℃; (f) selective sensing characteristics of PdO@ZnO-SnO2 NTs toward 0.001‰ of various analytes at 400 ℃ [