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化学进展 2024, Vol. 36 Issue (2): 177-186 DOI: 10.7536/PC230613 前一篇   后一篇

• 综述 •

以水为原料的过氧化氢原位制备方法

于敬泽1, 谢腾峰2,*()   

  1. 1 吉林大学新能源与环境学院 长春 130021
    2 吉林大学化学学院 长春 130012
  • 收稿日期:2023-06-19 修回日期:2023-11-11 出版日期:2024-02-24 发布日期:2024-01-08
  • 作者简介:

    谢腾峰 教授、博士生导师，研究方向：能源与环境光催化、太阳能电池、光生电荷检测谱仪开发、光电化学。

  • 基金资助:
    国家自然科学基金项目(22172057)
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In-situ Preparation Methods of Hydrogen Peroxide via Water Oxdation

Jingze Yu1, Tengfeng Xie2()   

  1. 1 College of New Energy and Environment, Jilin University, Changchun 130021, China
    2 College of Chemistry, Jilin University, Changchun 130012, China
  • Received:2023-06-19 Revised:2023-11-11 Online:2024-02-24 Published:2024-01-08
  • Contact: *e-mail: xietf@jlu.edu.cn
  • Supported by:
    National Natural Science Foundation of China(22172057)

过氧化氢（H2O2）是一种重要的化学品，可作为清洁的消毒剂，主要采用蒽醌法集中生产，运输和储存过程存在爆炸风险，因此需要开发原位制备方法。以氧气为原料的电化学还原和光催化还原已被广泛关注，但反应在气液固三相界面进行，设备复杂、产量受限。以水为原料的固液界面氧化过程也是原位产生H2O2的重要途径，本文概述电化学、光催化等氧化水制备H2O2的常见方法，重点介绍热催化、超声压电、等离子体、微液滴等研究近期出现的原位制备过氧化氢新方法，为过氧化氢原位制备，特别是消毒领域的研究者提供参考。

关键词： 消毒, 过氧化氢, 原位制备, 水氧化

Hydrogen peroxide (H2O2) is an important chemical that may be used as a clean disinfectant. For scale application, H2O2 is produced primarily by the anthraquinone process. The necessary transportation and storage processes bring explosion risks, so it is urgent to develop in-situ preparation methods. Electrochemical and photocatalytic reduction of oxygen to product H2O2 have received wide attention, but these reactions are carried out at the gas-liquid-solid interface. This three-phase reaction requires complex equipment and sequentially limits large-scale production. Another equally important pathway for in-situ H2O2 production is the oxidation of water which needs only solid-liquid two-phase interface. This paper summarizes the common methods of oxidizing water to prepare H2O2, such as electrochemistry and photocatalysis, and focuses on the recent new methods of in-situ H2O2 preparation, including thermal catalysis, ultrasonic piezoelectricity, plasma and microdroplet method. These methods provide the references for in-situ H2O2 production and in particular its utilization in the field of disinfection.

Contents

1 Industrial process for the production of hydrogen peroxide

2 In-situ production of hydrogen peroxide via oxygen reduction reaction

3 In-situ production of hydrogen peroxide via water oxidation reaction

3.1 Electrochemical and photocatalytic hydrogen peroxide generation from water oxidation

3.2 Thermocatalytic hydrogen peroxide generation

3.3 Ultrasonic piezoelectrical hydrogen peroxide generation

3.4 Electrical discharge plasma hydrogen peroxide generation

3.5 Generation of hydrogen peroxide from aqueous microdroplets

4 Conclusion and outlook

Key words: disinfection, hydrogen peroxide, in-situ preparation, water oxidation
()
图1 电化学产H2O2反应器和反应路径示意图
Fig.1 Schematic diagram of electrochemical reactor and reaction route for H2O2 production
图2 光电化学产H2O2反应器和反应路径示意图
Fig.2 Schematic diagram of photo- electrochemical reactor and reaction route for H2O2 production
图3 超声作用下g-C3N4产H2O2的示意图
Fig.3 Schematic diagram of ultrasonic-driven generation of H2O2 over g-C3N4
表1 以水为原料现场产H2O2方法的对比
Table 1 Performance comparison of in-situ H2O2 preparation via water oxdation
Methods Typical H2O2 concentration(%) General yield (mL/min) Ref
electrochemicistry 0.04~0.1 ~2 1,32
photocatalysis
thermocatalysis ~0.1 0.05 49
piezoelectricity ≤0.01 ~1 54
plasma ~0.03 ~1 61
microdroplet ~0.1 unlimited 71,72
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