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化学进展 2019, Vol. 31 Issue (12): 1749-1758 DOI: 10.7536/PC190529 前一篇   

• •

分子印迹聚合物用于环境内分泌干扰物的检测与去除

谢晓纹, 马晓国**(), 郭丽慧   

  1. 广东工业大学 环境科学与工程学院 广州 510006
  • 收稿日期:2019-05-28 出版日期:2019-12-15 发布日期:2019-10-15
  • 通讯作者: 马晓国
  • 基金资助:
    国家自然科学基金项目(41272262); 广州市科技计划项目(201803030040); 广东省教育厅重大项目(自然科学)(261555101)
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Molecularly Imprinting Polymers for Detection and Removal of Environmental Endocrine Disruptors

Xiaowen Xie, Xiaoguo Ma**(), Lihui Guo   

  1. School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China
  • Received:2019-05-28 Online:2019-12-15 Published:2019-10-15
  • Contact: Xiaoguo Ma
  • About author:
    ** E-mail:
  • Supported by:
    National Natural Science Foundation of China(41272262); Science and Technology Planning Project of Guangzhou, China(201803030040); Major Projects (Natural Science) of Education Department of Guangdong Province, China(261555101)

环境内分泌干扰物对人体健康和生态环境具有严重危害,发展高效的环境内分泌干扰物检测方法与去除技术具有重要意义。由于拥有高度的吸附选择性、较大的吸附容量和良好的可重复利用性,分子印迹聚合物在环境内分泌干扰物的检测与去除方面得到了诸多应用。本文介绍了分子印迹聚合物的制备方法及性能特点,综述了近年来基于分子印迹聚合物的固相萃取技术和传感器技术在环境内分泌干扰物的灵敏、特异性检测中的应用,以及基于分子印迹聚合物的吸附技术与其他方法的联用技术用于环境内分泌干扰物的选择性高效去除,并分析了分子印迹聚合物在合成和使用方面存在的问题,展望了其应用前景。

关键词： 分子印迹聚合物, 环境内分泌干扰物, 检测, 去除

Environmental endocrine disruptors(EEDs) have very serious harms to human health and ecological environment, thus it is of great significance to develop efficient technologies to detect and remove EEDs in real environmental samples. Due to their traits of high adsorption selectivity, large adsorption ability and good regeneration ability, molecularly imprinted polymers(MIPs) have become more and more important in the applications of detection and removal of EEDs. In this paper, the features of EEDs and their application in our daily life, in industries and other aspects are introduced. And also the characteristics, preparation methods and performance characteristics of MIPs are described. In addition, the applications of MIPs based on solid phase extraction(SPE) method and sensor technology in the sensitive and specific detection of the low background concentration EEDs, and also the applications of MIPs based on adsorption technology and other hyphenated techniques in the selective, fast and efficient removal of EEDs, are reviewed. Furthermore, the study work of our laboratory in this respect are presented in this review. Last but not least, the problems in the synthesis and use of MIPs are also analyzed in detail, and the applications of MIPs in the future are prospected.

Key words: molecularly imprinted polymers, environmental endocrine disruptors(EEDs), detection, removal
()
图1 共价及非共价印迹的合成过程[15]
Fig. 1 Schemes of covalent and noncovalent molecular imprinting[15]
图2 MIP固相萃取与HPLC在线联用分析系统[55]
Fig. 2 System configuration for on-line sample purification using MIP based SPE prior to detection by HPLC[55]
图3 (A)GO、MGO、MGO@SiO2 及MIPs的合成路线图;(B)固相萃取过程分离和富集溶液或水样中6种邻苯二甲酸酯[65]
Fig. 3 (A) Schematic synthetic illustration of GO, MGO, MGO@SiO2 and MIPs;(B) detailed process of SPE to separate and enrich trace six PAEs in solution or water samples[65]
图4 分子印迹电化学传感器形成机制示意图[69]
Fig. 4 Schematic representation for the formation mechanism of the MIS[69]
图5 复合模板印迹聚合物的合成过程[85]
Fig. 5 Synthesis schematic diagram of the multi-templates imprinted polymer[85]
表1 不同文献中分子印迹聚合物的性能参数对比
Table 1 Comparison of parameters of molecularly imprinted polymers in different literatures
Material type Method Target
compound		 Functional monomer Cross-linking agent Adsorption
quantity
(mg·g-1)		 Imprinting
factor		 Application Ref
MMIP Surface imprinting technology DEHP Phenyltrimethoxysilane Tetraethyl orthosilicate 30.7 2.5 Adsorption removal 22
Dual-dummy-template MIPs Surface imprinting technology DMP (3-aminopropyl)triethoxysilane
(APTES)Phenyltrimethoxysilane
(PTMOS)		 Tetraethyl orthosilicate 7.97 1.50 SPE 65
DEP 9.86 1.80
DBP 10.80 1.0
BBP 19.16 1.40
DEHP 45.25 2.0
DNOP 24.88 1.20
MI-SBA-15 Semi-covalent approach BPA (3-isocyanatopropyl)triethoxysilane
(ICPTES)		 Tetraethyl orthosilicate 23.3 3.1 SPE 79
MIP Precipitation polymerization IBP 2-vinylpyridine Ethylene glycol dimethacrylate 106.4 2.0 Adsorption removal 82
NPX 117.6 2.5
KEP 147.1 3.8
DFC 192.3 2.6
CA 163.9 3.0
M-MIP Surface imprinting technology E2 Methacrylic acid Ethylene glycol dimethacrylate 6.0 1.9 Adsorption removal 84
BPA 5.8 1.6
MIP Surface imprinting technology BPA 4-vinylbenzoic acid Ethylene glycol dimethacrylate 16.81 4.18 SPE 85
4-tert-OP 35.97 3.71
4-NP 61.73 2.62
图6 双域膜的制备路线及其在目标污染物去除中的应用[86]
Fig. 6 The route for preparation of double-domain film and its application in the removal of the target contaminant[86]
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