Progress in Chemistry

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Azido Energetic Plasticizers for Gun and Rocket Propellants

Baodong Zhao, Fulei Gao, Yinglei Wang, Yajing Liu, Bin Chen, Yongfei Pan

Progress in Chemistry, 2019, 31(2/3): 475-490. DOI: 10.7536/PC180732

Properties	AcBAMP	ProBAMP	ButBAMP	DEGBAA
N /%^a	31.10	28.17	25.75	32.80
OB /%^b	-124	-145	-162	-112
ρ /g·cm^{-3 c}	1.21	1.16	1.09	1.00
T_p/℃^d	230	227	226	215
T_g /℃^e	-80	-86	-95	-63
p_CJ /GPa^f	7.9	7.2	6.2	4.6
V_Det /m·s^{-1 g}	5420	5292	5048	4363
I_s /s^h	175	171	167	169
IS /Jⁱ	> 40	> 40	> 40	> 10
FS /N^j	> 360	> 360	> 360	160

Table 3 Properties of plasticizers AcBAMP, ProBAMP, ButBAMP and DEGBAA^[30]

Other figure/table from this article

Fig. 1 Structures and abbreviations of representative azido plasticizers
Fig. 2 Synthetic route for TMETA^[24]
Fig. 3 Synthetic routes for plasticizers BDPF and DAEF^{[26, 27]}
Fig. 4 Structures of plasticizers BDAPs^[28]
Table 1 Properties of plasticizers BDAPs^[28]
Table 2 Plasticizing performance of BDAPs on binders GAP and GAP Polyurethane^[28]
Fig. 5 Synthetic route for plasticizer TAA^[29]
Fig. 6 Synthetic route for plasticizers BAMPs^[30]
Fig. 7 Structures of plasticizers BAAEM and BAAEG^{[31, 32]}
Fig. 8 Synthetic route for plasticizers [G-1]-(N₃)₆ and [G-1]-(N₃)₈^[33]
Fig. 9 Structures of plasticizers DAEs^[34]
Table 4 Properties of plasticizers DAEs^[34]
Fig. 10 Structures of plasticizers AEs^[35]
Table 5 Plasticizing performance of plasticizers AEs on GAP and PolyBAMO^[35]
Fig. 11 Synthetic route for NMPA^[36]
Fig. 12 Synthetic route for DAENP^[38]
Fig. 13 Synthetic route for DAMNP and ENPEA^{[41, 42]}
Fig. 14 Synthetic route for plasticizer DPTB^[44]
Fig. 15 Synthetic route for compound DABAMDB^[46]
Fig. 16 Synthetic route for DADNH and BAADNH^{[49, 50]}
Fig. 17 Synthetic route for DIANP and PNAN^{[51~54, 58, 61]}
Fig. 18 Synthetic route for DANP and DATH from Urotropine^{[64, 69]}
Fig. 19 Synthetic route for plasticizer DANP from urea^[65]
Fig. 20 Synthetic route for AENAs^[70]
Fig. 21 Synthetic route for plasticizer ADFE^[71]
Fig. 22 Synthetic route for plasticizer DADFAH^[75]
Fig. 23 Synthetic route for GAPA-1 and GAPA-2^[76]
Fig. 24 Synthetic route for AATGAP^[77]
Fig. 25 Synthetic route for GAPA-n^[78]
Fig. 26 Synthetic route for TNB-GAP^[79]
Fig. 27 Synthetic route for PHPGN, PAPGN and PMPGN^[80]
Table 6 Comparison of the properties of representative azido plasticizers^{[24, 28, 30, 34, 38, 58, 75]}

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