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化学进展 2022, Vol. 34 Issue (8): 1809-1814 DOI: 10.7536/PC210922 前一篇   后一篇

• 综述 •

无铅卤系钙钛矿纳米晶:新一代光催化材料

范倩倩1,2,3,*(), 温璐2,3, 马建中1,2,3,*()   

  1. 1 陕西科技大学轻化工助剂化学与技术教育部重点实验室 西安 710021
    2 陕西科技大学轻工科学与工程学院 西安 710021
    3 陕西科技大学西安市绿色化学品与功能材料重点实验室 西安 710021
  • 收稿日期:2021-09-18 修回日期:2021-11-19 出版日期:2022-08-20 发布日期:2022-04-01
  • 通讯作者: 范倩倩, 马建中
  • 基金资助:
    国家自然科学基金(52103088); 轻化工助剂化学与技术教育部重点实验室开放课题(KFKT2020-08); 中国博士后科学基金面上项目(2020M683667XB)
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Lead-Free Halide Perovskite Nanocrystals: A New Generation of Photocatalytic Materials

Qianqian Fan1,2,3(), Lu Wen2,3, Jianzhong Ma1,2,3()   

  1. 1 Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology,Xi’an 710021, China
    2 College of Bioresources Chemical & Materials Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China
    3 Xi’an Key Laboratory of Green Chemicals and Functional Materials, Shaanxi University of Science and Technology, Xi’an 710021, China
  • Received:2021-09-18 Revised:2021-11-19 Online:2022-08-20 Published:2022-04-01
  • Contact: Qianqian Fan, Jianzhong Ma
  • Supported by:
    National Natural Science Foundation of China (No. 52103088). Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry open fund(KFKT2020-08); China Postdoctoral Science Foundation project(2020M683667XB)

由于TiO2光催化材料具有反应速度快、稳定性好、不产生二次污染等优点,常被应用于污染物降解、CO2还原、制氢等领域,然而TiO2可见光利用率低,限制了其进一步广泛应用。近年来,无铅卤系钙钛矿纳米晶由于其带隙可调、可见光吸收能力强等优势在光催化领域显示出巨大的潜力。相关研究表明:无铅卤系钙钛矿纳米晶可成功应用于CO2还原、有机污染物降解等领域,效果显著。基于此,本文首先阐述了无铅卤系钙钛矿纳米晶的制备方法,并系统地总结了其在CO2还原、制氢、污染物降解、NO去除等领域的应用研究进展,最后就现阶段无铅卤系钙钛矿纳米晶光催化材料研究中存在的问题及今后的研究方向进行了分析和展望。

关键词： 无铅卤系钙钛矿纳米晶, 新型光催化材料, CO2还原, 制氢, 污染物降解

TiO2 based photocatalytic technology is of wide application in the fields of pollutant degradation, CO2 reduction, hydrogen production, etc. owing to its set of intriguing properties, including fast reaction speed, high visible light utilization efficiency, and no secondary pollution. However, the low utilization rate of visible light for TiO2 materials limits it further use. In recent years, lead-free halide perovskite nanocrystals are of great interest in the field of photocatalysis due to their notable advantages such as tunable band gap and high visible light absorption. Relevant studies show that lead-free halide perovskite nanocrystals can be successfully applied in the fields of CO2 reduction and organic pollutant degradation, with significant effects. This review describes the preparation methods of lead-free halide perovskite nanocrystals, and summarizes its applications in the fields of CO2 reduction, hydrogen production, pollutant degradation and NO removal systematically. Finally, the current issues of lead-free halide perovskite nanocrystals as photocatalytic materials and the outlook for the future directions are discussed and prospected.

Contents

1 Introduction

2 Preparation methods of lead-free halide perovskite nanocrystal

2.1 Ligand-assisted reprecipitation

2.2 Heat injection

2.3 Other methods

3 Application of lead-free halide perovskite nanocrystals in the field of photocatalysis

3.1 CO2 reduction

3.2 Hydrogen production

3.3 Degradation of organic pollutants

3.4 NO removal

4 Conclusion and outlook

Key words: lead-free halide perovskite nanocrystals, new photocatalytic materials, CO2 reduction, hydrogen production, degradation of pollutants
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图1 利用LARP法制备MA3Bi2Br9纳米晶的过程示意图
Fig. 1 Schematic diagram of the preparation process of MA3Bi2Br9 nanocrystals by LARP method
图2 热注入法制备CsSnX3 (X=I/Br/Cl) 纳米晶的过程示意图
Fig. 2 Schematic diagram of the process of preparing CsSnX3 (X=I/Br/Cl) nanocrystals by hot injection method
图3 水热法制备Cs2NaVCl3纳米晶的过程示意图
Fig. 3 Schematic diagram of the process of preparing Cs2NaVCl3 nanocrystals by hydrothermal method
表1 无铅卤系钙钛矿纳米晶的光催化性能及应用领域
Table 1 Photocatalytic properties and application fields of lead-free halide perovskite nanocrystals
Material Photocatalytic performance Application References
Cs2Sb2Br9 The output of CO reached 127.5 μmol·g-1·h-1 CO2 Reduction 31
Cs2AgBiBr6 The output of CO and CH4 reached 2.35μmol·g-1·h-1 and 1.6 μmol·g-1·h 18
Cs2AgBiBr6@g-C3N4 The output of CO and CH4 reached 0.64 μmol·g-1·h-1 and 1.55 μmol·g-1·h-1 32
(CH3NH3)3Bi2I9 The hydrogen production rate under visible light is 169.21 μmol·g-1·h-1 Hydrogen evolution 33
Cs2AgBiBr6 The hydrogen production rate under visible light is 48.9 μmol·g-1·h-1 34
DMASnBr3 @g-C3N4 The hydrogen production rate under simulated sunlight is 1700 μmol·g-1·h-1 35
Cs2AgInCl6 98.5% Sudan Red Ⅲ can be degraded within 16 min Degradation of organic
pollutants		 36
MASnI3/TiO2 97% Rhodamine B can be degraded within 40 min 37
Cs2AgBiBr6 97% NO can be removed within 30 min NO removal 41
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