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化学进展 2016, Vol. 28 Issue (8): 1156-1169 DOI: 10.7536/PC160312 前一篇   后一篇

• 综述与评论 •

铁基纳米材料功能化及对水中汞离子的去除

孙悦, 周晓馨, 楼子墨, 刘榆, 傅瑞琪, 徐新华*   

  1. 浙江大学环境工程系 杭州 310058
  • 收稿日期:2016-03-01 修回日期:2016-05-01 出版日期:2016-08-15 发布日期:2016-07-12
  • 通讯作者: 徐新华 E-mail:xuxinhua@zju.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21477108，21277119）资助
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导出 被引次数 ( 3 | 2 )

Functionalized Iron-Based Nano-Materials for Removal of Mercury from Aqueous Solution

Sun Yue, Zhou Xiaoxin, Lou Zimo, Liu Yu, Fu Ruiqi, Xu Xinhua*   

  1. Department of Environmental Engineering, Zhejiang University, Hangzhou 310058, China
  • Received:2016-03-01 Revised:2016-05-01 Online:2016-08-15 Published:2016-07-12
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21477108, 21277119)
在水体重金属污染中，汞污染问题日益严峻，已成为全球性环境问题之一。近年来，纳米FeSx、Fe3O4、Fe等铁基材料凭借优越的吸附性能以及比表面积优势，受到研究者的广泛关注。对铁基纳米材料进行稳定化、官能团改性之后可以增强纳米粒子的分散度，为汞离子提供更多的吸附点位，进一步加强对水中汞离子的去除效果。本文重点阐述了纳米FeSx的稳定化、Fe3O4等铁基材料的巯基化（-SH）、氨基化（-NH2）等功能化改性方法及对Hg的去除；总结了功能化铁基纳米材料对水中Hg的去除效果和影响因素；探究了功能化铁基纳米材料去除水中汞的机理；最后展望了铁基功能化纳米材料处理水体汞离子的发展方向。
关键词： 铁基纳米材料, 功能化, 脱汞
Mercury pollution has posed increasingly severe threat to environment all over the world. Dealing with the problem of mercury contamination in water bodies is extremely urgent. The iron-based nanoparticles like FeSx、Fe3O4、Fe are used to remove mercury from aqueous solutions due to their high adsorption capacity and large surface area. In addition, using particle stabilization techniques and functional group modification could increase the dispersion of iron-based nanoparticles, offer more adsorption sites for the adsorption of mercury, which could enhance the effect of mercury removal. This paper emphasizes on the stabilization of FeSx nanoparticles, thiol-functionalization and amino-functionalization of Fe3O4, etc. The applications of functionalized iron-based nano-materials are summarized. The influential factors of mercury removal by iron-based materials are further discussed, and then the adsorption mechanisms of mercury by functionalized iron-based nanoparticles are also explored. Finally, the outlook of mercury removal in water environment by modified iron-based nano-materials are presented.

Contents
1 Introduction
2 Functional iron sulfide
2.1 Bio-stabilizer stabilized iron sulfide
2.2 Supported iron sulfide
2.3 The mechanisms of mercury removal by iron sulfide
3 Functional magnetic iron-based materials
3.1 Thiol-functionalization
3.2 Amino-functionalization
3.3 Other functionalizations
3.4 The mechanisms of mercury removal by magnetic iron-based materials
4 Other iron-based materials
5 Conclusion

Key words: iron-based nano-materials, functionalization, mercury removal

中图分类号: 

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[1] Lyons W B,Wayne D M,Warwick J J,Doyle G A.Environmental Geology,1998,34(2/3):143.
[2] 苗利军(Miao L J).农业工程(Agricultural Engineering),2013(3):83.
[3] 郑徽(Zheng H),金银龙(Jin Y L).卫生研究(Journal of Hygiene Research),2006,35(5):663.
[4] 陈腊梅(Chen L M).化学工程与装备(Chemical Engineering&Equipment),2014,(12):149.
[5] 于建国(Yu J G).化学工业(Chemical Industry),2010,28(2):40.
[6] 杨英伟(Yang Y W),屈撑囤(Qu C T),刘鲁珍(Liu L Z).石油化工应用(Petrochemical Industry Application),2015,(6):4.
[7] Cabán-Acevedo M,Faber M S,Tan Y,Hamers R J,Song J.Nano Letters,2012,12(4):1977.
[8] Liu T,Wang Z L,Sun Y.Chemical Engineering Journal,2014,263:55.
[9] 孔凡海(Kong F H),邱建荣(Qiu J R),刘豪(Liu H),曾汉才(Zeng H C),幸文婷(Xing W T),赵然(Zhao R).工程热物理学报(Journal of Engineering Thermophysics),2010(7):1227.
[10] 王阳(Wang Y).兰州大学硕士论文(Master Dissertation of Lanzhou University),2014.
[11] Khaleel A,Li W,Klabunde K J.Nanostructured Materials,1999,12(99):463.
[12] 刘玲(Liu L).南开大学硕士论文(Master Dissertation of Nankai University),2011.
[13] Gong Y,Tang J,Zhao D.Water Research,2015,89:309.
[14] Shao D,Ren X,Wen J,Hu S,Xiong J,Jiang T,Wang X,Wang X.Journal of Agricultural Science&Technology,2016,302:1.
[15] Gong Y,Liu Y,Xiong Z,Zhao D.Environmental Science&Technology,2014,48(7):3986.
[16] Gong Y,Liu Y,Xiong Z,Kaback D,Zhao D.Nanotechnology,2012,23(29):294007.
[17] 董婷婷(Dong T T).华南理工大学硕士论文(Master Dissertation of South China University of Technology),2011.
[18] 霍飞飞(Huo F F).北京工业大学硕士论文(Master Dissertation of Beijing University of Technology),2012.
[19] 刘荣琼(Liu R Q),赵敏(Zhao M),汪瑞峰(Wang R F).江苏环境科技(Jiangsu Environmental Science and Technology),2008,21(3):12.
[20] Dong N T,Singh M,Ulbrich P,Strnadova N,Stepanek F.Separation&Purification Technology,2011,82(1):93.
[21] 李凝(Li N),张凯琳(Zhang K L),韦立宁(Wei L N),彭楠楠(Peng N N),侯爵(Hou J).桂林理工大学学报(Journal of Guilin University of Technology),2013,33(1):107.
[22] Carpenter E E.Journal of Magnetism&Magnetic Materials,2001,225(s1/2):17.
[23] Wolthers M,Charlet L,Weijden C H V D,Linde P R V D,Rickard D.Geochimica Et Cosmochimica Acta,2005,69(14):3483.
[24] Wolthers M,Gaast S J,Rickard D.American Mineralogist,2003,88(11/12 Part2):2007.
[25] Jeong H Y,Bjorn K,Blum J D,Hayes K F.Environmental Science&Technology,2007,41(22):7699.
[26] Margareta S,Anders D,Bert A.Journal of Hazardous Materials,2006,136(3):830.
[27] 常青(Chang Q).西安科技大学硕士论文(Master Dissertation of Xi'an University of Science and Technology),2006.
[28] Liu J,Valsaraj K T,Devai I,DeLaune R D.Journal of Hazardous Materials,2008,157(s 2/3):432.
[29] 唐德保(Tang D B).冶金安全(Metallurgical Safety),1983,(06):35.
[30] 宁远(Ning Y).有色金属(Nonferrous Metals),2001,(3):90.
[31] Leeuwen H V,Fan M,Brown R C,Wang J,Wang W,Song Y.Environmental Science&Technology,2006,36(5):405.
[32] 陈永(Chen Y),洪玉珍(Hong Y Z),曹峰(Cao F),李建保(Li J B),马艳平(Ma Y P),吴溢文(Wu Y W).Proceedings of the 2008 National Symposium on Functional Materials Technology and Industry,2008.
[33] Xiong Z,He F,Zhao D,Barnett M O.Water Research,2009,43(20):5171.
[34] Rickard D,Morse J W.Marine Chemistry,2005,97(s 3/4):141.
[35] Han Y S,Jeong H Y,Demond A H,Hayes K F.Water Research,2011,45(17):5727.
[36] Han Y S,Gallegos T J,Demond A H,Hayes K F.Water Research,2011,45(2):593.
[37] 孙明洋(Sun M Y).浙江大学博士论文(Doctoral Dissertation of Zhejiang University),2015.
[38] Bower J,Savage K S,Weinman B,Barnett M O,Hamilton W P,Harper W F.Environmental Pollution,2008,156(2):504.
[39] Hokkanen S,Bhatnagar A,Sillanpää M.Water Research,2016,91:156.
[40] Dong S H,Orillano M,Khodary A,Duan Y,Batchelor B,Abdel-Wahab A.Water Research,2014,53(8):310.
[41] Yantasee W,Warner C L,Sangvanich T,Addleman R S,Carter T G,Wiacek R J,Fryxell G E,Timchalk C,Warner M G.Environmental Science&Technology,2007,41(14):5114.
[42] Liang X,Xu Y,Sun G,Wang L,Sun Y,Qin X.Colloids&Surfaces A Physicochemical&Engineering Aspects,2009,349(1/3):61.
[43] 谭丽莎(Tan L S),孙明洋(Sun M Y),胡运俊(Hu Y J),程丽华(Cheng L H),徐新华(Xu X H).化学进展(Progress in Chemistry),2013(12):2147.
[44] Teja A S,Koh P Y.Progress in Crystal Growth&Characterization of Materials,2009,55(26):22.
[45] 洪帆(Hong F).华中科技大学硕士论文(Master Dissertation of Huazhong University of Science and Technology),2008.
[46] Huang C,Hu B.Spectrochimica Acta Part B Atomic Spectroscopy,2008,63(3):437.
[47] 李广柱(Li G Z).吉林大学博士论文(Doctoral Dissertation of Jilin University),2015.
[48] Zhang S,Zhang Y,Liu J,Xu Q,Xiao H,Wang X,Xu H,Zhou J.Chemical Engineering Journal,2013,226(24):30.
[49] 周利民(Zhou L M),刘峙嵘(Liu Z R),黄群武(Huang Q W).高分子材料科学与工程(Polymeric Materials Science and Engineering),2010(4):78.
[50] 潘胜东(Pan S D).浙江大学硕士论文(Master Dissertation of Zhejiang University),2012.
[51] Pan S,Shen H,Xu Q,Luo J,Hu M.Journal of Colloid&Interface Science,2012,365(1):204.
[52] Parham H,Zargar B,Shiralipour R.Journal of Hazardous Materials,2012,205/206(1):94.
[53] Shen X,Wang Q,Chen W L,Pang Y.Applied Surface Science,2014,317:1028.
[54] 王琴(Wang Q).江南大学硕士论文(Master Dissertation of Jiangnan University),2012.
[55] 贺全国(He Q G),吴伟(Wu W),杨云(Yang Y),张继德(Zhang J D),王吉清(Wang J Q).精细化工中间体(Fine Chemical Intermediates),2007,37(2):63.
[56] 胡玮(Hu W),娄兆文(Lou Z W).化学研究(Chemical Research),2013,(2):144.
[57] 周利民(Zhou L M),王一平(Wang Y P),刘峙嵘(Liu Z R),黄群武(Huang Q W).核技术(Nuclear Techniques),2007,(9):768.
[58] Zhang F,Shi Y,Zhao Z,Ma B,Wei L,Lu L.Journal of Materials Science,2014,49(9):3478.
[59] Wang M,Meng G,Huang Q,Lu Y,Gu Y.Sensors&Actuators B Chemical,2013,185(8):47.
[60] Minsung P,Sungmin S,In Su L,Jong Hwa J.Chemical Communications,2010,46(25):4478.
[61] Yang W,Qi Y,Li Y,Wu J,Ma X,Yu C,Ji L.Journal of Hazardous Materials,2013,260(6):9.
[62] Hu H,Pan L,Wang Z.Journal of Alloys&Compounds,2010,492(s 1/2):656.
[63] Qi X,Li N,Xu Q,Chen D,Li H,Lu J.Rsc Advances,2014,4(88):47643.
[64] Wang Z,Wu D,Wu G,Yang N,Wu A.Journal of Hazardous Materials,2013,s 244/245(2):621.
[65] Sun Z.RSC Advances,2015,5(15):11000.
[66] Liu J F,Zhao Z S,Jiang G B.Environmental Science&Technology,2008,42(18):6949.
[67] Girginova P I,Daniel-Da-Silva A L,Lopes C B,Figueira P,Otero M,Amaral V S,Pereira E,Trindade T.Journal of Colloid&Interface Science,2010,345(2):234.
[68] 刘煌(Liu H).浙江工商大学硕士论文(Master Dissertation of Zhejiang Gongshang University),2012.
[69] Li G,Zhao Z,Liu J,Jiang G.Journal of Hazardous Materials,2011,192(1):277.
[70] Li K,Wang Y,Huang M,Yan H,Yang H,Xiao S,Li A.Journal of Colloid&Interface Science,2015,455:261.
[71] Diagboya P N,Olu-Owolabi B I,Adebowale K O,Olu-Owolabi BI.Rsc Advances,2015,5:2536.
[72] Singh S,Barick K C,Bahadur D.Journal of Hazardous Materials,2011,192(3):1539.
[73] Schuster E.Water Air&Soil Pollution,1991,56(1):667.
[74] 胡运俊(Hu Y J).浙江大学硕士论文(Master Dissertation of Zhejiang University),2014.
[75] 周欣(Zhou X).西南大学硕士论文(Master Dissertation of Southwest University),2013.
[76] Yan W,Herzing A A,Kiely C J,Zhang W X.Journal of Contaminant Hydrology,2010,118(3/4):96.
[77] 施秋伶(Shi Q L),周欣(Zhou X),张进忠(Zhang J Z),邱昕凯(Qiu X K).环境科学(Environmental Science),2014(8):2985.
[78] Lu X,Huangfu X,Ma J.Journal of Hazardous Materials,2014,280:71.
[79] Liang P,Li Y C,Zhang C,Wu S C,Cui H J,Yu S,Wong M H.Journal of Hazardous Materials,2013,244/245(2):322.
[80] Ambika S,Nambi I M,Senthilnathan J.Chemical Engineering Journal,2016,289:544.
[81] 颜小星(Yan X X).天津师范大学硕士论文(Master Dissertation of Tianjin Normal University),2014.
[82] 孔凡海(Kong F H),赵俊武(Zhao J W).热力发电(Thermal Power Generation),2013(11):76.
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