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化学进展 2018, Vol. 30 Issue (6): 753-764 DOI: 10.7536/PC171012 前一篇   后一篇

• 综述 •

共价有机框架材料的发展与应用:气体存储、催化与化学传感

王婷1, 薛瑞1, 魏玉丽1,2, 王明玥1, 郭昊1, 杨武1*   

  1. 1. 西北师范大学化学化工学院 甘肃省生物电化学与环境分析重点实验室 教育部生态环境相关高分子材料重点实验室 兰州 730070;
    2. 兰州城市学院化学化工学院 兰州 730070
  • 收稿日期:2017-10-12 修回日期:2017-11-28 出版日期:2018-06-15 发布日期:2018-03-07
  • 通讯作者: 杨武,e-mail:xbsfda123@126.com E-mail:xbsfda123@126.com
  • 基金资助:
    国家自然科学基金（No.21665024）项目资助
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导出 被引次数 ( 3 )

Development and Applications of Covalent Organic Frameworks(COFs) Materials: Gas Storage, Catalysis and Chemical Sensing

Ting Wang1, Rui Xue1, Yuli Wei1,2, Mingyue Wang1, Hao Guo1, Wu Yang1*   

  1. 1. College of Chemistry and Chemical Engineering, Key Lab of Bioelectrochemistry and Environmental Analysis of Gansu Province, Key Lab of Eco-Environment Related Polymer Materials of Ministry of Education, Northwest Normal University, Lanzhou 730070, China;
    2. College of Chemistry and Chemical Engineering, Lanzhou City University, Lanzhou 730070, China
  • Received:2017-10-12 Revised:2017-11-28 Online:2018-06-15 Published:2018-03-07
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21665024).
共价有机框架材料（Covalent Organic Frameworks，COFs）是由有机结构单元通过共价键连接的具有周期性结构的多孔化合物。作为一类新型的结晶性有机多孔材料，由于其密度低、比表面积大、孔隙率高、结晶度好、稳定性高及结构单元可设计等特点受到科学界的广泛关注，在气体吸附与分离、光电、催化、药物传递、储能及化学传感与色谱分离等领域表现出良好的应用前景。本文对COFs材料的发展与应用研究进展进行了简要的综述，对COFs应用中尚待解决的问题进行了总结并对未来的发展方向进行了展望。
关键词： 共价有机框架材料, 多孔聚合物, 气体吸附与存储, 催化, 荧光传感
Covalent organic frameworks (COFs) are porous compounds with periodic topology structures in which the organic building units are linked by covalent bonds. As a new type of crystalline porous organic materials with multiple advantages, such as low density, large surface area, porosity, good crystallinity, high stability, designable structural units and so on, they have won more and more attention of scientists and been widely applied in many fields including gas adsorption and separation, optoelectronic device, catalysis, drug delivery, energy storage, chemical sensing and chromatographic separation. In the present paper, development and application advances of COFs materials are reviewed in outline, the burning issues concerning the applications are summarized and their possible development trends are also prospected.
Contents
1 Development of COFs materials
2 Applications of COFs materials
2.1 Storage and separation of gas
2.2 Catalysis
2.3 Fluorescent sensing
2.4 Other applications
3 Conclusion
Key words: covalent organic frameworks (COFs), porous polymer, gas adsorption and storage, catalysis, fluorescent sensing

中图分类号: 

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