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化学进展 2008, Vol. 20 Issue (04): 469-482 前一篇   后一篇

• 综述与评论 •

多金属氧酸盐催化的液相氧化反应*

郎贤军1,2 路瑞玲1,2 李臻1 夏春谷1**   

  1. （1.中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000；2.中国科学院研究生院 北京 100049）
  • 收稿日期:2007-05-08 修回日期:2007-06-11 出版日期:2008-04-24 发布日期:2008-04-24
  • 通讯作者: 夏春谷
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Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates

Lang Xianjun1,2 Lu Ruiling1,2 Li Zhen1 Xia Chungu1**   

  1. (1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China)
  • Received:2007-05-08 Revised:2007-06-11 Online:2008-04-24 Published:2008-04-24
  • Contact: Xia Chungu
介绍了多金属氧酸盐的结构和性能, 综述了这类化合物具有的多功能性和可调性，并对它们与环境温和、经济廉价的条件（溶剂，氧化剂等）的良好兼容性等特点进行了概述。多金属氧酸盐可以在原子/分子层次上进行催化剂的设计，在绿色催化和清洁生产等方面具有良好的应用前景。文本总结了多金属氧酸盐在液相清洁催化氧化方面的进展，主要针对以过氧化氢和分子氧为氧化剂的烯烃类化合物的环氧化反应、烷烃和芳香族化合物的氧化反应，并详细探讨了此类氧化反应的反应机理。同时也关注了多金属氧酸盐在仿生催化领域的应用。
关键词： 多金属氧酸盐, 清洁氧化, 过氧化氢, 分子氧, 仿生催化
After a brief introduction to the structure and general properties of polyoxometalates, the unusual versatility and tunability and their compatibility with environmentally and economically attractive conditions (solvents, oxidants, etc.) are outlined. These characteristics enable polyoxometalates suitable for catalyst to design at the atomic/molecular levels and applicable in the aspects of green catalysis and clean production. Recent developments of clean oxidation systems catalyzed by polyoxometalates are summarized in detail. The emphasis is on the epoxidation reaction of olefinic compounds, oxidation of alkanes and aromatic compounds with the comparatively ideal oxidants, hydrogen peroxide and molecular oxygen respectively. The oxidation mechanisms are elucidated in detail. In addition, the applications of polyoxometalate in the area of biomimetic catalysis are discussed.
Key words: polyoxometalate, clean oxidation, hydrogen peroxide, molecular oxygen, biomimetic catalysis

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