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化学进展 2015, Vol. 27 Issue (6): 687-703 DOI: 10.7536/PC150164 前一篇   后一篇

• 超分子化学专辑 •

超分子组装体在催化领域中的应用

赵金, 刘育*   

  1. 南开大学化学系 元素有机化学国家重点实验室 天津化学化工协同创新中心 天津 300071
  • 收稿日期:2015-01-01 修回日期:2015-03-01 出版日期:2015-06-15 发布日期:2015-04-20
  • 通讯作者: 刘育 E-mail:yuliu@nankai.edu.cn
  • 基金资助:
    国家重点基础研究发展计划(973)项目(No.2011CB932502)和国家自然科学基金项目(No.91227107,21432004)资助
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Catalytic Applications of Supramolecular Assemblies

Zhao Jin, Liu Yu*   

  1. State Key Laboratory of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Department of Chemistry, Nankai University, Tianjin 300071, China
  • Received:2015-01-01 Revised:2015-03-01 Online:2015-06-15 Published:2015-04-20
  • Contact: 10.7536/PC150164 E-mail:yuliu@nankai.edu.cn
  • Supported by:
    The work was supported by the State Basic Research Program of China(973 Program) (No.2011CB932502) and the National Natural Science Foundation of China (No. 91227107, 21432004).
超分子组装体的各组分规整排列、高比表面积等微纳米结构特点使其在催化应用领域中显示出独特的催化性能,成为当前研究的一个热点。本文将超分子组装体按照空间维度分为四类,对不同维度的超分子组装体在催化领域中的应用研究进行了简要综述;依据不同维度下组装体的结构特点,分别探讨了其催化机制以及应用优势,并对其今后的发展方向作了进一步的展望。
关键词： 超分子, 组装体, 催化
The catalytic systems based on supramolecular assemblies have became a hot research topic. The assemblies exhibit unique catalytic properties due to their specific structural characteristics, such as regular arrangement of component, high specific surface area. In this review, the catalytic mechanism and advantages of the supramolecular assemblies in different dimensions are reviewed, and their future developments are also prospected.

Contents
1 Introduction
2 The catalytic applications of zero dimension assemblies
2.1 Micelle based catalytic systems
2.2 Vesicle based catalytic systems
2.3 Nanoparticle based catalytic systems
3 The catalytic applications of one dimension assemblies
3.1 Supramolecular polymer based catalytic systems
3.2 Nanofiber based catalytic systems
3.3 Nanotube based catalytic systems
4 The catalytic applications of two dimension assemblies
5 The catalytic applications of three dimension assemblies
5.1 Gel based catalytic systems
5.2 Framework based catalytic systems
6 Conclusion and outlook

Key words: supramolecular, assemblies, catalyst

中图分类号: 

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