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化学进展 2011, Vol. 23 Issue (12): 2442-2456 前一篇   后一篇

• 综述与评论 •

离子液体微乳液体系的应用研究

孟雅莉1,2, 李臻1*, 陈静1, 夏春谷1   

  1. 1. 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000;
    2. 中国科学院研究生院 北京 100049
  • 收稿日期:2011-04-01 修回日期:2011-07-01 出版日期:2011-12-24 发布日期:2011-09-29
  • 作者简介:e-mail:zhenli@licp.cas.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2011CB201404)和“十二五”国家科技支撑计划重点项目(No.2011BAE17B00)资助

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Application Studies of Ionic Liquid Based Microemulsions

Meng Yali1,2, Li Zhen1*, Chen Jing1, Xia Chungu1   

  1. 1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
    2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2011-04-01 Revised:2011-07-01 Online:2011-12-24 Published:2011-09-29
室温离子液体具有诸多优异的物理化学性质及功能,是一类备受关注的新型介质和材料,应用于诸多领域。特别是近年来,由离子液体参与形成的微乳液因其在生物、医药、催化以及材料制备等领域具有潜在的应用前景而备受关注。本文综述了近年来咪唑类离子液体作为极性、非极性和表面活性剂组分,分别取代微乳液体系中的水相、油相和表面活性剂相,形成的一系列新型的微乳液体系的研究进展,归纳了水、有机溶剂、高聚物、助表面活性剂、温度等因素对离子液体微乳液性质的影响。重点介绍了离子液体微乳液的热点应用,包括以离子液体微乳液液滴为模板合成纳米材料,离子液体微乳液作为酶反应的介质及其在有机反应等方面的研究进展。
关键词： 离子液体, 微乳液, 表面活性剂, 生物, 纳米材料
Room temperature ionic liquids (RTILs) are being increasingly studied as environmentally benign media or catalysts for chemical reactions and new-style functional materials with promising applications in many fields, due to their unique and attractive physicochemical properties including negligible vapor pressure, nonflammability, high chemical/thermal stability, low toxicity and favorable conductivity. In recent years, great attention has been paid to ionic liquid based microemulsions due to their potential application prospects in biology, pharmaceutical, catalysis and material preparation. The recent studies in ionic liquid based microemulsions wherein ionic liquid is substituted for the oil component, for the polar or water component and for the surfactant component are reviewed in this paper. A series of influencing factors in the properties of ionic liquid based microemulsions are summarized, such as water, organic solvent, polymer, cosurfactant and temperature. The hot applications of ionic liquid based microemulsions in synthesis of nano-materials, biocatalysis, and organic reactions are also summarized. Foe enzyme in IL microemulsions, the improvement in activity is attributed to the safe environment created by IL-based reaction systems, in which enzyme molecules are entraped into aqueous microdroplets formed in W/IL microemulsions. The IL/O microemulsion systems are widely used as a medium to prepare porous or hollow nano materials. Contents 1 Introduction 2 Ionic liquid/oil/surfactant microemulsion system 2.1 Phase behavior and microstructure 2.2 Applications 3 Ionic liquid/water/surfactant microemulsion system 3.1 Phase behavior and microstructure 3.2 Applications 4 Other types of ionic liquid microemulsions 5 Conclusions and outlook
Key words: ionic liquids, microemulsion, surfactants, biology, nano-materials Contents

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摘要

离子液体微乳液体系的应用研究