Progress in Chemistry

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Azido Energetic Plasticizers for Gun and Rocket Propellants

Baodong Zhao, Fulei Gao, Yinglei Wang, Yajing Liu, Bin Chen, Yongfei Pan

Progress in Chemistry, 2019, 31(2/3): 475-490. DOI: 10.7536/PC180732

Composition	T_g /℃	Composition	T_g /℃
GAP	-49.78	PolyBAMO	-53.77
AE-2	-42.24	AE-8	-41.01
AE-2+GAP	-38.82	AE-8+GAP	-50.25
AE-2+PolyBAMO	-48.22	AE-8+PolyBAMO	-54.71
AE-3	-75.97	AE-10	-67.49
AE-3+GAP	-53.90	AE-10+GAP	-52.49
AE-3+PolyBAMO	-59.75	AE-10+PolyBAMO	-56.09
AE-4	-34.38	AE-11	-55.66
AE-4+GAP	-53.90	AE-11+GAP	-51.30
AE-4+PolyBAMO	-59.75	AE-11+PolyBAMO	-55.38
AE-5	-52.25	AE-12	-45.99
AE-5+GAP	-50.11	AE-12+GAP	-49.47
AE-5+PolyBAMO	-53.60	AE-12+PolyBAMO	-53.93
AE-6	-55.48	AE-13	-20.84
AE-6+GAP	-50.11	AE-13+GAP	-52.98
AE-6+PolyBAMO	-53.60	AE-13+PolyBAMO	-47.67

Table 5 Plasticizing performance of plasticizers AEs on GAP and PolyBAMO^[35]

Other figure/table from this article

Fig. 1 Structures and abbreviations of representative azido plasticizers
Fig. 2 Synthetic route for TMETA^[24]
Fig. 3 Synthetic routes for plasticizers BDPF and DAEF^{[26, 27]}
Fig. 4 Structures of plasticizers BDAPs^[28]
Table 1 Properties of plasticizers BDAPs^[28]
Table 2 Plasticizing performance of BDAPs on binders GAP and GAP Polyurethane^[28]
Fig. 5 Synthetic route for plasticizer TAA^[29]
Table 3 Properties of plasticizers AcBAMP, ProBAMP, ButBAMP and DEGBAA^[30]
Fig. 6 Synthetic route for plasticizers BAMPs^[30]
Fig. 7 Structures of plasticizers BAAEM and BAAEG^{[31, 32]}
Fig. 8 Synthetic route for plasticizers [G-1]-(N₃)₆ and [G-1]-(N₃)₈^[33]
Fig. 9 Structures of plasticizers DAEs^[34]
Table 4 Properties of plasticizers DAEs^[34]
Fig. 10 Structures of plasticizers AEs^[35]
Fig. 11 Synthetic route for NMPA^[36]
Fig. 12 Synthetic route for DAENP^[38]
Fig. 13 Synthetic route for DAMNP and ENPEA^{[41, 42]}
Fig. 14 Synthetic route for plasticizer DPTB^[44]
Fig. 15 Synthetic route for compound DABAMDB^[46]
Fig. 16 Synthetic route for DADNH and BAADNH^{[49, 50]}
Fig. 17 Synthetic route for DIANP and PNAN^{[51~54, 58, 61]}
Fig. 18 Synthetic route for DANP and DATH from Urotropine^{[64, 69]}
Fig. 19 Synthetic route for plasticizer DANP from urea^[65]
Fig. 20 Synthetic route for AENAs^[70]
Fig. 21 Synthetic route for plasticizer ADFE^[71]
Fig. 22 Synthetic route for plasticizer DADFAH^[75]
Fig. 23 Synthetic route for GAPA-1 and GAPA-2^[76]
Fig. 24 Synthetic route for AATGAP^[77]
Fig. 25 Synthetic route for GAPA-n^[78]
Fig. 26 Synthetic route for TNB-GAP^[79]
Fig. 27 Synthetic route for PHPGN, PAPGN and PMPGN^[80]
Table 6 Comparison of the properties of representative azido plasticizers^{[24, 28, 30, 34, 38, 58, 75]}

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