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化学进展 2018, Vol. 30 Issue (9): 1364-1379 DOI: 10.7536/PC180108 前一篇   后一篇

• 综述 •

F-发光探针的设计策略和应用研究

王茜1, 胡睿2*, 李沙瑜1*   

  1. 1. 重庆大学化学化工学院 重庆 401331;
    2. 中国科学院化学研究所 北京 100190
  • 收稿日期:2018-01-15 修回日期:2018-05-28 出版日期:2018-09-15 发布日期:2018-06-28
  • 通讯作者: 胡睿, 李沙瑜 E-mail:hurui@iccas.ac.cn;shayuli@cqu.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21205122，21672219）资助
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Design Strategy and Application of F- Luminescent Probes

Xi Wang1, Rui Hu2*, Shayu Li1*   

  1. 1. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China;
    2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2018-01-15 Revised:2018-05-28 Online:2018-09-15 Published:2018-06-28
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21205122, 21672219).
氟离子在人类的生产生活以及生态平衡等方面都起着非常重要的作用。生理上，人体中大部分的氟存在于牙齿和骨骼，氟化物与人体生命活动以及牙齿骨骼组织代谢密切相关，氟离子缺乏或摄入过量都会导致严重的健康问题。生态中，用含氟水灌溉，含氟尘埃沉降，以及土壤中的空气与受氟污染大气的交换，都会使土壤和地下水受到污染。因此，对生理以及自然环境中氟离子的定量检测和控制有重要意义。由于传统检测方法的局限性，具有选择性好、可视化检测以及原位无损等优点的发光检测技术成为物质检测与分析领域的热点，基于发光检测技术的氟离子发光探针的设计方法也引起了科研工作者极大的研究兴趣，并将其运用在生物检测或者实际的生活产品中。本综述总结了近五年来基于不同种类及检测机理设计的氟离子探针的研究进展，同时对探针的负载和应用方式进行了深入分析，最后对氟离子发光探针的发展方向进行了展望。
关键词： 氟离子, 检测, 发光, 探针
F- has a very significant impact on human life and ecological environment. Bone and teeth contain the majority of fluoride in the human body, which is closely related to human life activities and metabolism of teeth and bone tissue.Dietary deficiency or excessive intake of fluoride has been related to serious health problems. Moreover, soil and groundwater are contaminated by the use of fluoridated wastewater for irrigation, the settling of fluoridated dust, and the exchange of air in the soil with fluorinated air. Therefore, it is of vital importance to the quantitative detection and control of fluoride. Due to the advantages of good selectivity, in-situ visual and nondestructive detection compared with limitations of traditional methods, the design routine of luminescent probes of fluoride have attracted great interest of researchers,and it also can be used in biological detection or real life productions This review summarizes the research progress in luminescent fluoride probes with various kinds and recognition mechanisms in recent five years. The composite probes based on supported polymers and functionalized nanoparticles are also discussed. Finally, the development trend of luminescent fluoride probes is forecast.
Contents
1 Introduction
2 One-component probes
2.1 Probes based on the interaction of fluoride ion and Lewis acid
2.2 Probes utilizing weak interactions
3 Composite probes
3.1 Organic luminophor
3.2 Inorganic luminophor
4 Conclusion and outlook
Key words: fluoride ion, detection, luminescence, probes

中图分类号: 

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