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化学进展 2017, Vol. 29 Issue (6): 683-694 DOI: 10.7536/PC170231 前一篇   

• 综述 •

普鲁士蓝类材料在钠离子电池中的研究进展

王昊1,2, 邓邦为1,2, 葛武杰1,2, 陈滔1,2, 瞿美臻1, 彭工厂1*   

  1. 1. 中国科学院成都有机化学研究所 成都 610041;
    2. 中国科学院大学 北京 100049
  • 收稿日期:2017-02-28 修回日期:2017-04-09 出版日期:2017-06-15 发布日期:2017-05-10
  • 通讯作者: 彭工厂,e-mail:pgc0102@163.com E-mail:pgc0102@163.com
  • 基金资助:
    国家自然科学基金项目（No.51474196），国家高技术研究发展计划（863计划）（No.2013AA031703）和“西部之光”人才培养计划资助
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Recent Advances in Prussian Blue Analogues Materials for Sodium-Ion Batteries

Hao Wang1,2, Bangwei Deng1,2, Wujie Ge1,2, Tao Chen1,2, Meizhen Qu1, Gongchang Peng1*   

  1. 1. Chengdu Institute of Organic Chemistry, Chinese Academy of Science, Chengdu 610041, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2017-02-28 Revised:2017-04-09 Online:2017-06-15 Published:2017-05-10
  • Contact: 10.7536/PC170231 E-mail:pgc0102@163.com
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51474196), the National High-Tech R&D Program of China (No. 2013AA031703) and the "Western Light" Project.
近年来，钠离子电池以其独特的优势引起了研究者广泛的关注，有望成为下一代可商业化的储能设备。然而，钠离子电池的发展也面临着诸多的挑战。以普鲁士蓝为代表的新型储能材料，具有开放式框架体系和多孔道结构，能容纳钠离子自由快速脱嵌，从而有效提高钠离子电池的电化学性能。本文从制备工艺、材料机理、修饰方法三方面综述了普鲁士蓝材料在钠离子电池领域的应用现状。特别介绍了迁移离子、过渡金属、结合水与空位对钠离子电池电化学性能的影响。同时，总结了基于普鲁士蓝类材料的水性电池、杂化电池和适配电解液的研究现状。最后，对目前应用中存在的问题和研究重点做了简要评论，展望了该研究领域下一步的发展方向和应用前景。
关键词： 钠离子电池, 普鲁士蓝, 复合材料, 正极, 机理
Recently, the attention to sodium-ion batteries (SIBs) has been aroused on the next generation energy storage systems applications, due to their specific advantages. However, the development of SIBs remains significant challenges. Owing to their open frameworks and porous channels for Na+ fast migration, the Prussian blue analogues (PBs) materials can effectively improve the electrochemical performance of SIBs. Herein, we summarize the recent advances and applications of PBs materials for SIBs in terms of preparation process, electronic mechanism and modification technology. The effects of migration ions, transition metals, bound water and vacancy on the electrochemical performance of SIBs are particularly introduced. Moreover, we summarize the research progress on the PBs-based aqueous SIBs, hybrid batteries and appropriate electrolyte. Further, the current difficulties and future research directions of the PBs-based SIBs are also discussed to give an outlook of the prospect trends and application potentials in energy storage systems.

Contents
1 Introduction
2 Preparation of Prussian blue analogues
2.1 Co-precipitation method
2.2 Hydrothermal method
3 Mechanism study of Prussian blue analogues
3.1 Migration ions
3.2 Transition metals
3.3 Bound water and vacancy
4 Modification of Prussian blue analogues
4.1 Doping
4.2 Coating
5 Aqueous rechargeable sodium-ion battery
6 Other researches
6.1 Metal-sodium hybrid battery
6.2 Electrolyte and separator
6.3 Security studies
7 Conclusion

Key words: sodium-ion batteries, Prussian blue analogues, composite materials, cathode, mechanism

中图分类号: 

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