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化学进展 2022, Vol. 34 Issue (5): 1181-1190 DOI: 10.7536/PC210449 前一篇   后一篇

• 综述 •

石墨烯/金属-有机框架复合材料制备及其应用

乔瑶雨, 张学辉, 赵晓竹, 李超, 何乃普*()   

  1. 兰州交通大学研究院 兰州交通大学化学化工学院 兰州 730070
  • 收稿日期:2021-04-27 修回日期:2021-06-29 出版日期:2022-05-24 发布日期:2021-07-29
  • 通讯作者: 何乃普
  • 基金资助:
    甘肃省科技计划项目(20YF8GA032)
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Preparation and Application of Graphene/Metal-Organic Frameworks Composites

Yaoyu Qiao, Xuehui Zhang, Xiaozhu Zhao, Chao Li, Naipu He()   

  1. Research Institute, School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University,Lanzhou 730070, China
  • Received:2021-04-27 Revised:2021-06-29 Online:2022-05-24 Published:2021-07-29
  • Contact: Naipu He
  • Supported by:
    Science and Technology Programs of Gansu Province(20YF8GA032)

金属-有机框架(Metal-Organic Frameworks,MOFs)是由金属离子与有机配体通过配位键连接而成的高度有序多孔网络框架。MOFs具有比表面积大、孔径可调、结构多样等特性,在材料、环境以及生物医药等领域的应用具有潜在的优势。但是,MOFs存在易水解、稳定性较低、导电性差以及不易加工等缺点,与其他材料复合是改善其性能的有效途径之一。石墨烯具有突出的化学稳定性、良好的导电性、光学特性和力学特性等性能。石墨烯与MOFs的复合可有效提高和改善MOFs光电性能、稳定性以及可回收利用性。本综述介绍了原位生长法、界面生长法和共混成型法等石墨烯/MOFs复合材料的制备方法。进一步论述了其在气体分离与存储、水体净化、化学传感器和催化剂领域的应用。最后,对石墨烯/MOFs复合材料制备技术的开发及其潜在应用进行了总结和展望。

关键词： 石墨烯, 金属-有机框架, 复合材料, 吸附, 传感器, 催化剂

Metal-organic frameworks (MOFs), a novel class of crystalline materials with the ordered porous network frameworks, are formed by the coordination of metal ions and organic bridging ligands. Because of special and unique features such as the large surface area, tunable structure and high porosity, MOFs have attracted a lot of attention in materials, environment, biomedicine and so on. However, MOFs have some disadvantages including of being easily hydrolyzed, low stability, and low electrical conductivity. It is an ideal strategy that MOFs combined with other materials to improve their features and performances. In particular, graphene shows outstanding chemical stability, good electrical conductivity, optical properties and mechanical properties. Graphene compositing with MOFs can effectively improve the photoelectric properties, stability and recyclability of MOFs. Hence, in the current paper, preparation methods of graphene/MOFs composites, including in situ growth method, interfacial growth method and blending molding method, are reviewed. We also discuss their superior performance in the fields of gas separation and storage, water purification, chemical sensors, and catalysts. Moreover, the preparation development and potential applications of graphene/MOFs composites are proposed.

Contents

1 Introduction

2 Preparation methods of graphene/MOFs composite materials

2.1 In situ growth method

2.2 Interfacial growth method

2.3 Blending molding method

3 Applications of graphene/MOFs composite materials

3.1 Gas adsorption and storage

3.2 Water purification

3.3 Chemical sensor

3.4 Catalyst

4 Conclusions and outlook

Key words: graphene, metal-organic frameworks, composite materials, adsorption, sensor, catalyst
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图1 逐步合成法制备Ni-MOFs@GO纳米薄片[25]
Fig. 1 Preparation of Ni-MOFs@GO nanosheets by the step-by-step method[25]. Copyright 2016, ACS
图2 逐步合成法制备石墨烯/ZIF-8杂化气凝胶[28]
Fig. 2 Preparation of graphene/ZIF-8 hybrid aerogels by the step-by-step method[28]. Copyright 2018, ACS
图3 一步合成法制备SGO@HKUST-1复合材料[31]
Fig. 3 Preparation of SGO@HKUST-1 composite material by one-pot method[31]. Copyright 2016, ACS
图4 界面生长法制备Cu3(BTC)2/GO复合材料[35]
Fig. 4 Preparation of Cu3(BTC)2/GO composite material by interfacial growth method[35]. Copyright 2015, ACS
图5 MOFs气体吸附与分离示意图[39]
Fig. 5 Adsorption and separation of gases using MOFs[39]. Copyright 2021, ACS
图6 基于MOFs的硝基爆炸物传感器[65]
Fig. 6 Nitrobenzene recognition based on an MOF Sensor[65]. Copyright 2021, ACS
图7 Ni-MOF-74/G复合材料合成工艺示意图[71]
Fig. 7 A schematic diagram of the synthesis process of Ni-MOF-74/G[71]. Copyright 2018, ACS
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