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化学进展 2016, Vol. 28 Issue (10): 1541-1549 DOI: 10.7536/PC160537 前一篇   后一篇

• 综述与评论 •

刺激响应型超分子凝胶

逯桃桃1, 刘娟2, 李辉1, 魏太保1, 张有明1, 林奇1*   

  1. 1. 西北师范大学化学化工学院 生态环境相关高分子材料教育部重点实验室 甘肃省高分子材料重点实验室 兰州 730070;
    2. 西北民族大学化工学院 兰州 730030
  • 收稿日期:2016-05-01 修回日期:2016-07-01 出版日期:2016-10-15 发布日期:2016-11-05
  • 通讯作者: 林奇 E-mail:linqi2004@126.com
  • 基金资助:
    国家自然科学基金项目（No.21574104，21161018，21262032）资助
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Stimulus-Responsive Supramolecular Gels

Lu Tao-Tao1, Liu Juan2, Li Hui1, Wei Tai-Bao1, Zhang You-Ming1, Lin Qi1*   

  1. 1. Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;
    2. College of Chemical Engineering, Northwest University for Nationalities, Lanzhou 730030, China
  • Received:2016-05-01 Revised:2016-07-01 Online:2016-10-15 Published:2016-11-05
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21574104, 21161018, 21262032).
随着超分子化学的日益发展，刺激响应型超分子凝胶作为一种超分子材料受到人们广泛关注。超分子凝胶是由非共价键作用力自组装而成，基于这一特性，当超分子凝胶受到外界刺激（如温度、光、pH、化学物质、机械力等）时，该凝胶能够产生响应，如溶胶-凝胶转化、颜色变化或荧光变化等。刺激响应型超分子凝胶在离子识别材料、自修复材料、生物材料等领域展现出了非常好的应用前景。本文综述了近五年来刺激响应型超分子凝胶的研究进展，并根据刺激种类的不同，将超分子凝胶分为以下几类：热敏感型超分子凝胶、化学物质和pH响应型超分子凝胶、光敏感型超分子凝胶、氧化还原响应型超分子凝胶、机械力刺激响应型超分子凝胶和多重刺激响应型超分子凝胶。本文根据上述分类对超分子凝胶进行了介绍，同时对该研究领域作了展望。
关键词： 超分子凝胶, 刺激响应, 离子刺激, 荧光
With the increasing development of supramolecular chemistry, stimulus-responsive supramolecular gels as a supramolecular material attract more attention. Supramolecular gels are self-assembled by non-covalent forces, when supramolecular gels are stimulated by temperature, light, pH, chemistry substances, mechanical strength etc., the gels can produce the appropriate response, such as sol-gel transition, change in color or fluorescence. Stimulus-responsive supramolecular gels have very good prospects in the areas of ion recognition materials, self-healing materials and biomaterials. This paper reviews the progress of stimulus responsive supramolecular gels in the past five years. According to the different types of stimulation, the gels are devided into the following categories:heat-sensitive organic gel, chemistry substances and pH-responsive supramolecular gels, light-sensitive organic gel, redox-responsive supramolecular gel, mechanical force-responsive supramolecular gels and multiple stimuli-responsive supramolecular gel. According to these classifications, the supramolecular gels are introduced and at the same time,the developing orientation for further research is presented.

Contents
1 Introduction
2 The heat-sensitive supramolecular gel
3 Chemicals substances and pH-responsive supramolecular gels
3.1 Ions-responsive supramolecular gels
3.2 Compounds-responsive supramolecular gels
3.3 pH-responsive supramolecular gels
4 Light-sensitive supramolecular gel
5 Redox-responsive supramolecular gel
6 Mechanical force-responsive supramolecular gel
7 Multiple stimuli-responsive supramolecular gel
8 Conclusion and outlook

Key words: supramolecular gels, stimulus response, ion stimulation, fluorescence

中图分类号: 

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[1] Segarra-Maset M D, Nebot V J, Miravet J F, Escuder B. Chem. Soc. Rev., 2013, 42:7086.
[2] Yu G C, Yan X Z, Han C Y, Huang F H. Chem. Soc. Rev., 2013, 42:6697.
[3] Babu S S, Praveen V K, Ajayaghosh A. Chem. Rev., 2014, 114:1973.
[4] Peng H Q, Niu L Y, Chen Y Z, Wu L Z, Tung C H, Yang Q Z. Chem. Rev., 2015, 115:7502.
[5] Tam A Y Y, Yam V W W. Chem. Soc. Rev., 2013, 42:1540.
[6] Segarra-Maset M D, Nebot V J, Miravet J F, Escuder B. Chem.Soc.Rev., 2013, 42:7086.
[7] Senguptaa S, Mondal R. RSC Adv., 2016, 6:14009.
[8] Kumar D K, Steed J W. Chem. Soc. Rev., 2014, 43:2080.
[9] Wei Z, Yang J H, Zhou J X, Xu F, Zrínyi M, Dussault P H, Osadag Y, Chen Y M. Chem. Soc. Rev., 2014, 43:8114.
[10] Liu Y C, Wang Y, Jin L Y, Chen T Yin B Z. Soft Matter, 2016, 12:934.
[11] Babu S S, Praveen V K, Ajayaghosh A. Chem. Rev., 2014, 114:1973.
[12] Du X W, Zh J, Shi J F, Xu B. Chem. Rev., 2015, 115:13165.
[13] Jie K C, Zhou Y J, Yao Y, Huang F H. Chem. Soc. Rev., 2015, 44:3568.
[14] Jung S H, Kim K Y, Woo D K, Lee S S, Jung J H. Chem. Commun., 2014, 50:13107.
[15] Yao Y, Chi X D, Zhou Y J, Huang F H. Chem. Sci., 2014, 5:2778.
[16] Yu X D, Chen L M, Zhang M M, Yi T. Chem. Soc. Rev., 2014, 43:5346.
[17] Ma X X, Zhang J J, Tang N, Wu J C. Dalton Trans., 2014, 43:17236.
[18] Anees P, Sreejith S, Ajayaghosh A. J. Am. Chem. Soc., 2014, 136:13233.
[19] Castelletto V, Hamley I W, Segarra-Maset M D, Gumbau C B, Miravet J F, Escuder B, Seitsonen J, Ruokolainen J. Biomacromolecules, 2014, 15:591.
[20] Chen C T, Chen C H, Ong T G. J. Am. Chem. Soc., 2013, 135:5294.
[21] Zhou M, Liu K Y, Qian X. J. Appl. Polym. Sci., 2016, DOI:10.1002/APP.43279.
[22] Mayoral M J, Rest C, Stepanenko V, Schellheimer J, Albuquerque R Q, Fernández G. J. Am. Chem. Soc., 2013, 135:2148.
[23] Aparicio F, Nieto-Ortega B, Nájera F, Ramírez F J, Navarrete J T L, Casado J, Sánchez L. Angew. Chem. Int. Ed., 2014, 53:1373.
[24] Reid R, Sgobba M, Raveh B, Rastelli G, Sali A, Santi D V. Macromolecules, 2015, 48(19):7359.
[25] Yu G C, Yan X Z, Hana C Y, Huang F H. Chem. Soc. Rev., 2013, 42:6697.
[26] Ka-Man Au V, Zhu N Y, Yam V W W. Inorganic Chem., 2013, 52(2):558.
[27] Zang L B, Shang H X, Wei D Y, Jiang S M. Sensors and Actuators B. 2013, 185:389.
[28] Ghosh S, Mahapatra R D, Dey J. Langmuir, 2014, 30(6):1677.
[29] Zhong D C, Liao L Q, Wang K J, Liu H J, Luo X Z. Soft Matter, 2015, 11:6386.
[30] Buerklea L E, Rowan S J. Chem. Soc. Rev., 2012, 41:6089.
[31] Zhang Y M, Lin Q, Wei T B, Qin X P, Li Y. Chem. Commun., 2009, 6074.
[32] Lin Q, Yang Q P, Sun B, Fu Y P, Zhu X, Wei T B, Zhang Y M. Soft Matter, 2014, 10:8427.
[33] Lin Q, Sun B, Yang Q P, Fu Y P, Zhu X, Wei T B, Zhang Y M. Chem. Eur. J., 2014, 20:1.
[34] Lin Q, Sun B, Yang Q P, Fu Y P, Zhu X, Zhang Y M, Wei T B. Chem. Commun., 2014, 50:10669.
[35] Lin Q, Zhu X, Fu Y P, Yang Q P, Sun B, Wei T B, Zhang Y M. Dyes and Pigments, 2015, 113:748.
[36] Lin Q, Zhu X, Fu Y P, Zhang Y M, Fang R, Yang L Z, Wei T B. Soft Matter, 2014, 10:5715.
[37] Lin Q, Lu T T, Zhu X, Sun B, Yang Q P, Wei T B, Zhang Y M. Chem. Commun., 2015, 51:1635.
[38] Lin Q, Lu T T, Lou J C, Wu G Y, Wei T B, Zhang Y M, Chem. Commun., 2015, 51:12224.
[39] Lin Q, Lu T T, Zhu X, Wei T B, Li H, Zhang Y M. Chem. Sci., 2016, DOI:10.1039/C6SC00955G.
[40] Zhang Y M, Shi B B, Li H, Qu W J, Gao G Y., Lin Q, Yao H, Wei T B. Polym. Chem., 2014, 5:4722.
[41] Yao H, Wu H P, Chang J, Lin Q, Wei T B,Zhang Y M. New J. Chem., 2016, DOI:10.1039/C5NJ03422A.
[42] Li H, Zhu Y R, Shi B B, Wu G Y, Zhang Y M, Lin Q, Yao H, Wei T B. Chin. J. Chem., 2015, 33:373.
[43] Xing L B, Yang B, Wang X J, Wang J J, Chen B, Wu Q H, Peng H X, Zhang L P, Tung C H, Wu L Z. Langmuir, 2013, 29(9):2843.
[44] Kumari S, Chauhan G S. Applied Materials & Interfaces., 2014, 6(8):5908.
[45] Ghosh K, Panja S, Bhattacharya S. RSC Adv., 2015, 5:72772.
[46] Yu G C, Jie K C, Huang F H. Chem. Rev., 2015, 115:7240.
[47] Ji X F, Shi B B, Wang H, Xia D Y, Jie K C, Wu Z L, Huang F H. Adv. Mater., 2015, 27:8062.
[48] Chen L, Jiang F L, Lin Z Z, Zhou Y F, Yue C Y, Hong M C. J. Am. Chem. Soc., 2005, 127(24):8588.
[49] Wei T B, Li H, Y R Zhu, Lu T T, Shi B B, Lin Q, Yao H, Zhang Y M. RSC Adv., 2015, 5:60273.
[50] Miao W G, Zhang L, Wang X F, Qin L, Liu M H. Langmuir, 2013, 29(18):5435.
[51] Jie K C, Zhou Y J, Yao Y, Shi B B, Huang F H. J. Am. Chem. Soc., 2015, 137:10472.
[52] Fang L, Hu Y L, Li Q, Xu S T, Dhinakarank M K, Gong W T, Ning G L. Org. Biomol. Chem., 2016, DOI:10.1039/C6OB00064A.
[53] Tran-Thi T H, Dagnelie R, Crunaire S, Nicole L. Chem. Soc. Rev., 2011,40:621.
[54] Samai S, Sapsanis C, Patil S P, Ezzeddine A, Moosa B A, Omran H, Emwas A H, Salama K N, Khashab N M. Soft Matter, 2016, 12:2842.
[55] Chen C T, Chen C H, Ong T G. J. Am. Chem. Soc., 2013, 135:5294.
[56] Gasnier A, Bucher C, Moutet J C, Royal G, Saint-Aman E, Terech P. Macromol. Symp., 2011, 304:87.
[57] Dhara B, Patra P P, Jha P K, Jadhav S V, Kumar G V P, Ballav N J. Phys. Chem. C, 2014, 118:19287.
[58] Xia W, Ni M F, Yao C H, Wang X L, Chen D Z, Lin C, Hu X-Y, Wang L Y. Macromolecules, 2015, 48:5456.
[59] Yu X D, Chen L M, Zhang M M, Yi T. Chem. Soc. Rev., 2014, 43:5346.
[60] Herpt J T V, Stuart M C A, Browne W R, Feringa B L. Langmuir, 2013, 29:8763.
[61] Roy S, Katiyar A K, Mondal S P, Ray S K, Biradha K. ACS Appl. Mater. Interfaces, 2014, 6:11493.
[62] Maity S, Kumar P, Haldar D. Soft Matter, 2011, 7(11):5239.
[63] Zhang M, Meng L, Cao X, Jiang M, Yi T. Soft Matter, 2012, 8(16):4494.
[64] Li Z Y, Zhang Y Y, Zhang C W, Chen L J, Wang C, Tan H W, Yu Y H, Li X P, Yang H B. J. Am. Chem. Soc., 2014, 136(24):8577.
[65] Dong S Y, Zheng B, Xu D H, Yan X Z, Zhang M M, Huang F H. Adv. Mater., 2012, 24:3191.
[66] Yan X Z, Xu D H, Chi X D, Chen J Z, Dong S Y, Ding X, Yu Y H, Huang F H. Adv. Mater., 2012, 24:362.
[67] Liu Z X, Feng Y, Yan Z C, He Y M, Liu C Y, Fan Q H. Chem. Mater., 2012, 24:3751.
[68] Yuan C, Guo J N, Tan M, Guo M Y, Qiu L H, Yan F. ACS Macro Lett., 2014, 3:271.
[69] Xie F, Qin L, Liu M H. Chem. Commun., 2016, 52:930.
[70] Chen H, Feng Y, Deng G J, Liu Z X, He Y M, Fan Q H. Chem. Eur. J., 2015, 21:11018.
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摘要

刺激响应型超分子凝胶