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化学进展 2023, Vol. 35 Issue (8): 1258-1265 DOI: 10.7536/PC221214 前一篇   后一篇

• 综述 •

基于过氧乙酸的高级氧化技术及在水处理消毒中的应用

李怡宁, 隋铭皓*()   

  1. 同济大学环境科学与工程学院 上海 200092
  • 收稿日期:2022-12-28 修回日期:2023-03-27 出版日期:2023-08-24 发布日期:2023-05-10
  • 作者简介:

    隋铭皓 同济大学环境科学与工程学院教授、博士生导师。主要研究方向包括高级氧化水处理技术和微生物消毒技术研究。主持国家自然科学基金、重点研发计划课题等省部级课题11项,发表学术论文近百篇,其中SCI论文40 篇。

  • 基金资助:
    国家自然科学基金项目(2019YFC0408801)
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Peracetic Acid-Based Advanced Oxidation Processes and Its Applications in Water Disinfection

Yining Li, Minghao Sui()   

  1. College of Environment Science and Engineering, Tongji University,Shanghai 200092, China
  • Received:2022-12-28 Revised:2023-03-27 Online:2023-08-24 Published:2023-05-10
  • Contact: *e-mail: minghaosui@tongji.edu.cn
  • Supported by:
    National Natural Science Foundation of China(2019YFC0408801)

近年来有研究发现基于过氧乙酸(PAA)的高级氧化技术(AOP)不仅可以降解水中新兴的微污染物,还比单独PAA有更好的消毒效果。本文总结了PAA的高级氧化技术活化机理,阐述了PAA的AOP在水消毒中的应用研究进展。基于目前的研究,发现UV/PAA在水消毒的前沿问题中,如藻类及藻毒素的去除、真菌及抗生素耐药菌灭活等方面都有良好的处理效果,有待更进一步的探索,其他方式活化PAA的AOP在水消毒领域的研究数量不多,拥有广阔的研究潜力,除此之外,对PAA的AOP中可能存在的消毒副产物进行识别也可能是未来的研究热点。

关键词： 过氧乙酸, 高级氧化技术, 活化机理, 水处理消毒

Recent research has revealed that PAA-based advanced oxidation processes (AOP) can simultaneously destroy developing micropollutants in water while having a greater disinfection efficacy than PAA alone. This paper summarizes the activation mechanism of PAA-based AOP and its use in water disinfection. According to recent study, UV/PAA has a good treatment effect in the cutting-edge problems of water disinfection, such as the removal of algae and algal toxins, the inactivation of fungus and antibiotic-resistant bacteria, etc. It is awaiting more investigation. There are few AOPs in the realm of water disinfection that activate PAA in other ways, but they have significant research promise. Identification of potential disinfection by-products found in AOP of PAA may also become a focus of future research.

Contents

1 Introduction

2 Peracetic acid-based advanced oxidation processes and activation mechanism

2.1 Radiation activation

2.2 Metal catalysts activation

2.3 Activated carbon catalysts activation

3 Recent advances of peracetic acid-based advanced oxidation processes in water disinfection

3.1 Recent advances of bacterial inactivation

3.2 Recent advances of fungus and algae inactivation

3.3 Recent advances of virus inactivation

3.4 Recent advances of DBPs

4 Conclusion and outlook

Key words: peracetic acid, advanced oxidation processes, activation mechanism, water disinfection
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图1 UV活化PAA机理[23]
Fig.1 Mechanism of Ultraviolet Activation of PAA[23].Copyright 2020, American Chemical Society
图2 热活化PAA机理[17]
Fig.2 Mechanism of Thermal Activation of PAA[17].Copyright 2020, American Chemical Society
表1 基于PAA的AOP降解有机污染物的研究概述
Table 1 Overview of studies employing PAA-based AOPs for removing organic compounds
Precesses Target Contamiants pH kobs Priaary Radicals ref
UV/PAA BZF 7.1 (2.40± 0.06)×10-2 min-1 HO· 46
UV/PAA DCF 7.1 1.38± 0.03 min-1HO· 46
UV/PAA CA 7.1 (2.30±0.03)×10-1 min-1 HO· 46
UV/PAA IBP 7.1 (8.83±0.15)×10-2 min-1 HO· 46
UV/PAA NAP 7.1 (3.07±0.07)×10-1 min-1 HO· 46
UV/PAA CBZ 7.1 (8.25±0.31)×10-2 min-1 HO· 46
Fe2+/PAA MB 3.0~8.2 0.17~1.75 s-1 HO· 27
Fe2+/PAA NPX 3.0~8.2 0.45~2.33 s-1 HO· 27
Fe2+/PAA BPA 3.0~8.2 0.21~0.75 s-1 HO· 27
nCuO/PAA CBZ 7 0.07 min-1 CH3C(O)OO· 33
ZVC/PAA DCF 2.0~11.0 0.1034~0.0017 min-1 HO· 35
Cu2+-HCO3-
(CO32-)/PAA		 DCF 9.3 0.0835 min-1 RO· 36
nCo3O4/PAA CBZ 7 0.03 min-1 RO· 42
Co2+/PAA SMX 7 0.1322 min-1 CHSC(O)OO· 37
Co2+/PAA BPA 7 (2.98±0.01)×10-4
(3.34±0.24)×10-2s-1		 CH3C(O)
OO·		 38
Co2+/PAA NAP 7 (4.05±0.01)×10-4
(8.12±0.38)×10-2s-1		 CH3C(O)
OO·		 38
Co2+/PAA SMX 7 (1.60±0.00)×10-4
(1.95±0.08)×10-2s-1		 CH3C(O)
OO·		 38
Co2+/PAA CBZ 7 (2.32±0.03)×10-4
(3.23±0.07)×10-3s-1		 CH3C(O)
OO·		 38
Mn2+/PAA Orange Ⅱ 7 6.05×10-2s-1 MnⅣ=O 41
MoS2/PAA SMX 7 0.128 min-1 HO· 26
US/MnO2/PAA Phenol 7 0.89 min-1 - 24
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