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化学进展 2010, Vol. 22 Issue (01): 107-112 前一篇   后一篇

• 综述与评论 •

基于硅材料的分子印迹聚合物的制备及应用*

阚显文;尹宇新;耿志荣;王志林**   

  1. （南京大学化学化工学院 配位化学国家重点实验室 南京 210093）
  • 收稿日期:2009-02-02 修回日期:2009-04-01 出版日期:2010-01-24 发布日期:2010-01-07
  • 通讯作者: 王志林 E-mail:wangzl@nju.edu.cn
  • 基金资助:

    国家自然科学基金

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The Preparation and Applications of Molecularly Imprinted Polymers Based on Silica Materials

Kan Xianwen; Yin Yuxin; Geng Zhirong; Wang Zhilin**   

  1. (State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China)
  • Received:2009-02-02 Revised:2009-04-01 Online:2010-01-24 Published:2010-01-07
  • Supported by:

    National Natural Science Foundation of China

分子印迹聚合物因制备简单、稳定性好、且具有分子识别功能使其在色谱分离、固相萃取、化学传感、模拟酶催化等方面有了广泛的应用。近年来，基于硅的分子印迹聚合物发展较为快速。本文主要介绍了以硅为母体材料和以硅为基质材料的分子印迹聚合物的制备及分子识别性质研究，并对其应用进行了分类，在此基础上对其将来的发展进行了展望。

关键词： 分子印迹聚合物, 硅材料, 分子识别

Owing to the advantages of its easy preparation, stability and molecular recognition capacity, molecularly imprinted polymers (MIPs) have been applied in separation, solid-phase extraction, enzyme mimic, chemical sensor, and other fields. In recent years, MIPs based on silicon develop rapidly. Here, the preparation and properties studies of MIPs based on silicon using as matrix and substrate materials are introduced, and the applications of MIPs based on silicon are reviewed. And the prospects for the future development of MIPs based on silicon is also given.

Contents
1 Introduction
2 Molecularly imprinted technology
3 Preparation of molecularly imprinted polymers based on silica materials
3.1 Imprinted polymers using silanes as matrix materials
3.2 Using silica gel as substrate materials
4 Applications of imprinted polymers based on silica materials
4.1 Chromatography separation
4.2 Solid-phase extraction
4.3 Mimic enzyme catalysis
4.4 Electrochemical sensor
5 Conclusion

Key words: molecularly imprinted polymers(MIPs), silica materials, molecular recognition

中图分类号: 

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