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化学进展 2011, Vol. 23 Issue (12): 2457-2465 前一篇   后一篇

• 综述与评论 •

梯度接触角表面的构建与应用

张勇, 皮丕辉, 文秀芳, 郑大锋, 蔡智奇, 程江*   

  1. 华南理工大学化学与化工学院 广州 510640
  • 收稿日期:2011-03-01 修回日期:2011-06-01 出版日期:2011-12-24 发布日期:2011-09-29
  • 作者简介:e-mail:cejcheng@scut.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20976055)资助

下载PDF ( 1934 ) 引用
导出 被引次数 ( 7 | 2 )

Construction and Application of Wettability Gradient Surfaces

Zhang Yong, Pi Pihui, Wen Xiufang, Zheng Dafeng, Cai Zhiqi, Cheng Jiang*   

  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
  • Received:2011-03-01 Revised:2011-06-01 Online:2011-12-24 Published:2011-09-29
梯度接触角是梯度表面张力的反映,固体表面的润湿性由表面化学组成和表面微观形貌共同决定。通过表面化学组成和表面微观形貌的梯度化,可制备接触角变化范围不同的梯度接触角表面。本文综述了梯度接触角表面在液滴移动、微流体流动和生物吸附等领域中的应用。梯度接触角表面具有的不平衡杨氏力是促进液滴移动的主要原因,而表面所产生的接触角滞后则阻碍液滴移动;在生物学领域,梯度接触角表面会造成蛋白质和细胞选择性吸附或黏附。最后,简要探讨了梯度接触角表面存在的问题和发展方向。
关键词： 梯度润湿, 接触角滞后, 表面张力, 制备, 应用
A gradient wettability surface is the one that displays a gradual change in its surface tension along its length. The wettability of solid surfaces is governed by both the surface chemical composition and the geometrical microstructure. In this paper, two ways to fabricate the wettability gradient surfaces, controlling the chemical composition or surface morphology along the surfaces are introduced,and the application of the functional wettability surfaces, such as droplet moving, micro-fluid flow, and biosorption has been presented. The dominant force responsible for drop movement is the unbalanced Young force that results from the difference in wettability between the front and backsides of the drop, and the contact angle hysteresis has a reduced effect on the droplet moving. Generally speaking, the higher the gradient, the faster the droplet moved. The wettability gradient surfaces are also used for control of liquids flow on submillimeter scales. In addition, surface wettability is found to play an important role in biosorption and the difference in protein adsorption behavior can be attributed mainly to the wettability gradient and the type of protein. Problems existed in this research field and prospects of wettability gradient surfaces are also discussed briefly. Contents 1 Introduction 2 Preparation of the wettability gradient surfaces 2.1 Surface-chemical gradients 2.2 Morphological gradients 3 Application of the wettability gradient surfaces 3.1 Droplet moving 3.2 Micro-fluid flow 3.3 Biosorption 4 Conclusion
Key words: wettability gradient, contact angle hysteresis, surface tension, preparation, application

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摘要

梯度接触角表面的构建与应用