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Progress in Chemistry 2012, Vol. Issue (9): 1729-1741 Previous Articles   Next Articles

• Review •

Immobilized Proline and Its Derivatives Employed in the Catalysis of Asymmetric Organic Synthesis

Hou Chen, Zhu Hao, Li Yijing, Li Yanfeng   

  1. State Key Laboratory of Applied Organic Chemistry, Institute of Biochemical Engineering & Environmental Technology, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
  • Received: Revised: Online: Published:
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During the past several years, poline and its derivatives were widely used as a kind of chiral organocatalysts in asymmetric organic synthesis. Due to their simple structure, high efficiency and superior stereoselectivity, poline and its derivatives are considered as one of the most promising chiral organocatalysts in asymmetric organic synthesis. However, a large amount of catalyst is necessarily used in reactions. The recovery and reuse of the catalysts are also impracticable. Since the immobilization of proline and its derivatives could simplify the separation of the products and facilitate catalyst recovery and reuse, the immobilization of proline and its derivatives and their applications in asymmetric organic synthesis are caused highly concern. A great deal of research focused on the immobilized proline and its derivatives achieved satisfactory achievement in recent years. The preparation of immobilized proline and its derivatives and their applications in asymmetric organic synthesis, such as Aldol reaction, Michael reaction and Mannich reaction, etc. are summarized in this review. Contents 1 Introduction
2 Aldol reaction
3 Michael reaction
4 Asymmetric hydrogenation reaction
5 Mannich reaction
6 Baylis-Hillman reaction
7 Conjugate addition reaction
8 Ullmann reaction
9 Asymmetric diethylzinc addition
10 α-Aminoxylation reaction
11 Conclusion and outlook
Key words: proline, derivatives, immobilization, asymmetric organic synthesis

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