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化学进展 2013, Vol. 25 Issue (10): 1691-1702 DOI: 10.7536/PC121146 前一篇   后一篇

• 综述与评论 •

铈铁复合氧化物的结构特征及其催化应用

李孔斋, 王华, 魏永刚, 祝星   

  1. 昆明理工大学 冶金节能减排教育部工程研究中心 昆明650093
  • 收稿日期:2012-11-01 修回日期:2013-03-01 出版日期:2013-11-12 发布日期:2013-07-18
  • 通讯作者: 王华 E-mail:wanghuaheat@hotmail.com
  • 基金资助:

    国家自然科学基金项目(No.51004060,51104074,51174105)和金川预研基金(金川201115)资助

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Structural Features of Ce-Fe Mixed Oxide and Its Applications in Catalysis

Li Kongzhai, Wang Hua, Wei Yonggang, Zhu Xing   

  1. Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction, Ministry of Education, Kunming University of Science and Technology, Kunming 650093, China
  • Received:2012-11-01 Revised:2013-03-01 Online:2013-11-12 Published:2013-07-18

氧化铈(CeO2)是一种重要的催化材料,在环境催化和催化氧化等诸多领域表现出了出色的催化性能。将其他金属离子引入氧化铈晶格通过电荷平衡原理诱导产生丰富的氧空位,是提高氧化铈催化性能的有效方法。当Fe3+进入CeO2晶格时,由于其离子半径较小,可同时形成取代和间隙两类固溶体,取代与间隙位Fe3+的摩尔比决定着氧空位的浓度,这使铈铁复合氧化物上的氧空位浓度极具调变性。另外,由于氧化铁本身亦对某些反应具有催化活性,游离的氧化铁与氧化铈颗粒间形成的特殊界面也表现出了优异的催化特性。铈铁间多重的协同作用使这类复合氧化物具有较高的研究和使用价值。本文介绍了铁离子在氧化铈中的固溶度和氧空位调变性等铈铁复合氧化物的结构特点,探讨了该材料的结构对其制备条件的敏感性,概述了其在催化领域的应用,并讨论了铈铁交互作用在催化过程中的作用。结合本课题组的一些研究成果,指出了铈铁材料尚未解决的一些关键问题和可能的研究方向。

关键词： 铈铁复合氧化物, 氧化铈, 氧化铁, 固溶体, 氧空位, 催化, 交互作用

CeO2 is one of the most interesting oxides in the fields of catalysis (e.g., environmental catalysis and catalytic oxidation) because of the rapid formation and elimination of oxygen vacancies. The performance of CeO2 can be strongly improved under doping. Synthesis of ceria-based solid solutions with controllable concentrations of oxygen vacancies is of great fundamental significance. Since the properties of the ceria-based solid solutions are affected by the dopant size and valence (lower valence ions in ceria could lower the activation energy for oxygen migration, and smaller ions enhance the oxygen storage capacity), introducing cations with smaller size and lower valence as compared to Ce4+ (e.g., Fe3+) into the ceria lattice owns considerable scientific and technological value. It has been observed a series of interesting phenomena in the structure and catalytic applications of CeO2-Fe2O3 solid solution. Moreover, the interface between CeO2 and Fe2O3 particles (e.g., Ce-O-Fe bridges) also reveals special features in catalysis. In this review, the structural features of Ce-Fe mixed oxides, including the solubility of Fe ions in ceria lattice, formation of oxygen vacancies and CeO2-Fe2O3 interaction are discussed, which are related to their activity in catalytical applications (e.g., purification of exhaust gases from vehicles, catalytic oxidation, hydrogen and syngas generation, and Fischer-Tropsch synthesis). Some key issues and possible directions on the Ce-Fe mixed oxides used in catalysis are discussed.

Contents
1 Introduction
2 Structural features of ceria-based solid solution
2.1 Formation of ceria-based solid solution and oxygen vacancies
2.2 Relationship among prepare methods, solubility of Fe in ceria lattice and oxygen vacancies concentration
3 Applications of Ce-Fe mixed oxides in catalysis
3.1 Purification of exhaust gases from vehicles
3.2 Catalytic oxidation
3.3 Hydrogen/syngas generation
3.4 Organic synthesis
3.5 Solid oxide fuel cells
3.6 Fischer-Tropsch synthesis
3.7 Catalytic wet peroxide oxidation
4 Conclusion and outlook

Key words: Ce-Fe mixed oxides, ceria, iron oxides, solid solution, oxygen vacancies, catalysis, interaction

中图分类号: 

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